Effects of laser heat treatment on the fracture morphologies of X80 pipeline steel welded joints by stress corrosion

The surfaces of X80 pipeline steel welded joints were processed with a CO2 laser, and the effects of laser heat treatment （LHT） on H2S stress corrosion in the National Association of Corrosion Engineers （NACE） solution were analyzed by a slow strain rate test. The fracture morphologies and chemical components of corrosive products before and after LHT were analyzed by scanning electron microscopy and energy-dispersive spectroscopy, respectively, and the mechanism of LHT on stress corrosion cracking was discussed. Results showed that the fracture for welded joints was brittle in its original state, while it was transformed to a ductile fracture after LHT. The tendencies of hydrogen-induced corrosion were reduced, and the stress corrosion sensitivity index decreased from 35.2% to 25.3%, indicating that the stress corrosion resistance of X80 pipeline steel welded joints has been improved by LHT.     

锥度量空间中四个自映射的公共不动点定理

在完备的锥度量空间中讨论了4个自映射的公共不动点定理,其存在性和唯一性得到证明。所得主要结果将锥度量空间中的公共不动点定理进行了推广。     

生态敏感性评价研究进展

生态敏感性评价不仅为分析和预测区域生态系统失衡和环境问题提供依据,而且是生态环境影响分析和城市生态系统建设调控的重要内容和环节。文章总结了生态敏感性评价的内涵,从生态敏感性评价对象、评价方法和步骤、评价体系建立的方法、评价权重确定和评价模型选择的方法等方面,阐述了当前生态敏感性评价的研究进展,分析了生态敏感性研究存在的不足,并对生态敏感性的应用前景做出了展望。     

泥页岩地层区域三维地质力学建模与应用

印尼A油田在钻井过程中泥页岩地层井壁坍塌严重,为安全快速钻井,减少复杂事故,文章提出了一种多源地质力学建模方法,该方法综合利用岩心实验数据、已钻井测井数据、地震反演数据和泥页岩失稳机理,对印尼A油田的地质力学参数进行了精细刻画,并建立了该油田三维孔隙压力空间分布、三维弹性模量空间分布、三维泊松比空间分布等三维属性体;利用有限元的方法,计算了该油田三维地应力分布,得到三维安全钻井液密度窗口。该模型有效耦合测井数据、岩心数据、地震数据等多源数据,可在钻井设计和钻井施工过程中根据目标井的坐标位置和井眼轨迹准确获取目标井的安全钻井液密度窗口,已在该油田B-8井中现场应用,模型所得到的安全钻井液密度窗口满足现场实际需要,实钻过程中无复杂,钻井周期相对油田前期平均钻井周期缩短40%。本模型为钻井设计及现场施工确定合理钻井液安全密度窗口提供了技术支撑,为解决泥页岩等易坍塌地层的井壁失稳提供一套地质工程一体化的解决方案。     

Separation of propylene and propane with a microporous metal–organic framework via equilibrium-kinetic synergetic effect

Adsorption separation of olefin and paraffin can greatly lower the energy consumption associated with the currently utilized distillation technique but remains a great challenge. Herein, we report the efficient separation of propylene (C₃H₆) and propane (C₃H₈) in a phosphate anion-functionalized metal–organic framework (MOF) ZnAtzPO₄ by synergetic effect of equilibrium and kinetics. The material features periodically expanded and contracted apertures decorated with electronegative groups, offering eligible pore shape and pore chemistry to effectively trap C₃H₆ under moderate isosteric heat of adsorption (27.5 kJ mol⁻¹) while obstruct the diffusion of C₃H₈. It simultaneously combines excellent thermodynamic selectivity (uptake ratio of 1.71) and kinetic selectivity (~31) for C₃H₆/C₃H₈ separation, meanwhile can be easily regenerated. Breakthrough experiment for C₃H₆/C₃H₈ gas mixture was conducted and confirmed the outstanding separation capability of ZnAtzPO₄. The equilibrium and kinetics cooperative C₃H₆/C₃H₈ adsorption separation was for the first time found in anion-functionalized MOFs, and further confirmed by computational studies.     

Oxidation resistance and thermal stability of the SiC-ZrB2 composite ceramic fibers

In this study, continuous SiC-ZrB₂ composite ceramic fibers were synthesized from a novel pre-ceramic polymer of polyzirconocenecarbosilane (PZCS) via melt spinning, electron beam cross-linking, pyrolysis, and finally sintering at 1800°C under argon. The ZrB₂ particles with an average grain size of 30.7 nm were found to be uniformly dispersed in the SiC with a mean size of 59.7 nm, as calculated using the Scherrer equation. The polycrystalline fibers exhibit dense morphologies without any obvious holes or cracks. The tensile strength of the fibers was greater than 2.0 GPa, and their elastic modulus was ~380 GPa. After oxidation at 1200°C for 1 hour, the strength of the fibers did not decrease despite a small loss of elastic modulus. Compared to the advanced commercial SiC fibers of Tyranno SA, the fibers exhibited improved high-temperature creep resistance in the temperature range 1300-1500°C.     

SURFACE CARBURIZATION OF TiAl BASED ALLOY

ＳＵＲＦＡＣＥＣＡＲＢＵＲＩＺＡＴＩＯＮＯＦＴｉＡｌＢＡＳＥＤＡＬＬＯＹ￥Ｈｕａｎｇ，Ｂａｉｙｕｎ；Ｈｅ，Ｙｕｅｈｕｉ；Ｑｕ，Ｘｕａｎｈｕｉ；Ｋｏｎｇ，Ｇａｏｎｉｎｇ（ＰｏｗｄｅｒＭｅｔａｌｌｕｒｇｙＲｅｓｅａｒｃｈＩｎｓｔｉｔｕｔｅ，Ｃｅｎｔｒａｌ...     

Effects of ZrO2 on the structure and magnetic properties of CoPt thin films

[CoPt 1.5 ml/ZrO2 xnm]10 multilayer films were deposited on glass substrates by magnetron sputtering and then annealed in vacuum at 600℃ for 30 min. Their structures and magnetic properties were investigated as a function of ZrO2 content. The results show that the grain size and coercivity first increase and then decrease with the increase in ZrO2 content. The maximum coercivity and grain size are obtained at 37 vol.% of ZrO2. The content of ZrO2 in the film plays an important role in the separation of CoPt grains and in the reduction of intergrain exchange interaction. On the basis of the studies of angular dependent coercivity, it is found that the magnetization reversal of CoPt films with （111 ） texture is different from either the domain wall motion or the S-W type of rotation mode.     

稀土和镁对热浸镀铝液和镀层组织的影响

研究了热浸镀铝液中添加微量稀土和镁对铝液质量和镀铝层厚度的影响及镀铝层的表面和第二相的形貌。结果表明，微量稀土改善了铝液的质量和镀层的组织，而微量镁有损铝液质量和镀层组织。     

碳热法合成具有蓝光发射特性的氧化镓纳米线、纳米带和纳米片

利用碳纳米管通过碳热法合成了氧化镓纳米线、纳米带和纳米片。采用扫描电镜和透射电镜对其进行了形态和结构表征。合成的氧化镓纳米结构是单晶体。室温光致发光谱分析发现，氧化镓纳米晶在蓝光区域487nm处产生明显的发射峰。