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81.
    
One important issue associated to magnetocaloric materials that hinders its technological application is the poor processability and structural integrity of those with the highest performance, usually intermetallics undergoing first-order magnetic phase transitions. Additionally, the performance of these magnetocaloric materials highly depends on the structural stability of the magnetocaloric phase, which is, in many cases, very sensitive to temperature and mechanical processes. Additive manufacturing via the extrusion of polymer-based composites is regarded as a promising way to overcome these issues. A recently presented manufacturing method of encapsulating functional fillers into polymer capsules has been used to produce a composite filament with a large load of magnetocaloric off-stoichiometric Ni2MnGa Heusler alloy fillers with a uniform distribution throughout the polymer matrix as demonstrated by x-ray tomography characterization. The incorporation of these metallic particles causes changes in the thermal behavior of the polymer as well as an increase in the flowability of the composite with respect to the polymer at the same temperature. The increased flowability of the composites found during manufacturing can be compensated by lowering the extrusion temperatures, making this technique even more convenient for preserving the filler properties, which is an important concern when additive manufacturing magnetocaloric materials. This is confirmed by the magnetic and magnetocaloric behavior of the composites, with responses proportional to the fraction of fillers.  相似文献   
82.
83.
    
The ductility of a column is one of the most important characteristics of a structure subjected to unexpected overloads, load reversals, blast loads or dynamic impacts. Structural ductile members are capable of dissipating large amounts of energy by undergoing large deformations before failure, hence providing early warning to the occupants of the building. Previous analyses conducted by the authors suggest that, in addition to the type of column (steel, reinforced concrete and composite steel–concrete), the applied measure of ductility as well as other factors (the materials used and the loading and boundary conditions) have a significant influence on a column’s ductility. This paper proposes a new approach to the analysis of the ductility of columns. This approach distinguishes between the column’s pre-peak, post-peak and total ductility, and develops ductility parameters based on the displacement and energy for each of these ductility types. Based on experimental and numerical research on two-chord composite steel–concrete columns subjected to vertical monotonic loads, the influence of concrete strength and batten plate spacing on the columns’ vertical ductility is evaluated. It is concluded that designing two-chord composite steel–concrete columns to have small batten plate spacing and a relatively low concrete strength class can maximise the vertical ductility.  相似文献   
84.
    
The coatings were prepared by the means of Pt and Pt/Pd galvanizing, followed by vapor phase aluminizing at 1050 °C. Microstructural and phase analysis revealed that all the investigated coatings consisted mainly of β-NiAl phase, however the Pt-modified aluminide coating also contained PtAl2 phase and pure platinum precipitates. The cross-sectional microstructure of the coatings was zonal and composed of β-NiAl phase zone and the diffusion zone. The Pt modified aluminide coating's cross-section also incorporated an outermost zone consisting of β-NiAl and PtAl2 phases. The concentration profiles proved that both Pt and Pd contents decrease gradually inwards the modified coatings. Cyclic oxidation tests at 1100 °C proved that Pt/Pd-modified aluminide coatings exhibit the best performance under cyclic conditions. The analysis of oxidation kinetics curves showed that the course of simple aluminide coating's oxidation is slightly different from that of Pt- and Pt/Pd-modified aluminide coatings.  相似文献   
85.
Reconfigurable manufacturing systems (RMS) address challenges in modern manufacturing systems arising from product variety and from rapid changes in product demand. This paper considers an arch-type reconfigurable machine tool (RMT) that has been built to demonstrate the basic concepts of RMT design. The arch-type RMT was designed to achieve customized flexibility and includes a passive degree-of-freedom, which allows it to be reconfigured to machine a family of parts. The kinematic and dynamic capabilities of the machine are presented, including the experimental frequency response functions (FRFs) and computed stability lobes of the machine in different configurations. A comparison of FRFs and stability lobes of the arch-type RMT reveals almost similar dynamic characteristics at different reconfiguration positions. These similar characteristics arise because the dominant mode where chatter occurs is due to the spindle–tool–tool holder assembly. Consequently, to ensure consistent dynamic behavior regardless of reconfiguration, a desirable dynamic design feature for RMTs is that the machine's structural frequencies are less dominant than the structural frequencies of the spindle, tool and tool holder.  相似文献   
86.
Abstract

Problem, research strategy, and findings: Of the three primary components of housing affordability measures—rent, transportation, and utilities—utility costs are the least understood yet are the one area where the cost burden can be reduced without household relocation. Existing data sources to estimate energy costs are limited to surveys with small samples and low spatial and temporal resolution, such as the American Housing Survey and the Residential Energy Consumption Survey. In this study, we present a new method for small-area estimates of household energy cost burdens (ECBs) that leverages actual building energy use data for approximately 13,000 multifamily properties across five U.S. cities and links energy costs to savings opportunities by analyzing 3,000 energy audit reports. We examine differentials in cost burdens across household demographic and socioeconomic characteristics and analyze spatial, regional, and building-level variations in energy use and expenditures. Our results show the average low-income household has an ECB of 7%, whereas higher income households have an average burden of 2%. Notably, even within defined income bands, minority households experience higher ECBs than non-Hispanic White households. For lower income households, low-cost energy improvements could reduce energy costs by as much as $1,500 per year.

Takeaway for practice: In this study we attempt to shift the focus of energy efficiency investments to their impact on household cost burdens and overall housing affordability. Our analysis explores new and unique data generated from measurement-driven urban energy policies and shows low-income households disproportionately bear the burden of poor-quality and energy-inefficient housing. Cities can use these new data resources and methods to develop equity-based energy policies that treat energy efficiency and climate mitigation as issues of environmental justice and that apply data-driven, targeted policies to improve quality of life for the most vulnerable urban residents.  相似文献   
87.
    
Carlina acaulis L. has a long tradition of use in folk medicine. The chemical composition of the roots and green parts of the plant is quite well known. There is the lowest amount of data on the cypsela (fruit) of this plant. In this study, the microscopic structures and the chemical composition of the cypsela were investigated. Preliminary cytochemical studies of the structure of the Carlina acaulis L. cypsela showed the presence of substantial amounts of protein and lipophilic substances. The chemical composition of the cypsela was investigated using spectrophotometry, gas chromatography with mass spectrometry, and high-performance liquid chromatography with spectrophotometric and fluorescence detection. The cypsela has been shown to be a rich source of macro- and microelements, vegetable oil (25%), α-tocopherol (approx. 2 g/kg of oil), protein (approx. 36% seed weight), and chlorogenic acids (approx. 22 g/kg seed weight). It also contains a complex set of volatile compounds. The C. acaulis cypsela is, therefore, a valuable source of nutrients and bioactive substances.  相似文献   
88.
    
Colloidal quantum dots (CQDs) are nanoscale building blocks for bottom‐up fabrication of semiconducting solids with tailorable properties beyond the possibilities of bulk materials. Achieving ordered, macroscopic crystal‐like assemblies has been in the focus of researchers for years, since it would allow exploitation of the quantum‐confinement‐based electronic properties with tunable dimensionality. Lead‐chalcogenide CQDs show especially strong tendencies to self‐organize into 2D superlattices with micrometer‐scale order, making the array fabrication fairly simple. However, most studies concentrate on the fundamentals of the assembly process, and none have investigated the electronic properties and their dependence on the nanoscale structure induced by different ligands. Here, it is discussed how different chemical treatments on the initial superlattices affect the nanostructure, the optical, and the electronic‐transport properties. Transistors with average two‐terminal electron mobilities of 13 cm2 V?1 s?1 and contactless mobility of 24 cm2 V?1 s?1 are obtained for small‐area superlattice field‐effect transistors. Such mobility values are the highest reported for CQD devices wherein the quantum confinement is substantially present and are comparable to those reported for heavy sintering. The considerable mobility with the simultaneous preservation of the optical bandgap displays the vast potential of colloidal QD superlattices for optoelectronic applications.  相似文献   
89.
90.
In this work we demonstrate enhancement of the fluorescence collection efficiency for chlorophyll-containing photosynthetic complexes deposited on SiO2 spherical nanoparticles. Microscopic images of fluorescence emission reveal ring-like emission patterns associated with chlorophyll-containing complexes coupled to electromagnetic modes within the silica nanoparticles. The interaction leaves no effect upon the emission spectra of the complexes, and the transient behavior of the fluorescence also remains unchanged, which indicates no influence of the silica nanoparticles on the radiative properties of the fluorophores. We interpret this enhancement as a result of efficient scattering of electromagnetic field by the dielectric nanoparticles that increases collection efficiency of fluorescence emission.  相似文献   
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