Application and validation of incrementally complex models for wind turbine aerodynamics,isolated wind turbine in uniform inflow conditions

A comparison of several incrementally complex methods for predicting wind turbine performance, aeroelastic behavior, and wakes is provided. Depending on a wind farm's design, wake interference can cause large power losses and increased turbulence levels within the farm. The goal is to employ modeling methods to reach an improved understanding of wake effects and to use this information to better optimize the layout of new wind farms. A critical decision faced by modelers is the fidelity of the model that is selected to perform simulations. The choice of model fidelity can affect the accuracy, but will also greatly impact the computational time and resource requirements for simulations. To help address this critical question, three modeling methods of varying fidelity have been developed side by side and are compared in this article. The models from low to high complexity are as follows: a blade element‐based method with a free‐vortex wake, an actuator disc‐based method, and a full rotor‐based method. Fluid/structure interfaces are developed for the aerodynamic modeling approaches that allow modeling of discrete blades and are then coupled with a multibody structural dynamics solver in order to perform an aeroelastic analysis. Similar methods have individually been tested by researchers, but we suggest that by developing a suite of models, they can be cross‐compared to grasp the subtleties of each method. The modeling methods are applied to the National Renewable Energy Laboratory Phase VI rotor to predict the turbine aerodynamic and structural loads and then also the wind velocities in the wake. The full rotor method provides the most accurate predictions at the turbine and the use of adaptive mesh refinement to capture the wake to 20 radii downstream is proven particularly successful. Though the full rotor method is unmatched by the lower fidelity methods in stalled conditions and detailed prediction of the downstream wake, there are other less complex conditions where these methods perform as accurately as the full rotor method. Copyright © 2014 John Wiley & Sons, Ltd.     

Polyetherimide-LaNi5 composite films for hydrogen storage applications

This study investigates the preparation of polyetherimide (PEI) – LaNi₅ composites films for hydrogen storage. Prior to the polymer addition, LaNi₅ was ball-milled at different conditions (250, 350, and 450 RPM) and annealed at 500 °C for 1 h under vacuum. The composites were produced with BM-LaNi₅-350 (PEI/LaNi₅-350) and annealed BM-LaNi₅-350 (PEI/LaNi₅-350-TT). Membranes were successfully produced through solvent casting assisted by an ultrasonic bath. The particles dispersion and the film morphology did not change after hydrogenation cycles. In the H₂ sorption experiments at 43 °C and 20 bar, the films stored H₂ without incubation time; both samples reached a capacity of ~0.6 wt%. The H₂ sorption kinetics of PEI/LaNi₅-350 was comparable to that of BM-LaNi₅-350, whereas PEI/LaNi₅-350-TT presented significantly slower kinetics. LaNi₅ oxidation was hindered by PEI, showing that it can be explored to improve metal hydrides air resistance. The results demonstrated that PEI films filled with LaNi₅ are promising materials for hydrogen storage.     

Large-scale systems resilience: A survey and unifying framework

A unifying framework in defining and measuring resilience has been an intense research topic. In this paper, resilience is measured as a function of intrinsic capacities of a system, the effectiveness of recovery, and the extrinsic random shock process. Some existing resilience measures are analyzed as special cases of the proposed unifying measure. Then, we develop a framework in which the key constituents in achieving resilience are identified. Resilience is represented by four key dimensions: reliability, robustness, recovery, and reconfigurability. Finally, some practical and specific strategies are proposed to enhance the resilience of critical infrastructure systems under the proposed framework.     

Cigarette characteristics,smoker characteristics,and the relationship to cigarette fires

Data were collected from eight cities on a wide range of cigarette and smoker characteristics for a sample of smokers. Of these, 564 smokers had had fires and were identified through fire department response to those fires, while the other 1,611 smokers had not had fires and were identified through a telephone sample survey of the communities. The characteristics analyzed included those that had shown evidence of a relationship to the risk of a cigarette-initiated fire, either in laboratory studies or in previous statistical analyses of fire experience.The smoker characteristics analyzed were household income, education, age, gender, and race. The cigarette characteristics analyzed were filter, tobacco column length, filter length, circumference, density, amount of tobacco, menthol, citrate, porosity, and pack type. In addition, a variable was used to control for the smoker's city.After controlling for all smoker characteristics and city, logistic regression modeling showed four cigarette characteristics to be significant: filter, filter length, porosity, and type of pack. Filter, filter length, and porosity all affect air intake, which, therefore, appears to be an important physical element in the combustion process associated with risk. Analysis limited to filtered cigarettes only showed the same characteristics to be significant, plus tobacco column length. Extension of the analysis to two-way interaction terms did not change any of the conclusions on which cigarette characteristics are important, but it did indicate that the role of pack type was different for men and women.Sensitivity analyses, shown in the appendix, supported the main conclusions that cigarette characteristics are significant after controlling for smoker characteristics and that the four specific cigarette characteristics—filter, filter length, porosity, and pack—are the ones that are significant. These analyses checked the impact of cluster sampling, sensitivity to missing data on smoker characteristics, and sensitivity to nonfire smoker cases with responses by people other than the smokers themselves.All this means that there are already cigarettes commercially available that exhibit a reduced propensity for ignition when one controls for smoker characteristics.This report was originally written as the final report in June 1993 as part of CPSC-P-91-1147 Contract Cigarette Fire Incident Study that the National Fire Protection Association conducted for the U.S. Consumer Product Safety Commission.Harwood, formerly with the Consumer Product Safety Commission, is retired.     

Nanocrystal-encoded fluorescent microbeads for proteomics: antibody profiling and diagnostics of autoimmune diseases

The first application of nanocrystal (NC)-encoded microbeads to clinical proteomics is demonstrated by multiplexed detection of circulating autoantibodies, markers of systemic sclerosis. Two-color complexes, consisting of NC-encoded, antigen-covered beads, anti-antigen antibody or clinical serum samples, and dye-tagged detecting antibodies, were observed using flow cytometry assays and on the surface of single beads. The results of flow cytometry assays correlated with the ELISA technique and provided clear discrimination between the sera samples of healthy donors and patients with autoimmune disease. Microbead fluorescence signals exhibited narrow distribution regardless of their surface antigen staining, without the need of any fluorescence compensation-a parameter determining the limit of sensitivity of flow cytometry assays. In single bead measurements, less than 30 dye-labeled antibodies interacting with the topoI-specific antibodies at the surface of a bead have been detected by the emission of dye excited through the FRET from NCs. In this format, the antibody-bead interaction reaction turns specifically the fluorescence signal from dye label off and on, additionally increasing autoantibody detection sensitivity.     

Conventional and less conventional mechanisms of professionalisation underpinning knowledge-intensive activities: the case of design in food industries

Professions are not only primary targets of institutional change, but also key contributors to innovation processes. By focusing on how the knowledge needed in support of innovation is professionalised and reaches accepted modes of organising work, the paper examines the interplay between the emergence of a new professional domain and the institutional dynamics of the industry(ies) within which professionals operate. To this aim, we propose a reflection on the mechanisms that underpin the professionalisation of design activities in food industries. Empirical evidence draws attention to those practices that allow knowledge originated in different contexts to be socialised and converge towards the same institutional umbrella, that is, a new professional domain. The degree to which such professionalisation resonates with extant professions literature is discussed.     

A study of electrochemically treated PAN based carbon fibres by IGC and XPS

Inverse gas chromatography (IGC) has been used with conventional and novel probes in conjunction with X-ray photoelectron spectroscopy (XPS) to assess the surface chemistry of a range of aged polyacrylonitrile carbon fibres. Using conventional probes the thermodynamic surface properties were investigated at 100 °C. The dispersive component of the surface free energy, , was determined and ranged from 73.1 mJ m⁻² to 92.2 mJ m⁻². Unconventional probes, chosen as analogues of the functionalities present in a potential matrix material, were also eluted through the IGC columns. Surface compositions and peak fitting of C 1s spectra from XPS analysis helped identify groups on the fibre surface. Using these results, mechanisms of interactions occurring at the interface of a carbon fibre reinforced polymer composite have been proposed. Hydrogen bonding and stronger acid-base interactions are the main mechanisms of interactions. Although, the carbon fibres are aged, oxygen and nitrogen functionalities introduced from surface treatment have remained active.     

Physicochemical characteristics and bronchial epithelial cell cytotoxicity of Folpan 80 WG® and Myco 500®, two commercial forms of folpet

Background

Pesticides, in particular folpet, have been found in rural and urban air in France in the past few years. Folpet is a contact fungicide and has been widely used for the past 50 years in vineyards in France. Slightly water-soluble and mostly present as particles in the environment, it has been measured at average concentration of 40.1 μg/m³ during its spraying, 0.16–1.2 μg/m³ in rural air and around 0.01 μg/m³ in urban air, potentially exposing both the workers and the general population. However, no study on its penetration by inhalation and on its respiratory toxicity has been published. The objective of this study was to determine the physicochemical characteristics of folpet particles (morphology, granulometry, stability) in its commercial forms under their typical application conditions. Moreover, the cytotoxic effect of these particles and the generation of reactive oxygen species were assessed in vitro on respiratory cells.

Results

Granulometry of two commercial forms of folpet (Folpan 80WG^® and Myco 500^®) under their typical application conditions showed that the majority of the particles (>75%) had a size under 5 μm, and therefore could be inhaled by humans. These particles were relatively stable over time: more than 75% of folpet remained in the particle suspension after 30 days under the typical application conditions. The inhibitory concentration (IC₅₀) on human bronchial epithelial cells (16HBE14o-) was found to be between 2.89 and 5.11 μg/cm² for folpet commercial products after 24 h of exposure. Folpet degradation products and vehicles of Folpan 80 WG^® did not show any cytotoxicity at tested concentrations. At non-cytotoxic and subtoxic concentrations, Folpan 80 WG^® was found to increase DCFH-DA fluorescence.

Conclusion

These results show that the particles of commercial forms of folpet are relatively stable over time. Particles could be easily inhaled by humans, could reach the conducting airways and are cytotoxic to respiratory cells in vitro. Folpet particles may mediate its toxicity directly or indirectly through ROS-mediated alterations. These data constitute the first step towards the risk assessment of folpet particles by inhalation for human health. This work confirms the need for further studies on the effect of environmental pesticides on the respiratory system.