Photoinitiated crosslinking of low density polyethylene. III: Degradation and stabilization of photocrosslinked polyethylene

Electron spectroscopy (ESCA) and reflectance infrared spectroscopy (ATR) were used to measure surface oxidation of photocrosslinked polyethylene. The deterioration of bulk properties during an artificial weathering test was also measured. It was found that the UV-irradiation during crosslinking process decreases the stability of the material considerably. Three kinds of antioxidants and photostabilizers (hindered phenols, hindered amines, and organic sulfides) which have no absorption in the UV region of 300 to 400 nm were added before crosslinking to improve the stability of the crosslinked material. Neither the rate nor the degree of photocrosslinking at different depths of the sample were affected significantly by these additives. It was found possible to prevent the decrease in stability due to the photocrosslinking by using small amounts of a stabilizer, e.g. 0.05% Tinuvin 770 (hindered amine).     

Induced low temperature catalytic ignition by transient changes in the gas composition

The effect of gas composition changes on the low temperature activity for supported platinum model catalysts has been studied. By introducing well-controlled periodic O₂ pulses to a simple diluted gas mixture of CO and O₂, a substantial improvement of the low temperature oxidation activity was observed. The reason for low activity on noble metals at low temperatures is often attributed to self-poisoning by CO. The improved catalytic performance observed is proposed to origin from the transients causing a surface reactant composition that is favourable for the reaction rate, i.e. lower degree of self-poisoning. This was also confirmed by in situ Fourier transform infrared (FT-IR) spectroscopy in combination with mass spectrometry (MS) measurements, which gave evidence for the existence of a strong interplay between the gas phase concentration and the adsorbate composition for these catalysts.     

Measuring psychosocial work quality and health: Development of health care measures of measurement.

Demands on workload and work efficiency have increased because of ongoing global changes in health care organizations. Assessing and evaluating effects of changes on organizational and individual well-being require valid and reliable methods. Questionnaires from 3 large health care studies were used to develop instruments for work quality and health. Study 1 included 2,935 participants from all occupational groups. Study 2 sampled 3,545 nurses and midwives. Participants in Study 3 consisted of 3,506 employees at a large hospital. Variable fields of work quality, health and well-being, and modifying factors were factor analyzed with replicated structures in new samples, including 6 factors of work quality, 5 health factors, and 2 modifying factors. All except 2 factors had high internal consistency (Cronbach's α?=?.69–84) and low factor intercorrelations within areas. Social climate (but not individual resources) had, according to our model, a modifying effect on the work-health interaction (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

An improved dynamic solar collector test method for determination of non-linear optical and thermal characteristics with multiple regression

The objective is to characterise the solar collector during a relatively short testing period with no requirement for steady state climatic conditions. This information is then used for predicting annual performance of the collector. A standard collector model that is compatible with the ISO 9806-1 test standard is used with correction terms for beam and diffuse incidence angle modifiers, thermal capacitance, wind speed and sky temperature. This results in a more complete characterisation of the collector. The collector parameters are identified by multiple linear regression, MLR. The method has been tested for characterisation of unglazed collectors, glazed flat plate collectors, evacuated tubular collectors, CPC collectors and concentrating collectors with satisfying results. Typically the correlation coefficient R² is better than 0.99 and the standard deviation of the difference between model and measurement is in the range 3–10 W/m².

In the original method the angular dependence of the optical efficiency and the temperature dependence of the heat losses are supposed to be adjusted to a predetermined function. The most recent development is a routine that makes it possible to accurately identify non-linear optical and thermal performance. This extended MLR method can identify the zero loss efficiency for every angle of incidence interval and the temperature dependent heat losses for every temperature interval. This opens the application of the method to collectors with special incidence angle and heat loss effects that cannot be described easily with a combination of elementary functions. Instead a table of parameter values is determined, which is used directly in standard simulation programmes. This method will further increase the accuracy when comparing different collector designs. It has been used for comparing different glazings and for comparison with spectrophotometric measurements. It has also been used for analysing the heat loss factors for Teflon and honeycomb glazings. Since the total power output of the collector is less dependent on the heat loss coefficient than on the optical efficiency the scattering in this data is larger than for the incidence angle curves.

The reflectance of booster mirrors cannot be derived with the MLR-method with acceptable accuracy. The correlation between direct irradiance and irradiance from the reflector exhibit a very strong correlation. Instead the effective reflectance of the mirror can be estimated by comparison of the measured output with calculation by the complete collector and reflector model. This effective reflectance is not compatible with the specular reflectance obtained from spectrophotometric measurements caused by large differences in acceptance angles.

Standard multiple linear regression available in most spread sheet and statistical programs can be used for the parameter identification in the extended MLR-procedure. The identification takes only a few seconds. At the Älvkarleby Laboratory the test method is now used as a routine tool for the evaluation of new collector materials and designs. The Swedish National testing institute has evaluated the methods with the conclusion that they have a potential for being used in standardised collector testing.     

The dynamics of Swedish national and regional house price movement

In this study, the recent persistent growth of regional house price pattern in Sweden is explained by the fundamental variables and the regional distributive perspective on household income and wealth are indicated to be important to understand the different level and development of regional housing market. We also discuss the long running relationship between house prices and migration flows and highlight its critical role on house price analyses.     

Photoinitiated crosslinking of low density polyethylene. V: Orientation in stretched samples

Low density polyethylene (LDPE) is extruded, stretched, and photocrosslinked at different temperatures with different stretch rations in a continuous production line. Three different sequences are adopted: crosslinking before drawing, crosslinking after drawing, and crosslinking during drawing. The effect of drawing is studied by measuring the tensile properties. The increase of tensile strength and the decrease of elongation at break after stretching are related to chain orientation in crystalline morphology measured by X-ray diffraction. Thermal analysis by differential scanning calorimetry (DSC) supports these results. Owing to chain relaxation, the effects of orientation by stretching are significant only when the samples are drawn at a temperature not much higher than the melting point. Annealing of the drawn samples at a temperature above the melting point shows that the orientation in a crosslinked sample is retained for a much longer time than in an uncrosslinked sample. For the crosslinked samples, it is found that crosslinking after or during drawing gives a material with lower shrinkage upon heating; however, crosslinking before drawing gives a heat-shrinkable material.     

Thermal destruction of PCB and hexachlorobenzene

PCB and hexachlorobenzene are considered to be two environmental compounds of concern that are most difficult to destroy. This report describes experiments that have been carried out in order to obtain basic data for appraisal of the risks involved in the thermal destruction of PCB and hexachlorobenzene.The investigation indicates that it is possible to destroy PCB by incineration provided that the transit time is sufficiently long. In the pilot scale incinerator used, a transit time of more than two seconds was required to obtain a residue of PCB that was less than 100 mg/kg PCB fed into the incinerator. It was not possible to determine any fixed relationship between the temperature and the PCB residue within the temperature range examined (675–1000°C). The investigation also shows that hexachlorobenzene is formed in association with the combustion of PCB and that the rate of formation increases at high temperatures (35 mg HCB/kg PCB at 1000°C).A temperature of 950°C is needed for the destruction of hexachlorobenzene if the residue is to be less than 100 mg HCB/kg HCB. At 800°C, with a transit time of about 2 s, there is a residue of approximately 1200 mg/kg.     

Photoinitiated crosslinking of low density polyethylene: II. Morphology and properties

The crystalline morphology and physical properties of photocrosslinked polyethylene in a low density polyethylene (LDPE)-benzophenone (BP)-triallyl isocyanurate (TAIC) system have been studied. The results of X-ray diffraction and DSC thermal analysis indicate that the effect of crosslinking on the degree of crystallinity of the material is quite limited, but the presence of crosslinks can affect the regularity of the crystal regions. This is proposed to be responsible for the slight variation in properties of the crosslinked material at room temperature, such as the decrease of modulus and the changes of yield behavior. The main improvements in properties of the photocrosslinked polyethylene are found at high temperatures, especially above the melting point. The strength is increased, and the heat distortion temperature is enhanced significantly, as previously reported in the literature.