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排序方式: 共有860条查询结果,搜索用时 15 毫秒
1.
Small-angle neutron scattering by a polymer melt with partly tagged chains is considered. When several types of chain (differently labelled) are present in the system a new long-range correlation effect which modifies the scattering spectrum is predicted. This effect will arise because of the chemical polydispersity of the sample. A general formalism is developed to calculate the scattering intensity and is applied to special cases: diblock and triblock chains. It is shown that even a small chemical polydispersity leads to important long-range fluctuations and modifies the scattering spectrum substantially. 相似文献
2.
Takeshi Kondo Sang Min Lee Michal Malicki Benoit Domercq Seth R. Marder Bernard Kippelen 《Advanced functional materials》2008,18(7):1112-1118
We report on a single‐layer organic memory device made of poly(N‐vinylcarbazole) embedded between an Al electrode and ITO modified with Ag nanodots (Ag‐NDs). Devices exhibit high ON/OFF switching ratios of 104. This level of performance could be achieved by modifying the ITO electrodes with some Ag‐NDs that act as trapping sites, reducing the current in the OFF state. Temperature dependence of the electrical characteristics suggest that the current of the low‐resistance state can be attributed to Schottky charge tunnelling through low‐resistance pathways of Al particles in the polymer layer and that the high‐resistance state can be controlled by charge trapping by the Al particles and Ag‐NDs. 相似文献
3.
Loranger Michel; Pépin Michel; Gignac Guy; Benoit Geneviève 《Canadian Metallurgical Quarterly》1995,36(1):59
Presents results of 3 studies on the psychometric properties of the LP-ABC (M. Loranger and M. Pépin, 1993), a French-language instrument for assessing general functioning in adults with mental retardation. The studies involved a total of 299 male and female Canadian adults with mental retardation. Results confirm the internal consistency, construct validity, criterion validity, discriminant validity, interrater reliability, and test–retest reliability of the LP-ABC. (English abstract) (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
4.
M. C. Julienne M. J. Alonso J. L. G
Mez Amoza J. P. Benoit 《Drug development and industrial pharmacy》1992,18(10):1063-1077
This study investigates the use of the solvent evaporation method for preparing acid and glycolic acid-based copolymer nanoparticles. Initially, appropriate technological and formulation factors for elaboration of polymeric particles were selected by screening. Most favourable results were obtained using polyvinyl alcohol as a dispersing agent and a high pressure homogenizer to reduce the droplet size of the emulsion initially formed. On the basis of the conclusion thus drawn, a composite rotational experimental design was employed to evaluate the joint influence of three formulation variables (phase volume ratio of the emulsion formed, polymer concentration and homogenization pressure) on the micromeritic properties of the suspension finally obtained (mean particle size, coefficient of variation and polydispersity of the particle size distribution). Analysis of variance corresponding to the experimental design, showed a significant influence of the volume phase ratio and the polymer concentration on the mean particle size and the coefficient of variation, whereas the polydispersity is also affected by the homogenization pressure. Considering this information, a 32 experimental factorial design was then selected to investigate the possible interaction between the phase volume ratio and the concentration of polyvinyl alcohol in the aqueous phase. Analysis of variance and subsequent sequencial regression analysis evidenced last hypothesis providing the way to determine the experimental conditions required to achieve a specific particle size distribution. 相似文献
5.
William L. Benoit 《The Journal of communication》2006,56(2):331-345
This study investigates retrospective and prospective voting from a communication perspective, looking to see whether there is relationship between election outcome and the relative emphasis U.S. presidential candidates place on retrospective (past) versus prospective (future) utterances in campaign messages. The sample includes a variety of presidential campaign messages (acceptance addresses, primary and general television spots, debates, direct mail advertising) from several campaigns (1948–2004) by numerous candidates. In the primary phase of the campaign, there is no difference between winners and losers in relative emphasis on retrospective and prospective statements. However, in the general phase of the presidential campaign, winners use a significantly larger proportion of retrospective (and a smaller proportion of prospective) utterances than losers. Furthermore, the relationship between emphasis on retrospective utterances and election outcome was larger for incumbents than challengers (but significant for both types of candidates). These findings support retrospective voting in the general, but not the primary, campaign. 相似文献
6.
Despite the common use of tapping-mode atomic force microscopy to image composites or polymer blends, very few studies have focused on the measurement of the interdiffusion at an interface between two polymers in contact. In this study, we show how to assess the interphase between two polymers with two methods. First, stable and robust tapping conditions are established, and the problem of the phase contrast is discussed. Second, a contact-resonance method is presented: the tip in contact with the sample is electrostatically excited at its resonance frequency by a self-controlled oscillator. The gain and frequency images allow us to measure the interdiffusion width. Both methods (using high and weak mechanical solicitation) give the same assessment of the interdiffusion width. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
7.
The extracellular environment controls many cellular activities thereby linking external material cues to internal cell function. By better understanding these processes, synthetic extracellular material niches can be tailored to present cells with highly regulated physical and/or chemical cues that promote or suppress selected cell functions. Here, poly(ethylene glycol) (PEG) hydrogels were functionalized with fluvastatin-releasing grafts and growth factor binding heparin domains to enable the dynamic exchange of information between the material and cells from the outside-in and inside-out (i.e., bidirectional signaling). By incorporating a fluvastatin-releasing graft and carefully controlling the dose and temporal release, materials were designed to promote bone morphogenic protein (BMP2) and alkaline phosphatase (ALP) production by human mesenchymal stem cells (hMSCs). When the release of fluvastatin was controlled to occur over 2 weeks, BMP2 and ALP production was increased 2.2-fold and 1.7-fold, respectively, at day 28 compared to hMSCs cultured in the absence of fluvastatin. By introducing a heparin functionality into the gel to sequester and localize the hMSC-produced BMP2, the osteogenic differentiation of hMSCs was further augmented over fluvastatin delivery alone. Osteopontin and core binding factor α1 gene expression was 6-fold and 4-fold greater for hMSCs exposed to fluvastatin in the presence of the heparin functionalities, respectively. These results demonstrate how multifunctional gels that interact with cells in a bidirectional manner can efficiently promote selected cell functions, such as the osteogenic differentiation of hMSCs. 相似文献
8.
The last decade has witnessed the development and uprising of social media web services. The use of these shared online media as a source of huge amount of data for research purposes is still a challenging problem. In this paper, a novel framework is proposed to collect training samples from online media data to model the visual appearance of social events automatically. The visual training samples are collected through the analysis of the spatial and temporal context of media data and events. While collecting positive samples can be achieved easily thanks to dedicated event machine-tags, finding the most representative negative samples from the vast amount of irrelevant multimedia documents is a more challenging task. Here, we argue and demonstrate that the most common negative samples, originating from the same location as the event to be modeled, are best suited for the task. A novel ranking approach is devised to automatically select a set of negative samples. Finally the automatically collected samples are used to learn visual event models using Support Vector Machine (SVM). The resulting event models are effective to filter out irrelevant photos and perform with a high accuracy as demonstrated on various social events originating for various categories of events. 相似文献
9.
Elhadi Shakshuki Hsiang-Hwa Koo Darcy Benoit Daniel Silver 《Journal of Computer and System Sciences》2008,74(2):279-296
Electronic calendars are important tools that are used by consumers on a daily basis. However, scheduling a meeting that involves persons with different commitments and preferences remains a difficult task. Meeting scheduling is difficult because current calendaring applications cannot handle the responsibility of automatically and autonomously managing time slots. This paper presents a distributed multi-agent system architecture in which each person is represented by an agent. These agents automatically and autonomously work together to assist different users to book meetings on their behalf. Each agent has the capability to manage, negotiate and schedule tasks, meetings, events, appointments for its assigned user. In this multi-agent system, the agents coordinate their activities and negotiate on behalf of their associated users to find a solution that satisfies the users' meeting requirements and preferences. A prototype of this system is implemented to demonstrate how the agents can automatically book meetings. 相似文献
10.