Development and application of a new spray impingement model considering film formation in a diesel engine

The present article presents an extension to the computational model for spray/ wall interaction and liquid film processes that has been dealt with in the earlier studies (Lee and Ryou, 2000a). The extensions incorporate film spread due to impingement forces and dynamic motion induced by film inertia to predict the dynamic characteristics of wall films effectively. The film model includes the impingement pressure of droplets, tangential momentum transfer due to the impinging droplets on the film surface and the gas shear force at the film surface. Validation of the spray/ wall interaction model and the film model was carried out for non-evaporative diesel sprays against several sources of experimental data. The computational model for spray/wall interactions was in good agreement with experimental data for both spray radius and height. The film model in the present work was better than the previous static film model, indicating that the dynamic effects of film motion should be considered for wall films. On the overall the present film model was acceptable for prediction of the film radius and thickness.     

Supercapacitive properties of polyaniline/hydrous RuO2 composite electrode

A composite electrode based on polyaniline (PANI) and hydrous RuO₂ is prepared by electrochemical deposition of PANI onto hydrous RuO₂ (PANI/RuO₂) and its supercapacitive properties are investigated using cyclic voltammetry. The specific capacitances of PANI/RuO₂ and hydrous RuO₂ electrodes are determined to be 708 and 517 F g⁻¹ at 5 mV s⁻¹, respectively. Simple electrodeposition of PANI on the hydrous RuO₂ can achieve comparatively greater capacitance values.