Thermal stability of modified end‐capped poly(lactic acid)

The influence of functional end groups on the thermal stability of poly(lactic acid) (PLA) in nitrogen‐ and oxygen‐enriched atmospheres has been investigated in this article using differential scanning calorimetry, thermogravimetric analysis (TGA), and dynamic mechanical analysis (DMA). Functional end groups of PLA were modified by succinic anhydride and l ‐cysteine by the addition–elimination reaction. PLA was synthesized by azeotropic condensation of l ‐lactic acid in xylene and characterized by nuclear magnetic resonance. The values of the activation energies determined by TGA in nitrogen and oxygen atmospheres revealed that the character of functional end groups has remarkable influence on the thermal stability of PLA. Moreover, DMA confirmed the strong influence of functional end groups of PLA on polymer chains motion. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 41105.     

Correlation of the loss in photovoltaic module performance with the ageing behaviour of the backsheets used

The influence of the type of backsheet on the electrical performance of test modules was evaluated before and after increasing time of accelerated ageing (damp heat [DH] exposure). Besides the measurement of the electrical power of the modules and the performance of the cells by electroluminescence, the ageing‐induced changes within the polymeric encapsulate and backsheets were investigated by means of vibrational spectroscopy and by thermo analytical methods. In addition, the permeability of the backsheets in the original and aged state was determined. This wide set of test parameters and methods allowed for the detection of correlations between (i) physical and chemical properties as well as their ageing‐induced changes of the materials and (ii) the module performance. A clear dependence of the relative loss in power output upon exposure under DH conditions for 2000 h could be observed for a set of identical test modules varied in composition only in the type of back cover used. While the modules containing gas‐tight backsheets and glass experienced only little loss in the relative power output, some modules with permeable backsheets showed a significant relative decrease in the power output and fill factor in dependence of the backsheet type used. Cell degradation could be visualised by recording electroluminescence images before and after the accelerated ageing test. The permeation properties of the backsheet used and their ageing‐induced changes seem to have an influence on the module performance. However, the absolute values neither of the water vapour transmission rate (WVTR) nor of the oxygen transmission rate (OTR) are directly linked to the loss in power output upon accelerated ageing under DH conditions. It could be shown that the ageing‐induced changes (relative transmission rates) between WVTR and OTR can be correlated with the module performance. These ageing‐induced changes in the permeation behaviour of the backsheets can be explained by (i) physical changes (e.g. post‐crystallisation, changes in the crystal structure or the crystalline microstructure) and (ii) chemical ageing effects such as a decrease in the molecular mass of the polyester (PET) polymer chains because of hydrolytic polymer degradation leading to a change in the crystallisation behaviour of PET. Hydrolytic degradation (= chemical ageing) of the PET core layer was observed (with varying extent) for all PET‐based backsheets and can, thus, not be directly correlated with the loss in performance of the corresponding test modules. The physical ageing effects, however, were detected only for those backsheets showing (i) strong deviating changes in the relative permeation rates for oxygen and water vapour upon accelerated ageing and (ii) a clear loss in electrical performance. Copyright © 2015 John Wiley & Sons, Ltd.     

Aurora Kinase A Is Involved in Controlling the Localization of Aquaporin-2 in Renal Principal Cells

The cAMP-dependent aquaporin-2 (AQP2) redistribution from intracellular vesicles into the plasma membrane of renal collecting duct principal cells induces water reabsorption and fine-tunes body water homeostasis. However, the mechanisms controlling the localization of AQP2 are not understood in detail. Using immortalized mouse medullary collecting duct (MCD4) and primary rat inner medullary collecting duct (IMCD) cells as model systems, we here discovered a key regulatory role of Aurora kinase A (AURKA) in the control of AQP2. The AURKA-selective inhibitor Aurora-A inhibitor I and novel derivatives as well as a structurally different inhibitor, Alisertib, prevented the cAMP-induced redistribution of AQP2. Aurora-A inhibitor I led to a depolymerization of actin stress fibers, which serve as tracks for the translocation of AQP2-bearing vesicles to the plasma membrane. The phosphorylation of cofilin-1 (CFL1) inactivates the actin-depolymerizing function of CFL1. Aurora-A inhibitor I decreased the CFL1 phosphorylation, accounting for the removal of the actin stress fibers and the inhibition of the redistribution of AQP2. Surprisingly, Alisertib caused an increase in actin stress fibers and did not affect CFL1 phosphorylation, indicating that AURKA exerts its control over AQP2 through different mechanisms. An involvement of AURKA and CFL1 in the control of the localization of AQP2 was hitherto unknown.     

Piezoelectric field measurements by photoreflectance in strained InGaAs/GaAs structures grown on polar substrates

Photoreflectance (PR) measurements were performed on specific structures grown by molecular-beam epitaxy on different substrate orientations: 111B, 111B 2° off, 111A and 100. A strained In_0.2Ga_0.8As quantum well was grown in the space charge layer of an undoped GaAs layer. On a polar substrate orientation 111, the strain-induced piezoelectric field in the quantum well modifies the field in the space charge layer. PR spectra recorded in such structures exhibit Franz Keldysh oscillations from which we can measure the internal electric field. The piezoelectric field is then deduced from a comparison between two structures differing only by the presence of the strained quantum well. Experimental values ranged between 110 kV/cm and 150 kV/cm, and were used to determine experimentally the piezoelectric constant e₁₄ in In_0.2Ga_0.8As.     

In0.53Ga0.47As MSM photodiodes withtransparent CTO Schottky contacts and digital superlattice grading

Metal-semiconductor-metal (MSM) photodiodes with an In_0.53 Ga_0.47As active region were investigated using a transparent cadmium tin oxide (CTO) layer for the interdigitated electrodes to improve the low responsivity of conventional MSM photodiodes with opaque electrodes. CTO is suitable as a Schottky contact, an optical window and an anti-reflection (AR) coating. The transparent contact prevents shadowing of the active layer by the top electrode, thus allowing greater collection of incident light. Responsivity of CTO-based MSM photodiodes with 1-μm finger widths and 2-μm finger spacings and without an AR coating between the electrodes was twice (0.62 A/W) that of a similar MSM photodiodes with Ti/Au electrodes (0.30 A/W). A thin 800 Å In_0.52Al_0.48 As layer was inserted below the electrodes to elevate the electrode Schottky barrier height. A digitally graded superlattice region (660 A) was also employed to reduce carrier trapping at the In _0.53Ga_0.47As/In_0.52Al_0.48As heterointerface which acts to degrade photodiode bandwidth. Bandwidth of opaque electrode MSMs was elevated nearly an order of magnitude over a previous MSM photodiode design with an abrupt heterointerface, whereas the bandwidth of transparent electrode MSM's only improved about five times, indicating resistive effects may be intervening     

Evolution of silver in a eutectic-based Bi<Subscript>2</Subscript>O<Subscript>3</Subscript>–Ag metamaterial

The development of novel manufacturing techniques of nano-/micromaterials, especially metallodielectric materials, has enabled dynamic development of such fields as nanoplasmonics. However, the fabrication methods are still mostly based on time-consuming and costly top-down techniques limited to two-dimensional materials. Recently, directional solidification has been proposed and utilized for manufacturing of volumetric nanoplasmonic materials using the example of a Bi₂O₃–Ag eutectic-based nanocomposite. Here, we explain the evolution of silver in this composite, from the crystal growth through the post-growth annealing processes. Investigation with tunneling electron microscopy shows that silver initially enters the composite as an amorphous AgBiO₃ phase, which is formed as a wetting layer between the grains of Bi₂O₃ primary phase. The post-growth annealing leads to decomposition of the amorphous phase into Bi₂O₃ nanocrystals and intergranular Ag nanoparticles, providing the tunable localized surface plasmon resonance at yellow light wavelengths.