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631.
The fundamental principles of chemical product design and associated systematic tools, within a broad domain of chemical products including molecules, formulations, and devices, are still under development. In this article, we propose a simple and fundamental conceptual model that defines the chemical product design problem as the inversion of three central design functions: quality, property, and process functions. The classic iterative cycles of product design problems may be envisioned as alternating between inversion and evaluation of these three functions, or in other words alternating between synthesis and analysis of solutions. On top of the proposed basic structure of the overall design problem, we then discuss the formulation of some subproblems as optimization problems and describe some useful solution tools. Three application examples are provided, including a more detailed case of formulation of a pharmaceutical ointment. © 2014 American Institute of Chemical Engineers AIChE J, 61: 802–815, 2015 相似文献
632.
Implementation of IEEE-1588 timing and synchronization for ATCA control and data acquisition systems
Miguel Correia Jorge Sousa Álvaro Combo António P. Rodrigues Bernardo B. Carvalho António J.N. Batista Bruno Gonçalves Carlos M.B.A. Correia Carlos A.F. Varandas 《Fusion Engineering and Design》2012,87(12):2178-2181
Control and data acquisition (C&DA) systems for Fusion experiments are required to provide accurate timing and synchronization (T&S) signals to all of its components. IPFN adopted PICMG's Advanced Telecommunications Computing Architecture (ATCA) industry standard to develop C&DA instrumentation. ATCA was chosen not only for its high throughput characteristics but also for its high availability (HA) features which become of greater importance in steady-state operation scenarios. However, the specified ATCA clock and synchronization interface may be too limited for the timing and synchronization needs in advanced Physics experiments. Upcoming specification extensions, developed by the “xTCA for Physics” workgroups, will contemplate, among others, a complementary timing specification, developed by the PICMG xTCA for Physics IO, Timing and Synchronization Technical Committee. The IEEE-1588 Precision Time Protocol (PTP) over Ethernet is one of the protocols, proposed by the Committee, aiming for precise synchronization of clocks in measurement and control systems, based on low jitter and slave-to-slave skew criteria.The paper presents an implementation of IEEE-1588 over Ethernet, in an ATCA hardware platform. The ATCA hardware consists of an Advanced Mezzanine Card (AMC) quad-carrier front board with PCI Express switching. IEEE-1588 is to be implemented on a Virtex-6 FPGA. Ethernet connectivity with the remote master clock is located on the rear transition module (RTM). The generated synchronized clock and absolute time in IRIG-B format are distributed to all systems endpoints by a cross-point switch which is also implemented on the FPGA. 相似文献
633.
Souza Vanessa Gimenes Régio Marcio Toesca de Almeida Marcel Gonçalves Farinha Maycon Ulisses Saraiva Bernardo Luciana Virginia Mario Ruviaro Clandio Favarini 《Clean Technologies and Environmental Policy》2023,25(8):2761-2775
Clean Technologies and Environmental Policy - Objective is to analyze the economic feasibility of implementing a greenhouse in a hydroponics production system in substrate (sand) on a small family... 相似文献
634.
635.
Felipe S. Stefanello Yuri G. Kappenberg Juliane N. Araújo Bianca Dozza Pablo A. Nogara João B. T. Rocha Nilo Zanatta Marcos A. P. Martins Helio G. Bonacorso Bernardo A. Iglesias 《Chembiochem : a European journal of chemical biology》2022,23(14):e202200248
A convenient synthesis of a broad series of thirteen examples of alkyne-spacer derivatives 2 from the well-known Sonogashira cross-coupling reaction on diazenyl-pyrazolo[1,5-a]pyrimidin-2-amine compounds 1 is reported. The reactivity of heterocycles 1 due the presence of selected electron-donor (EDG) and electron-withdrawing (EWG) groups attached to different alkynes was evaluated. Also, the reactional versatility due the position variation of the bromo atom at the scaffolds 1 was also investigated. In general, derivatives presented strong absorption bands at the 250–500 nm optical window and UV to cyan emission properties. Also, the redox analysis was recorded by electrochemical cyclic voltammetry technique. For HSA biomacromolecule assays, spectroscopic studies by UV-Vis, steady-state and time-resolved emission fluorescence, and molecular docking calculations evidenced the ability of each compound to establish interactions with human serum albumin (HSA). Finally, the behavior presented for this new class of heterocycles makes them a promising tool as optical sensors for albumins. 相似文献
636.
Maxsueli Aparecida Moura Machado Vinicius Silva Castro Maria Lúcia Guerra Monteiro Yago Alves de Aguiar Bernardo Eduardo Eustáquio de Souza Figueiredo Carlos Adam Conte-Junior 《International Journal of Dairy Technology》2023,76(1):74-80
We aimed at characterising the nonthermal technologies resistance profile of two Escherichia coli strains isolated from pasteurised milk and described as moderate-to-high heat resistance (MHR) (60°C/6 min) harbouring or not a transmissible locus of stress tolerance (tLST). The characterisation was carried out applying optimised conditions of ultraviolet-C light-emitting diodes (UVC-LED) (4950 mJ/cm2), ultrasound (US) (299 W) and their combination (UVC-LED + US). Both strains were more sensitive to UVC-LED (4.5–1.5 log cfu/mL) than to US (<1 log cfu/mL) or UVC-LED + US (4.5–1.5 log cfu/mL), which did not exhibit synergism. Thus, UVC-LED is a promising technology to eliminate E. coli harbouring tLST. 相似文献
637.
Alessandro Andreadis Giuliano Benelli Giovanni Giambene Bernardo Marzucchi 《Wireless Communications and Mobile Computing》2001,1(4):381-395
This paper, based on the PALIO Project within the fifth Research Framework of the European Commission, deals with an information tourist service accessible through mobile phones by means of the Wireless Application Protocol (WAP). We have considered a Global System for Mobile communications (GSM) network where the WAP traffic is transported by the Short Message Service (SMS) on a logical channel that also conveys signaling messages. Suitable models have been considered for both WAP browsing traffic and signaling traffic. We have proposed a theoretical approach to evaluate the mean delay to browse a WAP page taking into account the impact of the signaling load. Analytical predictions have been validated through comparisons with simulation results. Moreover, we have also considered a specific Quality of Service (QoS) requirement in terms of the maximum deck transmission delay that is guaranteed in 95 per cent of cases. Consequently, it has been possible to evaluate the number of WAP users that can be supported per cell. The study carried out in this paper permits to prove the feasibility for the envisaged mobile service based on WAP and it also allows dimensioning WAP pages so that each user experiences reasonable browsing delays. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
638.
Carlos M. Alexandre Bernardo R. Quintella Michaël Ovidio Isabel Boavida Maria J. Costa Arjan P. Palstra Rui L. Pedroso de Lima Maria Isabel P. de Lima João L.M.P. de Lima Pedro R. Almeida 《河流研究与利用》2023,39(3):538-553
Dam construction and streamflow regulation are increasing throughout the world, with impacts in impounded aquatic ecosystems. Hydropower dams, some of them causing a phenomenon called “hydropeaking” during their operation, are known for having a variety of impacts on downstream aquatic biota, particularly fish, and respective habitat. This can result in significant changes, from the community (e.g., fish assemblage structure) to the individual level (e.g., physiological and behavioural adjustments). Researchers and managers involved in the assessment of hydropeaking impacts must be resourceful and use methods that allow their precise evaluation, from large to fine-scale habitat and biological responses. In the last decades, technological advances allowed for the development of techniques and instrumentations that are increasingly being used in hydropeaking impact and mitigation assessments. This paper aims to provide a review, to researchers and managers interested in this field, of some of the most innovative methods and techniques, involving technology, that are available to study hydropeaking effects on downstream ecosystem, particularly from a fish perspective. We discuss the fundamentals behind such techniques, their advantages, and disadvantages, while also providing practical examples of their application and of the type of results that can be obtained. We finish by discussing some of the shortcomings of these methods and how related technology can evolve to solve current limitations. 相似文献
639.
Leso Bernardo Henrique Cortimiglia Marcelo Nogueira Ghezzi Antonio 《Cognition, Technology & Work》2023,25(1):151-179
Cognition, Technology & Work - Contributing to the scarce literature on how companies can deal with their business model of digital transition, this work explores the digital transformation... 相似文献
640.
The material properties of short fiber composites, such as modulus, strength and thermal expansion, are greatly dependent on the fiber orientation state in the composite. Although the orientation pattern is often quite complex, models that allow its prediction have been successfully applied in combination with micromechanical models to calculate moduli and thermal properties. This paper describes the derivation of a model to predict the strength of short fiber composites with arbitrary fiber orientation and fiber length distribution based on classical (micro-) mechanical theories. The predictions are in good agreement with data measured on short fiber composites with different fiber contents. 相似文献