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91.
92.
Christina Skiera Panagiotis Steliopoulos Thomas Kuballa Ulrike Holzgrabe Bernd Diehl 《Journal of the American Oil Chemists' Society》2012,89(8):1383-1391
Within the course of lipid peroxidation, hydroperoxides are formed as primary products. They can be used as analytical markers
to assess the deterioration status of oils and fats. Here a new 1H-NMR assay to determine the hydroperoxide amount in edible oils is presented. We were able to show that the analytical performance
of the method is similar to that of the commonly used peroxide value (PV) according to Wheeler. A total of 290 edible oil
samples were analyzed using both methods. For some oil varieties considerable discrepancies were found between the results
obtained. In the case of black seed and olive oil, two substances could be identified that cause positive (black seed oil)
and negative (olive oils) deviations from the theoretical PV expected from the NMR values. 相似文献
93.
Dr. Holger Siebeneicher Dr. Arwed Cleve Dr. Hartmut Rehwinkel Dr. Roland Neuhaus Dr. Iring Heisler Dr. Thomas Müller Dr. Marcus Bauser Dr. Bernd Buchmann 《ChemMedChem》2016,11(20):2261-2271
Despite the long‐known fact that the facilitative glucose transporter GLUT1 is one of the key players safeguarding the increase in glucose consumption of many tumor entities even under conditions of normal oxygen supply (known as the Warburg effect), only few endeavors have been undertaken to find a GLUT1‐selective small‐molecule inhibitor. Because other transporters of the GLUT1 family are involved in crucial processes, these transporters should not be addressed by such an inhibitor. A high‐throughput screen against a library of ~3 million compounds was performed to find a small molecule with this challenging potency and selectivity profile. The N‐(1H‐pyrazol‐4‐yl)quinoline‐4‐carboxamides were identified as an excellent starting point for further compound optimization. After extensive structure–activity relationship explorations, single‐digit nanomolar inhibitors with a selectivity factor of >100 against GLUT2, GLUT3, and GLUT4 were obtained. The most promising compound, BAY‐876 [N4‐[1‐(4‐cyanobenzyl)‐5‐methyl‐3‐(trifluoromethyl)‐1H‐pyrazol‐4‐yl]‐7‐fluoroquinoline‐2,4‐dicarboxamide], showed good metabolic stability in vitro and high oral bioavailability in vivo. 相似文献
94.
Christian Immanuel Müller Thomas Rauscher Andreas Schmidt Thomas Schubert Thomas Weißgärber Bernd Kieback Lars Röntzsch 《International Journal of Hydrogen Energy》2014
In this work different amorphous melt-spun Fe-alloys (Fe82B18, Fe80Si10B10, Fe60Co20Si10B10) were investigated as cathode materials for the alkaline electrolysis of water. In particular, the influence of cobalt as well as the metalloids boron and silicon on the activity for the hydrogen evolution reaction (HER) was studied in 1 M KOH at 298 K using cyclic voltammetric, galvanostatic and polarization techniques. The electrocatalytic activity was evaluated in the view of the overpotential. It was found that cyclic voltammetric techniques can be used to activate the melt-spun Fe-alloys strongly. Different cyclic voltammetric activation procedures are discussed and the influence of the sweep rate and the potential window on the HER activity was elucidated. The experimental data indicate that the addition of metalloids and, most importantly, of cobalt improves the HER activity of the materials. Thus, the overpotential can be reduced by 200 mV compared to polycrystalline Ni. 相似文献
95.
Revolute joints in applications always show clearance between pin and bushing due to manufacturing tolerances, the need of relative motion or progressing wear. Many researchers developed and investigated methodologies to calculate the dynamic behavior of mechanisms with such imperfect joints. Very often they use a simple slider-crank mechanism to test or demonstrate the capability of their approaches. In this paper, a methodology for simulating a slider-crank mechanism with an imperfect revolute joint in RecurDyn, a commercial multibody simulation tool, is presented. Therefore, a thorough investigation of existing contact, damping and friction force models as well as different ways of modeling revolute joints in RecurDyn was conducted. For the investigation of the damping models, a special program for calculating the model parameters for a given coefficient of restitution was developed. Only one damping model was capable of reproducing the experimental results, which were found in literature. Some characteristic results of the slider-crank mechanism are presented in a way that they can be compared to results in other papers. Thereby. a good correlation was achieved, demonstrating the capabilities of the methodology. 相似文献
96.
97.
Bernd Garska Monir Tabatabai Urs Fischer Norbert Moszner Andreas Utterodt Helmut Ritter 《Polymer International》2012,61(7):1061-1066
We describe the synthesis of 5,11,17,23‐tetra‐tert‐butyl‐25,27‐dioxypropylphosphonic acid‐26,28‐dimethacryloyloxy‐calix [4]arene and 5,11,17,23‐tetra‐tert‐butyl‐25‐oxypropylphosphonic acid‐27‐hydroxy‐26,28‐dimethacryloyloxy‐calix[4]arene starting from para‐tert‐butyl‐calix[4]arene. The complete reaction was proved by matrix‐assisted laser desorption ionization time of flight mass spectrometry and nuclear magnetic resonance spectroscopy. The influence of these compounds on the kinetics of the radical polymerization of methyl methacrylate was shown by dilatometry. Furthermore, the adhesive properties of dental adhesives containing these calix[4]arene derivatives were investigated. Copyright © 2012 Society of Chemical Industry 相似文献
98.
p‐type TCOs for use in transparent electronics In this article, a new type of semiconducting material is introduced. Transparent conducting thin films are already established in our everydaylife. But the type of these so‐called ?TCOs”? is dominated by electron transport, that means they are n‐type. To get transparent p‐n‐junctions and therefore transparent electronics, the missing part is a transparent p‐type material. Researchers all over the world have found different approach to produce this new generation of materials. At the Fraunhofer Institute for Surface Engineering and Thin Films (IST) in Braunschweig it is now possible to produce these kind of thin films as well. 相似文献
99.
100.
Bernd Propfe Danny Kreyenberg Joerg Wind Stephan Schmid 《International Journal of Hydrogen Energy》2013
There is currently intensive public discussion of fuel cell electric vehicles (FCEV) and other electric powertrains, such as battery electric vehicles (BEV), plug-in hybrid electric vehicles (PHEV) and hybridized combustion engine vehicles (HEV). In this context, the German government has set the target of one million electric vehicles on the road by 2020, and six million by 2030 [1]. The goal of this paper is to identify the possible market share of electric vehicles in the German new car fleet in three scenarios in the timeframe from 2010 to 2030. The VECTOR21 vehicle technology scenario model is used to model the fleet in three scenarios. In the reference scenario with business-as-usual parameters, 189,000 electric vehicles will be sold in Germany by 2020. Scenario two with purchase price incentives from 5000 EUR, high oil prices, and low prices for hydrogen and electricity will result in 727,000 vehicles. In the last scenario with substantial OEM mark-up reductions and external conditions as in the business-as-usual scenario, 3.28 million vehicles will be sold. 相似文献