Substitution reactions are an appropriate way to attach chemical functions to polymer chains for improving properties and to diversify the application of polymer materials. The stereoselective substitution of chlorine atoms affords a useful way to plasticize polyvinychloride (PVC) by attaching appropriate plasticizing functions (ester group) such as isooctylthiosalicylate. Thus, the substitution of chlorine atoms of PVC by reactant bearing plasticizing groups was carried out in a continuous mixing apparatus such as a twin screw extruder. This continuous chemical engineering process taking place in the extruder is studied as the function of the residence time distribution (RTD) measured by a UV method. This function combined with the kinetics of the chemical reaction allows to define a new function G as the distribution of the extent of conversion by analogy with the RTD function. 相似文献
A Cr/Al2O3 alkane dehydrogenation catalyst exhibits a maximum in ethylene yield during an ethane dehydrogenation cycle. Isotopic labelling experiments with monolabelled 13C-ethane and deuterium were used to elucidate whether the initial activity increase could be due to formation of an active, larger hydrocarbon intermediate on the surface. The results strongly indicate that this is not the case, and instead point to a traditional reaction cycle involving adsorption of ethane to form an ethyl species, followed by desorption of ethene and hydrogen. Transient kinetic data suggest that ethane adsorption is the rate-determining step of reaction. 相似文献
S-Net is a declarative coordination language and component technology aimed at radically facilitating software engineering for modern parallel compute systems by near-complete separation of concerns between application (component) engineering and concurrency orchestration. S-Net builds on the concept of stream processing to structure networks of communicating asynchronous components implemented in a conventional (sequential) language. In this paper we present the design, implementation and evaluation of a new and innovative runtime system for S-Net streaming networks. The Front runtime system outperforms the existing implementations of S-Net by orders of magnitude for stress-test benchmarks, significantly reduces runtimes of fully-fledged parallel applications with compute-intensive components and achieves good scalability on our 48-core test system. 相似文献
The prototyping of complex sheet metal parts using single point incremental forming (SPIF) requires the generation of optimal tool paths and/or tool path sequences that ensure that the formed part is within geometric design specifications. The presence of a multitude of features on complex parts leads to multiple inaccuracy inducing phenomena occurring simultaneously due to interactions between the features. This paper proposes a network analysis methodology using topological conceptual graphs to capture the effects of different phenomena on the final accuracy of a sheet metal part manufactured by SPIF. Using this framework optimized tool paths can be generated that compensate for the inaccuracy inducing behavior. Tool path generation algorithms to create partial tool paths that account for the accuracy of specific features in the part based on the proposed framework are also presented. Finally, the creation of integrated tool paths maintaining complementarity between tool paths and desired continuity behavior using non-uniform cubic B-splines is illustrated. A number of case studies demonstrating the applicability of the integrated framework are discussed, where the maximum deviations in the part are significantly reduced and the average absolute deviations for the complete part are brought down to less than 0.5 mm. 相似文献
The rising level of atmospheric CO2 has stimulated several recent studies attempting to predict the effects of increased CO2 on ecological communities. However, most of these studies have been conducted in the benign conditions of the laboratory and in the absence of herbivores. In the current study, we utilized large octagonal chambers, which enclosed portions of an intact scrub-oak community to investigate the interactive effects of CO2 and insect herbivory on myrtle oak, Quercus myrtifolia. Specifically, we assessed the effects of ambient and elevated CO2 (2x current concentrations) on percent foliar nitrogen, C:N ratio, total relative foliar tannin content, and the presence of leaf damage caused by leaf mining and leaf chewing insects that feed on myrtle oak. Total foliar N declined and C:N ratios increased significantly in oaks in elevated CO2 chambers. The percentages of leaves damaged by either leafminers or leaf chewers tended to be lower in elevated compared to ambient chambers, but they co-occurred on leaves less than expected, regardless of CO2 treatment. Leaves that had been either mined or chewed exhibited a similar wounding or defensive response; they had an average of 25 and 21% higher protein binding ability, which is correlated with tannin concentration, compared to nondamaged control leaves, respectively. While the protein-binding ability (expressed as total percent tannin) of leaves from elevated CO2 was slightly higher than from leaves grown in ambient chambers, this difference was not significant. 相似文献
Manic depression, also known as bipolar disorder, is a common and severe form of mental disorder. The European research project MONARCA aims at developing and validating mobile technologies for multi-parametric, long term monitoring of physiological and behavioral information relevant to bipolar disorder. One aspect of MONARCA is to investigate the long term monitoring of Electrodermal activity (EDA) to support the diagnosis and treatment of bipolar disorder patients. EDA is known as an indicator of the emotional state and the stress level of a person. To realize a long-term monitoring of the EDA, the integration of the sensor system in the shoe or sock is a promising approach. This paper presents a first step towards such a sensor system. In a feasibility study including 8 subjects, we investigate the correlation between EDA measurements at the fingers, which is the most established sensing site, with measurements of the EDA at the feet. The results indicate that 88% of the evoked skin conductance responses (SCRs) occur at both sensing sites. When using an action movie as psychophysiologically activating stimulus, we have found weaker reactivity in the foot than in the hand EDA. The results also suggest that the influence of moderate physical activity on EDA measurements is low and has a similar effect for both recording sites. This suggests that the foot recording location is suitable for recordings in daily life even in the presence of moderate movement. 相似文献
We analyze the class of surfaces which are equipped with rational support functions. Any rational support function can be decomposed into a symmetric (even) and an antisymmetric (odd) part. We analyze certain geometric properties of surfaces with odd and even rational support functions. In particular it is shown that odd rational support functions correspond to those rational surfaces which can be equipped with a linear field of normal vectors, which were discussed by Sampoli et al. (Sampoli, M.L., Peternell, M., Jüttler, B., 2006. Rational surfaces with linear normals and their convolutions with rational surfaces. Comput. Aided Geom. Design 23, 179–192). As shown recently, this class of surfaces includes non-developable quadratic triangular Bézier surface patches (Lávička, M., Bastl, B., 2007. Rational hypersurfaces with rational convolutions. Comput. Aided Geom. Design 24, 410–426; Peternell, M., Odehnal, B., 2008. Convolution surfaces of quadratic triangular Bézier surfaces. Comput. Aided Geom. Design 25, 116–129). 相似文献
A multi‐tip scanning tunneling microscope (STM) specifically designed for charge transport measurements at the nanoscale is described. Complementing the instrument with a versatile measurement electronics creates a powerful tool to give insight into fundamental transport properties at the nanoscale. We demonstrate the capabilities of the instrument by measuring resistance profiles along freestanding GaAs nanowires, by the acquisition of nanoscale potential maps, and by the identification of an anisotropy in the surface conductivity at a silicon surface. 相似文献
Profiling of the electrical properties of nanowires (NWs) and NW heterocontacts with high spatial resolution is a challenge for any application and advanced NW device development. For appropriate NW analysis, we have established a four-point prober, which is combined in vacuo with a state-of-the-art vapor-liquid-solid preparation, enabling contamination-free NW characterization with high spatial resolution. With this ultrahigh-vacuum-based multi-tip scanning tunneling microscopy (MT-STM), we obtained the resistance and doping profiles of freestanding NWs, along with surface-sensitive information. Our in-system 4-probe STM approach decreased the detection limit for low dopant concentrations to the depleted case in upright standing NWs, while increasing the spatial resolution and considering radial depletion regions, which may originate from surface changes. Accordingly, the surface potential of oxide-free GaAs NW {112} facets has been estimated to be lower than 20 mV, indicating a NW surface with very low surface state density.
Isogeometric analysis based on non-uniform rational B-splines (NURBS) as basis functions preserves the exact geometry but suffers from the drawback of a rectangular grid of control points in the parameter space, which renders a purely local refinement impossible. This paper demonstrates how this difficulty can be overcome by using T-splines instead. T-splines allow the introduction of so-called T-junctions, which are related to hanging nodes in the standard FEM. Obeying a few straightforward rules, rectangular patches in the parameter space of the T-splines can be subdivided and thus a local refinement becomes feasible while still preserving the exact geometry. Furthermore, it is shown how state-of-the-art a posteriori error estimation techniques can be combined with refinement by T-splines. Numerical examples underline the potential of isogeometric analysis with T-splines and give hints for further developments. 相似文献