全文获取类型
收费全文 | 1093篇 |
免费 | 22篇 |
国内免费 | 9篇 |
专业分类
电工技术 | 10篇 |
综合类 | 1篇 |
化学工业 | 164篇 |
金属工艺 | 14篇 |
机械仪表 | 16篇 |
建筑科学 | 94篇 |
矿业工程 | 29篇 |
能源动力 | 45篇 |
轻工业 | 50篇 |
水利工程 | 5篇 |
石油天然气 | 8篇 |
无线电 | 126篇 |
一般工业技术 | 123篇 |
冶金工业 | 151篇 |
原子能技术 | 6篇 |
自动化技术 | 282篇 |
出版年
2022年 | 6篇 |
2021年 | 10篇 |
2020年 | 7篇 |
2019年 | 15篇 |
2018年 | 14篇 |
2017年 | 16篇 |
2016年 | 16篇 |
2015年 | 15篇 |
2014年 | 18篇 |
2013年 | 92篇 |
2012年 | 43篇 |
2011年 | 38篇 |
2010年 | 27篇 |
2009年 | 37篇 |
2008年 | 42篇 |
2007年 | 55篇 |
2006年 | 57篇 |
2005年 | 59篇 |
2004年 | 54篇 |
2003年 | 53篇 |
2002年 | 34篇 |
2001年 | 34篇 |
2000年 | 35篇 |
1999年 | 32篇 |
1998年 | 38篇 |
1997年 | 26篇 |
1996年 | 29篇 |
1995年 | 21篇 |
1994年 | 22篇 |
1993年 | 11篇 |
1992年 | 7篇 |
1991年 | 14篇 |
1990年 | 6篇 |
1989年 | 12篇 |
1988年 | 5篇 |
1987年 | 10篇 |
1986年 | 8篇 |
1985年 | 19篇 |
1984年 | 10篇 |
1983年 | 9篇 |
1982年 | 8篇 |
1981年 | 9篇 |
1980年 | 5篇 |
1979年 | 12篇 |
1978年 | 5篇 |
1977年 | 5篇 |
1975年 | 3篇 |
1973年 | 4篇 |
1968年 | 4篇 |
1963年 | 3篇 |
排序方式: 共有1124条查询结果,搜索用时 15 毫秒
61.
Crystallization of Polymer-Derived Silicon Carbonitride at 1873 K under Nitrogen Overpressure 总被引:1,自引:0,他引:1
Martin Friess Joachim Bill Jerzy Golczewski re Zimmermann Fritz Aldinger Ralf Riedel Rishi Raj 《Journal of the American Ceramic Society》2002,85(10):2587-2589
The chemical stability of an amorphous silicon carbonitride ceramic, having the composition 0.57SiC·0.43Si3 N4 ·0.49C is studied as a function of nitrogen overpressure at 1873 K. The ceramic suffers a weight loss at p N2 < 3.5 bar (1 bar = 100 kPa), does not show a weight change from 3.5 to 11 bar, and gains weight above 11 bar. The structure of the ceramic changes with pressure: it is crystalline from 1 to 6 bar, amorphous at ∼10 bar, and is crystalline above ∼10 bar. The weight-loss transition, at 3.5 bar, is in excellent agreement with the prediction from thermodynamic analysis when the activities of carbon, SiC, and Si3 N4 are set equal to those of the crystalline forms; this implies that the material crystallizes before decomposition. The amorphous to crystalline transition that occurs at ∼10 bar, and which is accompanied by weight gain, is likely to have taken place by a different mechanism. A nucleation and growth reaction with the atmospheric nitrogen is proposed as the likely mechanism. The supersaturation required to nucleate α-Si3 N4 crystals is calculated to be 30 kJ/mol. 相似文献
62.
Narayanan Janakiraman Markus Weinmann Jörg Schuhmacher Klaus Müller Joachim Bill Fritz Aldinger Paramanand Singh 《Journal of the American Ceramic Society》2002,85(7):1807-1814
Amorphous Si-B-C-N ceramic powder samples obtained by thermolysis of boron-modified polysilazane, {B[C2 H4 Si(H)NH]3 } n , were isothermally annealed at different temperatures (1400–1800°C) and hold times (3, 10, 30, and 100 h). A qualitative and semiquantitative analysis of the crystallization behavior of the materials was performed using X-ray diffraction (XRD). The phase evolution was additionally followed by 11 B and 29 Si MAS NMR as well as by FT-IR spectroscopy in transmission and diffuse reflection (DRIFTS) modes. Bulk chemical analyses of selected samples were performed to determine changes in the chemistry/phase composition of the materials. It was observed that silicon carbide is the first phase to nucleate around 1400–1500°C, whereas silicon nitride nucleates at and above 1700°C. Crystallization accelerates with increasing annealing temperature and proceeds with increasing annealing time. Furthermore, the surface area of the powders strongly influences the thermal stability of silicon nitride and thus controls overall chemical and phase composition of the materials on thermal treatment. 相似文献
63.
Dr. Ryota Hidese Dr. Kenichi Ataka Dr. Eckhard Bill Dr. Seigo Shima 《Chembiochem : a European journal of chemical biology》2015,16(13):1861-1865
[Fe]‐Hydrogenase (Hmd) catalyzes reversible hydride transfer from H2. It harbors an iron‐guanylylpyridinol as a cofactor with an FeII that is ligated to one thiolate, two COs, one acyl‐C, one pyridinol‐N, and solvent. Here, we report that CuI and H2O2 inactivate Hmd (half‐maximal rates at 1 μM CuI and 20 μM H2O2) and that FeII inhibits the enzyme with very high affinity (Ki=40 nM ). Infrared and EPR studies together with competitive inhibition studies with isocyanide indicated that CuI exerts its inhibitory effect most probably by binding to the active site iron‐thiolate ligand. Using the same methods, it was found that H2O2 binds to the active‐site iron at the solvent‐binding site and oxidizes FeII to FeIII. Also it was shown that FeII reversibly binds away from the active site iron, with binding being competitive to the organic hydride acceptor; this inhibition is specific for FeII and is reminiscent of that for the [FeFe]‐hydrogenase second iron, which specifically interacts with H2. 相似文献
64.
Eduardo Di Mauro Matteo Camaggi Nils Vandooren Caleb Bayard Jordan De Angelis Alessandro Pezzella Bill Baloukas Richard Silverwood Abdellah Ajji Christian Pellerin Clara Santato 《Polymer International》2019,68(5):984-991
In the human body, the black‐brown biopigment eumelanin blocks harmful ultraviolet (UV) radiation. In the plastics industry, additives are often added to polymers to increase their UV‐absorption properties. We herein report an assessment of the biopigment eumelanin as a nature‐inspired additive for plastics to enhance their UV absorption. Since eumelanin is produced by natural sources and is nontoxic, it is an interesting candidate in the field of sustainable plastic additives. In this work, the eumelanin‐containing films of commercial ethylene–vinyl acetate copolymer, a plastic used for packaging applications, were obtained by melt compounding and compression molding. The biopigment dispersion in the films was improved by means of the melanin free acid treatment. It was observed that eumelanin amounts as low as 0.8 wt% caused an increase of the UV absorption, up to one order of magnitude in the UVA range. We also evaluated the effect of eumelanin on the thermal stability and photostability of the films: the biopigment proved to be double‐edged, working both as UV‐absorption enhancer and photo‐prooxidant, as thermogravimetric analysis and infrared spectroscopy revealed. © 2019 Society of Chemical Industry 相似文献
65.
Richard B Kreider Colin D Wilborn Lem Taylor Bill Campbell Anthony L Almada Rick Collins Mathew Cooke Conrad P Earnest Mike Greenwood Douglas S Kalman Chad M Kerksick Susan M Kleiner Brian Leutholtz Hector Lopez Lonnie M Lowery Ron Mendel Abbie Smith Marie Spano Robert Wildman Darryn S Willoughby Tim N Ziegenfuss Jose Antonio 《Journal of the International Society of Sports Nutrition》2010,7(1):1-43
Sports nutrition is a constantly evolving field with hundreds of research papers published annually. For this reason, keeping up to date with the literature is often difficult. This paper is a five year update of the sports nutrition review article published as the lead paper to launch the JISSN in 2004 and presents a well-referenced overview of the current state of the science related to how to optimize training and athletic performance through nutrition. More specifically, this paper provides an overview of: 1.) The definitional category of ergogenic aids and dietary supplements; 2.) How dietary supplements are legally regulated; 3.) How to evaluate the scientific merit of nutritional supplements; 4.) General nutritional strategies to optimize performance and enhance recovery; and, 5.) An overview of our current understanding of the ergogenic value of nutrition and dietary supplementation in regards to weight gain, weight loss, and performance enhancement. Our hope is that ISSN members and individuals interested in sports nutrition find this review useful in their daily practice and consultation with their clients. 相似文献
66.
Peter K. Windsor Stephen P. Plassmeyer Dominic S. Mattock Jonathan C. Bradfield Erika Y. Choi Bill R. Miller III Byung Hee Han 《International journal of molecular sciences》2021,22(6)
Deposition of amyloid β (Aβ) fibrils in the brain is a key pathologic hallmark of Alzheimer’s disease. A class of polyphenolic biflavonoids is known to have anti-amyloidogenic effects by inhibiting aggregation of Aβ and promoting disaggregation of Aβ fibrils. In the present study, we further sought to investigate the structural basis of the Aβ disaggregating activity of biflavonoids and their interactions at the atomic level. A thioflavin T (ThT) fluorescence assay revealed that amentoflavone-type biflavonoids promote disaggregation of Aβ fibrils with varying potency due to specific structural differences. The computational analysis herein provides the first atomistic details for the mechanism of Aβ disaggregation by biflavonoids. Molecular docking analysis showed that biflavonoids preferentially bind to the aromatic-rich, partially ordered N-termini of Aβ fibril via the π–π interactions. Moreover, docking scores correlate well with the ThT EC50 values. Molecular dynamic simulations revealed that biflavonoids decrease the content of β-sheet in Aβ fibril in a structure-dependent manner. Hydrogen bond analysis further supported that the substitution of hydroxyl groups capable of hydrogen bond formation at two positions on the biflavonoid scaffold leads to significantly disaggregation of Aβ fibrils. Taken together, our data indicate that biflavonoids promote disaggregation of Aβ fibrils due to their ability to disrupt the fibril structure, suggesting biflavonoids as a lead class of compounds to develop a therapeutic agent for Alzheimer’s disease. 相似文献
67.
Mootaz M. Salman Zaid Al-Obaidi Philip Kitchen Andrea Loreto Roslyn M. Bill Richard Wade-Martins 《International journal of molecular sciences》2021,22(9)
Neurodegenerative diseases (NDs) including Alzheimer’s disease, Parkinson’s disease, amyotrophic lateral sclerosis, and Huntington’s disease are incurable and affect millions of people worldwide. The development of treatments for this unmet clinical need is a major global research challenge. Computer-aided drug design (CADD) methods minimize the huge number of ligands that could be screened in biological assays, reducing the cost, time, and effort required to develop new drugs. In this review, we provide an introduction to CADD and examine the progress in applying CADD and other molecular docking studies to NDs. We provide an updated overview of potential therapeutic targets for various NDs and discuss some of the advantages and disadvantages of these tools. 相似文献
68.
Nataraj Nandita Adam Elisabeth Hansson Bill S. Knaden Markus 《Journal of chemical ecology》2021,47(12):1042-1048
Journal of Chemical Ecology - Many pollinating insects exhibit flower constancy, i.e. they target flower species they have already experienced and fed from. While the insects might profit from... 相似文献
69.
Sorour Alotaibi Mihir Sen Bill Goodwine K. T. Yang 《Numerical Heat Transfer, Part A: Applications》2013,63(3):229-244
The temperature control of outlet air by changing the water flow rate in a single-pass waterto-air cross-flow heat exchanger is investigated. The conservation laws are applied to finite control volumes and an implicit formulation is used for transient numerical solutions. Conjugate forced convection heat transfer from the tube is solved to calculate the temperatures of the air and water coming out of the heat exchanger. In the simulations the outlet air temperature is controlled by changing the water flow rate entering the heat exchanger using a proportional-integral (PI) controller. The range of controllability of the heat exchanger was studied first. Then disturbances in the form of step changes in the inlet air temperature, the air flow rate, and the set point temperature were separately introduced. The effects of the limiting-condition constraints and different control parameters on controlling the outlet air temperature are presented. The results show that the control behavior can be simulated numerically and that this control methodology is effective within limits. 相似文献
70.
Induced seismicity associated with Enhanced Geothermal Systems 总被引:2,自引:0,他引:2
Ernest L. Majer Roy Baria Mitch Stark Stephen Oates Julian Bommer Bill Smith Hiroshi Asanuma 《Geothermics》2007
Enhanced Geothermal Systems (EGS) have the potential to make a significant contribution to the world energy inventory. One controversial issue associated with EGS, however, is the impact of induced seismicity or microseismicity, which has been the cause of delays and threatened cancellation of at least two EGS projects worldwide. Although microseismicity has in fact had few (or no) adverse physical effects on operations or on surrounding communities, there remains public concern over the amount and magnitude of the seismicity associated with current and future EGS operations. The primary objectives of this paper are to present an up-to-date review of what is already known about the seismicity induced during the creation and operation of EGS, and of the gaps in our knowledge that, once addressed, should lead to an improved understanding of the mechanisms generating the events. Several case histories also illustrate a number of technical and public acceptance issues. We conclude that EGS-induced seismicity need not pose a threat to the development of geothermal energy resources if site selection is carried out properly, community issues are handled adequately and operators understand the underlying mechanisms causing the events. Induced seismicity could indeed prove beneficial, in that it can be used to monitor the effectiveness of EGS operations and shed light on geothermal reservoir processes. 相似文献