时间戳服务在信息系统审计的研究应用

联网审计后,审计的审计线索由原来纸质的资料转为为计算机的电子数据,电子数据存在被篡改或伪造的可能,不能确保其真实性和可靠性,本文研究的是在被审计单位原始数据生成时,采用时间戳服务对其实时签名,来保证电子数据的真实性和可靠性。     

个人剂量无线监测装置的研制

本文提出了一种基于无线功能的个人剂量核辐射监测.旨在对辐射工作区域的工作人员提供辐射剂量的实时监测.该系统采用射频通信传输技术,将工二人所受的辐射剂量、剂量率和受照时间等数据发送至监控中心,以方便自动数据存储和分析.同时及时有效的预警,可避免工作人员超剂量受照的风险,对辐射环境卫生领域的深入研究也有重要的参考价值.     

Controllable Fabrication of Co3−xMnxO4 with Tunable External Co3+/Co2+ Ratio for Promoted Oxygen Reduction Reaction

Co_3?xMn_xO₄ is a bimetal oxide with excellent electrochemical activity in alkaline solution, has been regarded as a promising alternative in the field of ion-air batteries and proton exchange membrane fuel cell (PEMFC). Herein, we report a simple solvothermal-calcination method to fabricate Co_3?xMn_xO₄ with tunable external Co³⁺/Co²⁺ and Mn³⁺/Mn²⁺ ratio. The tunable ratio of element valence in the bimetal results in a higher exposure of active center for oxygen redox reaction (ORR), and thus lead to a better ORR activity, which was confirmed by X-ray photoelectron spectroscopy characterizations and electrochemical measurements. Specially, Co_1.8Mn_1.2O₄ with a Co³⁺/Co²⁺ ratio of 2.08 showed an overpotential of 0.37 V at benchmark ORR current density of 3 mA/cm² in 0.1 M KOH, which is lower than that of pure oxide (Mn₃O₄ 0.53 V and Co3O4 0.56 V). In addition, the as prepared Co_1.8Mn_1.2O₄ exhibited a positive half-wave potential (0.83 V vs RHE) due to their more active sites, promotes charge transfer, adsorption and desorption of oxygen species. This work provides a strategy for the design and fabrication of earth-abundant, low-cost electrocatalysts for PEMFC in practical applications.

Graphic Abstract

Co_3?xMn_xO₄ was fabricated by tuning external Co³⁺/Co²⁺ and Mn³⁺/Mn²⁺ ratio, and the activity initially shows a positive correlation with the ration of Co³⁺/Co²⁺ in Co_3?xMn_xO₄.

     

CaO-SiO2系玻璃的析晶动力学研究

利用溶胶-凝胶法制得CaO-SiO2系基础玻璃,通过差热分析曲线分析质量比为CaO-SiO2玻璃的析晶能力。经分析,其析晶活化能E=457.1kJ·mol-1,而晶化生长指数是随升温速率的不同而不同,速率越大,晶化生长指数越小。     

基于STL文件的Laplacian网格优化算法

针对直接重构得到且以STL文件格式存储的网格模型质量不高的问题, 提出了一种基于Laplacian坐标的网格模型全局优化算法。该算法在提高三角面片质量的同时可以很好地保持原网格模型的局部几何特征, 其核心思想是通过在最小二乘意义下求解由权重控制的包含顶点位置和拉普拉斯坐标双重约束的线性系统来对网格顶点进行重新定位。从实验结果可以看出, 该算法较以往的Lapacian优化算法在对网格细节特征的保持上有一定优势。     

幂律流体三维脉动流场数值模拟

利用ANSYS软件，模拟了振动诱导单螺杆挤出机熔体输送段中非牛顿幂律流体的三维脉动流场，得到了三维脉动流场的瞬时速度分布及螺槽中物料的流动轨迹。结果表明，在脉动流场作用下，非牛顿流体的瞬时速度响应与在驱动壁面上所施加的正弦形式的脉动驱动形式不同，横螺槽方向的环流中心位置受幂律指数影响，且发生周期性改变。振动的引入使得在相同的时间内，物料的流动路程增加，且可增大物料的平均停留时间，有利于改善混合效果。     

Exothermic effect in the process of electron‐beam curing of epoxy resins

Temperature measurements have been performed in the process of electron‐beam curing of EB‐I and EB‐II epoxy resin systems. The influence of initiator content, resin type, and dose rate on the temperature of the systems was studied. Transverse and longitudinal temperatures of samples in the glass vessel were also analyzed. The nature of temperature curves varied with the different epoxy resin systems in the steel mold, but did not change with different contents of the initiator. At the same time, the heat had no effect on the gel fraction of epoxy resin systems. The temperature curve was greatly affected by the dose rate, and its peak value, peak width, and plateau value also increased with it. The transverse temperature of EB‐II glass vessel samples increased as the radiation dose increased and, in the same sample, the temperature reduced as the distance between the radiation center and the test point increased. The longitudinal temperature of EB‐I and EB‐II resin systems in a glass vessel decreased as the radiation depth increased. As the radiation dose increased, the temperature of the EB‐I resin system increased simultaneously, while that of the EB‐II resin system initially increased and then kept constant when the dose reached a certain value. The temperatures of these two resin systems decreased rapidly when the radiation process stopped. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2217–2222, 2004     

癫痫脑电的递归确定性分析

利用排序递归图的分析方法对癫痫脑电进行了确定性(DET)的分析,得出癫痫头皮脑电(EEG)的DET高于健康EEG。DET特征的差异性在局部导联上更明显,局部导联的DET特征可以作为癫痫疾病的自动诊断特征。通过分析发作阶段和发作间隙皮层脑电(ECoG)的DET,得出整个频带的DET差别不大,而在beta频带,发作阶段的确定性明显高于发作间隙的DET。Beta频带的DET特征可以作为癫痫发作的预测特征。研究结果为癫痫疾病的自动诊断和癫痫发作预测提供了理论依据。     

Low-pressure CO2 sorption in ammonium-based poly(ionic liquid)s

Ammonium-based ionic liquid monomers and their corresponding polymers [poly(ionic liquid)s] are synthesized and characterized for CO₂ sorption. The polymers have much higher CO₂ sorption capacities than the room-temperature ionic liquids and imidazolium-based poly(ionic liquid)s. For example, P[VBTMA][PF₆] with polystyrene backbone has a CO₂ sorption capacity of 10.67 mol%. The CO₂ sorption is selective over N₂ and O₂. The effects of cation, backbone, substituent, anion and crosslinking on CO₂ sorption are discussed. The sorption mechanism study indicates that CO₂ sorption by the poly(ionic liquid)s is a bulk and surface phenomenon.     

基于改进混沌扩频序列的多用户混沌扩频通信系统的研究与仿真

提出一种改进混沌扩频序列,并将其应用在多用户混沌扩频通信系统中,给出了多用户混沌扩频通信系统的理论推导和SIMULINK仿真模型。对该系统进行了详细的性能分析,包括信噪比、用户数、改进混沌扩频序列的分形参数和初始值等各自对系统误码率的影响,并比较了改进混沌扩频序列与传统混沌扩频序列的系统误码率随信噪比和用户数的变化情况。结果表明改进混沌扩频序列要好于传统混沌扩频序列的系统误码率,具有较好的抗噪声和抗多址干扰的能力。