首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   200235篇
  免费   18322篇
  国内免费   9910篇
电工技术   13137篇
技术理论   14篇
综合类   13745篇
化学工业   31904篇
金属工艺   11445篇
机械仪表   13017篇
建筑科学   15570篇
矿业工程   6210篇
能源动力   5905篇
轻工业   14125篇
水利工程   3914篇
石油天然气   11581篇
武器工业   1769篇
无线电   24070篇
一般工业技术   23205篇
冶金工业   9390篇
原子能技术   2334篇
自动化技术   27132篇
  2024年   756篇
  2023年   3506篇
  2022年   6471篇
  2021年   9289篇
  2020年   6932篇
  2019年   5484篇
  2018年   6231篇
  2017年   6978篇
  2016年   6246篇
  2015年   8562篇
  2014年   10600篇
  2013年   12716篇
  2012年   14048篇
  2011年   14778篇
  2010年   12771篇
  2009年   12093篇
  2008年   11719篇
  2007年   10818篇
  2006年   10812篇
  2005年   9220篇
  2004年   6243篇
  2003年   5198篇
  2002年   4796篇
  2001年   4240篇
  2000年   4024篇
  1999年   4468篇
  1998年   3624篇
  1997年   3067篇
  1996年   2845篇
  1995年   2296篇
  1994年   1847篇
  1993年   1321篇
  1992年   1079篇
  1991年   798篇
  1990年   586篇
  1989年   477篇
  1988年   377篇
  1987年   244篇
  1986年   202篇
  1985年   125篇
  1984年   109篇
  1983年   79篇
  1982年   83篇
  1981年   68篇
  1980年   66篇
  1979年   32篇
  1978年   25篇
  1977年   26篇
  1976年   29篇
  1975年   16篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
集中供热优化节能自动控制系统的特点   总被引:1,自引:0,他引:1  
国家十一五规划中明确指出:五年内节能20%。根据供热系统耗能比重和现状,集中供热的节能潜力非常大。安装优化节能集中供热控制系统,并依此提高运行管理水平,可取得事半功倍的节能效果。基于多年持久的调查、研究、试验、产品开发和实际应用,我们体会到:只有从集中供热的特点出发,才能使集中供热控制系统既可靠又简单、价低,达到既确保人体舒适又真正节能的目标。本文将对集中供热优化节能控制系统在热力学模型、计算机控制方案、节能效果、可靠性和软硬件选择原则等方面的特点进行介绍。  相似文献   
992.
A Single-Die 124 dB Stereo Audio Delta-Sigma ADC With 111 dB THD   总被引:1,自引:0,他引:1  
This paper presents a highly power-efficient stereo delta-sigma ADC designed for high-precision applications, with measured inter-channel isolation over 130 dB. This design adopts a single-loop, fifth-order, 33 level analog modulator with positive and negative feedforward paths. An interpolated multilevel quantizer with unevenly weighted quantization levels replaces a conventional 5-bit flash type quantizer. These new techniques suppress signal dependent energy inside the delta-sigma loop, reduce internal channel coupling and power consumption. Manufactured in 0.35 mum double poly, three metal CMOS process, the single-die chip includes two analog modulators, on-chip bandgap reference circuit, decimation filter and serial interface circuits. The core die area is around 14.8 mm2. The ADC achieves 124 dB dynamic range (A-weighted), -111 dB THD over 20 kHz bandwidth. Total power consumption is less than 330 mW.  相似文献   
993.
超低碳奥氏体不锈钢00Cr18Ni10还原脱磷研究   总被引:1,自引:0,他引:1  
在 2 5kg真空感应炉上用镁钙合金对超低碳奥氏体不锈钢 0 0Cr18Ni10进行了还原脱磷试验。通过充入工业纯氩使炉内压力为 6 6 .6 6kPa和精炼时的反应温度 14 5 0~ 15 0 0℃ ,加入镁钙合金 5 0kg t和助熔剂CaF2 11kg t,可使精炼后 0 0Cr18Ni10的磷含量进一步降低到 (5 0~ 6 0 )× 10 - 6 ,钢中氧、硫含量分别稳定降到(4~ 6 )× 10 - 6 和 15× 10 - 6 。  相似文献   
994.
A thin film of poly(l-serine) was prepared via electropolymerization for the determination of trace levels of estradiol. In pH 5.0 phosphate buffer, l-serine was oxidized during the cyclic potential sweeps between −0.60 and 2.0 V, forming a thin film at the electrode surface. The electrochemical behavior of estradiol was investigated. The oxidation peak potential of estradiol shifts negatively at the poly(l-serine) film-coated glassy carbon electrode (GCE) compared with that at the bare GCE. Otherwise, the oxidation peak current greatly increases at the poly(l-serine) film-modified GCE. These phenomena suggest that the poly(l-serine) film exhibits catalytic activity towards the electrochemical oxidation of estradiol. Based on this, a sensitive, rapid and simple electrochemical method was proposed for the determination of estradiol. The limit of detection is evaluated to be 2.0 × 10−8 mol L−1. Finally, this method was successfully used to determine estradiol in blood serum.  相似文献   
995.
The long‐term thermal‐oxidative aging behavior of polyamide 6 (PA6) was studied by comparison with the stabilized sample in this work. The variation of mechanical properties of the pure and the stabilized samples of PA6 with aging time at 110°C, 130°C, and 150°C were investigated, respectively. The aging mechanism of PA6 under heat and oxygen was studied in terms of the reduced viscosity, crystallization behavior, dynamic mechanical behavior, and chemical composition through the methods of polarized light microscopy (PLM), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), X‐ray photoelectron energy spectrum (XPS), and so on. The results indicated that at the initial stage of aging, the molecular crosslinking reaction of PA6 dominated resulting in the increase of the mechanical strength, reduced viscosity, and the glass transition temperature of the sample. And the molecular degradation dominated in the subsequent aging process resulting in the decrease of the melting temperature, the increase of the crystallinity, and the formation of the oxides and peroxides products. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008  相似文献   
996.
Biphenol monoacrylate (AL) was combined with a traditional hindered phenolic‐based binary antioxidant system to form a ternary stabilization system for the purpose of further improving the thermal–oxidative stability of polyamide 6 (PA6). The thermal stabilization effect of the antioxidant AL on PA6 was studied in terms of the reduced viscosity, the chemical structure, the yellow index, and the mechanical properties. The results showed that the antioxidant AL, with the proper chemical structure, could improve the thermal stability of PA6 effectively through a unique bifunctional stabilizing mechanism. The interaction of the molecules of PA6 with the antioxidant AL was investigated. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008  相似文献   
997.
Environmentally responsive hydrogels have become attractive research subjects for many applications. In this work, a series of pH‐sensitive and color‐changing nanoparticles (nanogels) with core–shell structures were synthesized. The cores were blue latex particles synthesized by a miniemulsion technique with styrene and methacrylic acid as monomers and Neozapon Blue 807 as a dye. The shell was a pH‐sensitive polymer that was precipitation‐polymerized onto the core from 2‐(diethylamino) ethyl methacrylate with N,N′‐methylenebisacrylamide, poly(propylene glycol) diacrylate, and divinylbenzene as crosslinking agents. In the resultant latexes, the color was observed to change from deep blue to pale blue as the pH of the system was changed from a high of 10 to a low of 3. The synthesized latexes and particles (gels) were then characterized with an ultraviolet–visible spectrometer, dynamic light scattering, Fourier transform infrared, and nuclear magnetic resonance. Atomic force microscopy was also used to investigate the different morphologies of the particles after the synthesized latexes were dried at different pH values. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008  相似文献   
998.
Using nickel-2,2′-dipyridyl complex as a template, N-vinyl-2-pyrrolidone as the metal coordination functional monomer, and ethylene glycol dimethacrylate as the crosslinker, polyvinylidene fluoride (PVDF) hollow fiber ultrafiltration membrane as the supported membrane, metal complex imprinted polymeric membranes were prepared. The association constant of template-monomer interaction in the prepolymerization solution was estimated to be 4.38 × 104 (L/mol)2 by spectrophotometric titration analysis. The attenuated total reflection Fourier transform infrared spectroscopy and scanning electron micrograph characterization indicated that the surface of the support PVDF membrane was completely coated by the imprinted polymer layer after modification. The imprinted membranes exhibited the selective permeability for the template in certain nickel acetate solution. The molecularly imprinted membranes gave higher permeation separation factors at about pH 6, whereas increasing pressure would lower the separation ability. The effects of ion concentration, cations and counterions, ligand selectivity, pH, and trans-membrane pressure were investigated and the permeation performances of the imprinted membranes could be regarded as facilitated transport mechanism. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008  相似文献   
999.
A method for the synthesis of novel sulfated ionomer of styrene–butadiene–styrene triblock copolymer (SBS) was developed. SBS was first epoxidized by performic acid in the presence of a phase‐transfer catalyst; this was followed by a ring‐opening reaction with an aqueous solution of alkali salt of bisulfate. The optimum conditions for the ring‐opening reaction of the epoxidized SBS with an aqueous solution of KHSO4 were studied. During the ring‐opening reaction, both phase‐transfer catalyst and ring‐opening catalyst were necessary to enhance the conversion of epoxy groups to ionic groups. The products were characterized with Fourier transform infrared spectrophotometry and transmission electron microscopy (TEM). After the potassium ions of the ionomer were substituted with lead ions, the lead sulfated ionomer exhibited dark spots under TEM. Some properties of the sulfated ionomer were studied. With increasing ionic groups or ionic potential of the cations, the water absorbency and emulsifying volume of the ionomer and the intrinsic viscosity of the ionomer solution increased, whereas the oil absorbency decreased. The sulfated ionomer possessed excellent emulsifying properties compared with the sulfonated SBS ionomer. The sodium sulfated ionomers in the presence of 10% zinc stearate showed better mechanical properties than the original SBS. When the ionomer was blended with crystalline polypropylene, a synergistic effect occurred with respect to the tensile strength. The ionomer behaved as a compatibilizer for blending equal amounts of SBS and oil‐resistant chlorohydrin rubber. In the presence of 3% ionomer, the blend exhibited much better mechanical properties and solvent resistance than the blend without the ionomer. SEM photographs indicated improved compatibility between the two components of the blend in the presence of the ionomer. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008  相似文献   
1000.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号