一种用于气液间传质的新型轴流式叶轮

一种用于气液间传质的新型轴流式叶轮黄庆民林齐浩李启恩（华南理工大学化学工程研究所，广州５１０６４１）关键词气液传质轴流式叶轮１前言在液体搅拌器中，轴流式叶轮由于功耗较小且泵吸量较大而被广泛采用。在气液两相搅拌器中，由于轴流式叶轮有气泛问题，一般均采...     

水煤浆在燃油热水锅炉内的燃烧试验

主要介绍了７ＭＷ燃油热水锅炉改烧水煤浆的改造设计，水煤浆炉前系统的调试，锅炉改造后的调试和水煤浆燃烧试验的结果。     

Dehydrogenation and aromatization of methane under non-oxidizing conditions

The dehydrogenation and aromatization of methane on modified ZSM-5 zeolite catalysts has been studied under non-oxidizing conditions with a fixed bed continuous-flow reactor and with a temperature programmed reactor. The results show that benzene is the only hydrocarbon product of the catalytic conversion of methane at high temperature (973 K). The catalytic activity of ZSM-5 is greatly improved by incorporating a metal cation (Mo or Zn). H₂ and ethene have been directly detected in the products with a mass spectrometer during TPAR. A carbenium ion mechanism for the activation of methane is suggested.     

我国石油企业海外拓展亟待实行现金统一管理

分析了我国石油企业海外资金运营管理方面存在的问题，提出了改进海外项目现金管理的几点措施。     

数显仪表在生产中的抗干扰措施探讨

着重分析了在生产中使用数显仪表干扰产生的原因，列举了抗干扰的措施和在生产实践中取得的成绩。     

Cu-HMS分子筛的合成及其表征

以十二胺为模板剂、正硅酸乙酯为硅源，在中性介质中于25℃下合成了含Cu的中孔杂原子分子筛Cu—HMS。用XRD、FT—IR、UV—Vis、XPS、^29SiMAS NMR、低温N2吸附等手段对分子筛结构及表面性能进行了表征。结果表明，Cu进入分子筛的骨架结构并以Cu^2 的形式存在。在常压85℃下，以Cu—HMS为催化剂、纯O2为氧化剂，对异丙苯的催化氧化反应进行了研究，结果表明Cu—HMS是一种很好的洁净氧化催化剂。     

环保聚糖树脂技术在醇酸涂料中的应用

<正>0引言中国涂料市场潜力巨大,近年来外资企业在华建厂占据了涂料中高端产品的一大部分市场,而中国本土一大部分企业所生产的通用溶剂型装饰漆则占据了涂料市场相当大的比例,其中醇酸漆就是一大类,市场需求量大。但化工原料价格连年攀升,尤其是有机溶剂石油产品,致使中国涂料厂商面临利润空间缩小     

A ratiometric fluorescent sensor for zinc(II) with high selectivity

Spectroscopic studies revealed that the compound [N,N′-di(quinoline-2-methylene) -1,2-phenylenediimine] (1) exhibited a rather high selectivity toward Zn²⁺ over other metal ions, even Cd²⁺. In acetonitrile, the red shift of fluorescent emission from 396 nm to 426 nm upon zinc binding is due to the formation of a 1:1 metal/ligand complex.     

Aerosol deposition of dense lead zirconate titanate thin films at room temperature

Lead zirconate titanate (Pb(Zr,Ti)O₃, PZT) films were grown on silicon 1 0 0 substrate by aerosol deposition, using solid-state reacted powder containing donor oxide Nb₂O₅, while the substrate was maintained at room temperature. The PZT films were simultaneously sintered upon deposition on a highly densified ceramic layer. Crystalline phases of the deposited films have been determined by X-ray diffractometry (XRD), and microstructures analysed by transmission electron microscopy (TEM). The cross-section microstructure consisted of several thin layers, including the PZT film and the platinum electrode and titanium-buffered layers on the substrate. High-resolution images revealed that the PZT layer contained a mixture of randomly oriented grains of nanometre size, which were embedded in an amorphous matrix. In contrast to the conventional liquid-phase sintering mechanism, sintering of the PZT films involved amorphised phases generated by pressure-induced amorphisation (PIA) from plastic deformation when the initial powder particles collided amongst one another upon reaching the silicon substrate during aerosol deposition. An analogy may be drawn to the impact of extraterrestrial meteorites in which diaplectic glass, i.e., amorphised phase, was formed and retained metastably at room temperature. The individual PZT grains were joined with the amorphised phase(s) and sintered to become a dense, thin film on the silicon substrate.     

基于软件定义网络和移动边缘计算的车联网高效任务卸载方案

随着车联网(IoV)中车辆和智能应用数目的增加使计算密集型任务激增,传统架构难以满足用户需求。为解决车联网计算资源不足且分配不均匀、应用时延需求无法满足、任务能耗成本较高的问题,结合移动边缘计算(MEC)和软件定义网络(SDN),设计了一种从宏基站到MEC服务器到车辆的车联网架构中的高效任务卸载方案,并提出一种改进的低复杂度非支配排序遗传算法,优化任务卸载成本和MEC服务器的负载均衡率。实验仿真结果表明,相比于随机卸载,NO-MEC卸载,NO-I卸载,传统NSGA、NSGA-Ⅱ卸载,GA卸载,Q-learning卸载,DQN卸载方案,所提方案有着更低的卸载成本,更优的负载均衡率,得到近似最高的系统效用,能够给车联网中的车辆用户带来更优质的网络服务。