Controlling properties of acrylate/epoxy interpenetrating polymer networks by premature termination of radical polymerization of acrylate

An approach is presented to control properties of sequentially synthesized acrylate/epoxy interpenetrating polymer networks (IPNs) and is used to print uniform and graded properties. These IPNs are constructed by partial formation of the acrylate network, removal of the excess components, expansion with the epoxy system, and curing. The partial crosslinking of the initial network is controlled by photo polymerization and used to manipulate the final properties. The process is used to print homogeneous and graded IPNs with properties in the range of 10 to 1000 MPa. The curing of acrylate, the control mechanism, is studied by Fourier Transform Infrared Spectroscopy (FTIR) during curing on a temperature and environment controlled attenuated total reflection system. Fast scanning calorimetry is used to study network formation, nanoindentation is used to characterize local change of modulus, and uniaxial tensile testing is used to characterize stress response of the printed systems. POLYM. ENG. SCI., 59:1729–1738 2019. © 2019 Society of Plastics Engineers     

水库大坝安全信息三维可视化系统开发

利用网络、三维地理信息系统、数据库、虚拟仿真以及OpenGL等技术,结合水利工程及大坝安全监控专业知识,以水库大坝枢纽工程为对象,开发了水库大坝安全信息三维可视化系统。通过与水库大坝实时安全监控综合数据库连接,将水库场景、枢纽结构和大坝安全信息及分析成果等以图像、文字、表格等多种方式实时、动态、直观地展现,实现枢纽结构及大坝安全信息的数字化和可视化。     

基于整车系统的动力电池包底部碰撞安全性试验研究

为提升电动汽车的行车安全性,揭示电动汽车车用动力电池包底部在机械滥用下的力学特征及行为特点,对电池包底部碰撞工况进行事故统计分析,设计了一种整车工况下电池包底部机械滥用的碰撞测试方案,探索电池包底部机械滥用过程中电池电压及结构等变化.结果表明:新能源汽车动力电池底部与障碍物作用过程为跳跃式接触,变形模式为锯齿波式;试验...     

煤岩孔裂隙结构分形特征及渗透率模型研究

为探究煤岩孔裂隙结构与渗透特性的联动关系,采用扫描电镜、偏光和分形等手段分析煤岩孔裂隙结构分布特征,利用自主研发的出口端正压三轴渗流装置,开展恒定有效应力条件下孔隙压力升高的渗流试验。基于分形理论,考虑煤岩表面孔隙分布情况对煤岩渗透率的影响机理,建立考虑孔裂隙分形特征的煤岩渗透率模型,通过试验验证其合理性,对煤岩孔裂隙下分形维数和渗透率耦合进行定量分析。研究结果表明:①六盘水矿区煤岩表面含有一定数量的孔隙和裂隙,其中四角田7号煤层孔裂隙发育情况最好,具有2条清晰的宽度较大的裂隙,并伴有大量交叉微裂隙及孔隙发育,煤岩结构破坏严重;②通过盒维数法可得煤岩孔裂隙分布具有明显的分形特征,且煤岩孔隙率与分形维数呈正相关关系;③恒定有效应力条件下,煤岩渗透率随孔隙压力升高呈现先急剧降低后趋于平缓的趋势,受孔裂隙结构影响,在相同的孔隙压力下煤岩渗透率存在明显差异。煤岩表面孔裂隙结构越复杂其分形维数越大,有助于瓦斯运移,渗透率呈上升趋势;④考虑孔裂隙分形特征的煤岩渗透率模型计算值与实测值吻合度较高,与前人研究成果相比,无论理论机理的适用性还是对试验点的匹配方面都更加适用,且能较好地反映孔隙压力与渗透率的联动关系。     

PDSOI NMOS器件激光模拟光电流效应

为获得N型金属氧化物半导体(NMOS)器件在γ射线辐照条件下的光电流特性,采用激光模拟技术,利用部分耗尽型绝缘体上硅(PDSOI)工艺NMOS器件进行激光照射试验,获得不同尺寸和拓扑结构器件在激光照射条件下光电流和激光入射能量之间的关系.利用TCAD仿真工具进行器件的光电流仿真,对比TCAD仿真与激光模拟试验数据,两组...     

掺杂Ce对Pd-Co/Cu-Co-Mn混合氧化物催化体系氧化羰基化法合成碳酸二苯酯

Effect of doping cerium in the support on the catalytic activity and side product of the reaction in the oxidative carbonylation of phenol to diphenyl carbonate (DPC) over the catalyst Pd-Co/Cu-Co-Mn mixed oxides was studied. The specific surface areas, crystal phase, valency, and content of the element on the surface of the catalysts were determined, and the products were detected by gas chromatograph/mass spectrometry (GC-MS). It is found that the catalyst without Ce shows higher activity than that with Ce, and the yields of DPC for the two catalysts can reach 30% and 23%, respectively. However, doping cerium can prevent the formation of 2-hydroxyphenyl benzoate and p-bromophenyl phenyl carbonate.     

随行振动胶塞用芳纶纤维布复合材料的制备及摩擦磨损性能

针对石油钻井中使用的随行振动胶塞与套管、岩石摩擦磨损较大的问题,提出采用芳纶纤维布复合材料来增强随行振动胶塞的耐磨性。根据Bnierley经验公式法试织出6种不同经纬密度的试样织品,借助万能磨耗机试验研究织物不同经纬密度和不同摩擦转速对芳纶纤维布复合材料耐磨性的影响。结果表明:摩擦转速一定的条件下,织物经纬密度越大,芳纶纤维布耐磨性越好;织物经纬密度相同的条件下,在一定摩擦转速范围内,芳纶纤维布耐磨性随着摩擦转速的提高而增强,但当摩擦转速过高时芳纶纤维布的耐磨性会出现下降趋势。     

Some observations on orderly development in an emerging city

Recent expression on the differences and similarities between cities in developed and emerging nations has perpetuated the notion that rural-urban migrants simply wander into cities of developing countries without purpose and that their pattern of settlement is unsystematic, and furthermore that they have little chance of significantly improving their economic status. This paper undertakes to determine whether some order is apparent in Accra, Ghana--an emerging city that is perhaps typical of other expanding cities in developing countries.Analysis of population density gradient and upward mobility among the masses, and employment of regression analysis are used to establish whether order exists in Accra's development process. The results indicate that settlement patterns appear to be in accordance with patterns observed in developed nations and upward mobility in the city appears to be substantial.This paper is based on chapters 6, 7, and 8 of the author's doctoral dissertation. The author is indebted to Professor Frank Mittelbach for helpful suggestions and comments. The research reported herein was undertaken by the author while conducting a study of urban land use and residential consumption in Accra, Ghana. During that time, he was a Research Fellow in the Department of Economics, University of Ghana, Legon. The research was supported by grants from the United Nations Association of the United States of America (Ralph Bunche Fellowship), African-American Scholars Council, American Institute of Real Estate Appraisers, UCLA Graduate Student Patent Fund, and the UCLA Graduate Advancement Program.     

泥质岩在不同pH值溶液中的崩解特性试验研究

为了研究泥质岩在不同pH值溶液中的崩解特性,为酸雨地区泥质岩的利用提供理论依据和技术指导,选取阜新海州露天矿泥质岩为例,进行室内浸水崩解试验。对泥质岩在不同pH值溶液中的崩解现象、崩解物的颗粒含量和崩解比进行分析、利用X射线衍射(XRD)、荧光光谱分析,测试岩样矿物化学成分。试验得到以下结论:不同pH值溶液中崩解强度大小关系是:酸>碱>中性;随着循环的进行,泥质岩的崩解程度不断加深,崩解速度先增大后逐渐减小甚至消失;泥质岩中许多不能溶于水的矿物成分可以和酸发生化学反应生成可溶性盐类,是泥质岩在酸中崩解最剧烈的主要原因;考虑泥质岩所处环境pH值不同对工程建设有重要意义。     

舰艇编队防空目标分配优化算法研究

针对所要解决的舰艇编队防空目标分配问题,文章结合现代防空作战特点,建立了防空目标分配模型,并讨论了数学模型的求解问题。对模拟退火算法、遗传算法、禁忌搜索算法进行了分析和研究,运用MATLAB软件编程仿真来解决所建立的防空目标分配模型。研究表明,禁忌搜索算法每次都能以100%的概率搜索到全局最优解,但由于其搜索时间过长而且搜索时间的随机性太强,不适用于解决战时的目标分配问题。而模拟退火算法和遗传算法则可以在较短的时间内达到较高的搜索概率,在实际运用中,应根据所限定时间的不同来对这两种算法进行选择使用。另外,从程序的复杂度上来看,模拟退火算法的程序相对较为简单,而遗传算法的程序相对较为复杂。