Synthesis and characterization of soluble aromatic azopolyamides containing sulfone and ether units

A series of new polyamides 3a–d containing aryl-azo, ether and sulfone groups in the main chain were synthesized from bis[4-(4-aminophenoxy)phenyl sulfone] 1 and several azo aromatic diacyl chlorides 2a–d by the low temperature solution polycondensation technique. FTIR spectroscopy, nuclear magnetic resonance (NMR) and elemental analyses confirmed the structure of these polymers. Owing to the aryl and amide groups in the main chain, these polymers exhibit photochromic properties as well as excellent thermal stabilities. The transition temperatures (T _g) are between 242 and 265 °C, and the char yields at 800 °C in nitrogen atmosphere were above 39%. Based on incorporation of flexible ether linkages and polar sulfone groups, the polyamides show desirable solubility in organic solvents such as DMAc, N,N-dimethylformamide (DMF), N-methyl-2-pyrroidinone (NMP) and dimethylsulfoxide (DMSO). And it is exemplified that polyamide containing 2 and 2′ substitutes performed better solubility. Funded by the National Natural Science Foundation of China (No. 50572081)     

Evolution of carbides and carbon content in matrix of an ultra-high carbon sintered steel during heat treatment process

DTA, thermal expansion, XRD, and SEM were used to evaluate the effect of quenching temperature on the mechanical properties and microstructure of a novel sintered steel Fe-6Co-1Ni-5Cr-5Mo-1C. Lattice parameters and the mass fraction of carbon dissolved in the matrix of the steel quenched were investigated. It is discovered that the hardness of the steel increases with quench-ing temperature in the range of 840-900℃ and remains constant in the range of 900 to 1100℃. It decreases rapidly when the tem-perature is higher than 1100℃. The mass fraction of carbon dissolved in the matrix of the steel quenched at 840℃ is 0.38, but when the quenching temperature is increased to 1150℃, it increases to 0.98. The carbides formed during sintering are still present at grain boundaries and in the matrix of the steel quenched at low quenching temperatures, such as 840℃. When the quenching temperature is increased to 1150℃, most of the carbides at grain boundaries are dissolved with just a small amount of spherical M23C6 existing in the matrix of the quenched steel.     

Failure mode and strength anisotropic characteristic of stratified rock mass under uniaxial compressive situation

A stratified rock mass model was founded by FLAC^3D. The failure mode and anisotropic characteristic of strength for stratified rock mass were analyzed. The analysis results show that the numerical simulation can visually reflect the failure modes of rock samples under different inclination angles β of structural plane. The stiffness of rock sample before peak strength changes in the compressive procedure. With the increase of β, the compressive strength σ _c of rock sample decreases firstly and then increases; when β is in the range of 20°–30° and 80°–90°, σ _c has the largest sensitivity to β; while β falls in the range of 30°–70°, σ _c varies little. When ϕ _j <β<90° (β _j is friction angle of structure plane), the results obtained from numerical simulation and theoretical analysis are in almost the same values; while β⩽ ϕ _j or β=90°, they are in great different values. The results obtained from theoretical analysis are obvious larger than those from numerical simulation; and the results from numerical simulation can reflect the difference of compressive strength of rock samples for the two situations of β⩾ ϕ _j and β=90°, which is in more accordance with the real situation. Foundation item: Project (50099620) supported by the National Natural Science Foundation of China     

Preparation and mechanical properties of polypropylene fiber reinforced calcined kaolin-fly ash based geopolymer

To improve the environmental benefits and solve the problems of large shrinkage and high brittleness, the partial replacement of calcined kaolin by fly ash as a raw material for geopolymer synthesis and the influences of polypropylene (PP) fiber on the mechanical properties and volume stability were investigated. The results show that compressive strength of the geopolymer containing 33.3%(mass fraction) fly ash by steam curing at 80 °C for 6 d is improved by 35.5%. The 3-day compressive strength, flexural strength and impacting energy of geopolymers containing 0.05%PP fiber increase by 67.8%, 36.1% and 6.25%, while the shrinkage and modulus of compressibility decrease by 38.6% and 31.3%, respectively. The results of scanning electron microscopy (SEM) and the appearances of crack growths confirm that PP fiber can offer a bridging effect over the harmful pores and defects and change the expanding ways of cracks, resulting in a great improvement of strength and toughness. Foundation item: Project(2006AA06Z225) supported by the National High-Tech Research and Development Program of China     

攻击型无人机鲁棒导引律研究

文章研究了攻击型无人机鲁棒导引系统,采用对干扰和摄动具有自适应能力的滑动模态变结构控制方法设计了攻击型无人机滑模导引规律.针对用于消除颤振的伪滑动模态不能实现精确跟踪的缺陷,对滑模导引规律中颤振消除进行了优化设计,引入系统运动状态轨迹接近角变量,使消除颤振的伪滑动模态边界层宽度随着系统状态到达滑动模态而逐渐减小为零,从而达到了既能消除颤振又能实现精确跟踪的设计目标.通过仿真验证了该导引规律具有攻击弹道平缓、抗目标机动扰动能力强、鲁棒性好、制导精度高的优点.     

一种新的基于隐式经验的服务发现模型

文章介绍了一个新的服务发现模型ICSD模型,解决了传统服务发现技术中服务的功能与非功能特性较难控制的问题.文中第1节定义了模型中用到理论的9个相关概念.第2节具体介绍了模型的实现原理,给出了模型的一个原理图及模型中用到的一个相似度计算算法.文中第3节介绍了一个基于ICSD模型开发的原型系统,并引入了一套测试方案对系统进行了验证.试验证明随着服务数量的增加,系统的精确率稳定到0.8.     

基于STC单片机的焊接摆动器控制系统的设计

介绍了基于STC单片机焊接摆动器控制系统的设计,包括电源模块、单片机控制模块、直流电机脉宽调制(PWM)调速模块、红外线二极管检测与放大电路模块、人机交互模块等系统硬件设计,以及用C语言实现的系统软件设计.该系统能够控制焊枪以特定的预置参数进行摆动并配合一台小车进行流水线操作,从而达到自动焊接过程中的特殊要求.通过现场运行,系统稳定,可靠性高,满足工业现场要求.     

基于随机滤波器的无位置传感器SMPM电机磁通辨识

用随机滤波器对无速度传感器的交流永磁电机的转子磁通进行观测.观测过程中为了降低计算量,采用参数的混合辨识方法,把滑模观测器引入磁通辨识系统,代替位置传感器对转子位置和速度进行估计.用Matlab7.0建立离线辨识模型,仿真分析了转子磁通估计值与实际值之间的误差,以及磁通估计值随负载转矩大小的变化情况.     

山地生态旅游区景观规划原则初探

针对山地生态旅游区景观规划的意义,从景观生态学的角度来探讨山地生态旅游区景观规划的原则,以期对目前山地生态旅游区的建设起到一定的参考和借鉴作用.     

方形气固流化床从鼓泡到湍动流型转变的实验研究

在368mm×368 mm方形气固床中对FCC颗粒进行流态化实验,研究了从鼓泡到湍动的流型转变行为及相关问题.实验测试了多个床层截面的压差波动,由波动标准差随表观气速变化的最大值获得了流型转变速度Uc.结果表明,方形床中的流态化平均行为在床层截面纵横两个方向一致,沿床层轴向呈现不均匀性,底部存在颗粒密相区;不同床层截面转变速度Uc不同,由床层上部向下扩展,Uc呈线性增加关系,说明流型转变至上而下进行;静床高度对Uc影响显著,静床高度增加,床层轴向各截面Uc相应增加;以上结果表明了目前仅与气固物性参数相关联的Uc预测模型有待改进.