Preparation of a monolith-supported Au/TiO2 catalyst active for CO oxidation

The development of a method for making an adherent coating of Au/TiO₂ on a cordierite monolith is described. The optimum method entails first forming a wash-coat of TiO₂ by combining a colloidal dispersion of TiO₂ with Degussa P-25 TiO₂ that has been washed, dried and crushed. Subsequent deposition of gold from HAuCl₄ solution at pH 9 resulted in a catalyst that was less active for the oxidation of carbon monoxide than a similar preparation using only P-25, but reproducible values of T₅₀ of about 250 K were obtained.     

A study of thermal,optical and electrical properties of new branched triphenylamine-based polyazomethines

A series of branched aromatic polyazomethines have been obtained by high temperature solution polycondensation of 4,4′,4″-triformyltriphenylamine with 3,3′-dimethoxybenzidine with different feed molar ratio. For three polymers additional condensation of chain end groups with monofunctional monomers such as 4-formyltriphenylamine or 2-naphthylamine was carried out. Moreover, two model compounds were prepared and investigated for comparison with branched polymers. The structures of polymers and models were characterized by means FTIR, ¹H, ¹³C NMR spectroscopy, elemental analysis and gel permeation chromatography (GPC). UV–vis properties of the thin films of the polymers and compounds were investigated on the glass substrate. Eg of the branched polymers was found about 2.47 eV. UV–vis and FTIR spectroscopy for iodine doped compounds were investigated. Doping decreased the value of Eg of the branched polyazomethines to about 1.71 eV. Refractive index (n) for branched polyazomethines was found about 1.97, while for the doped compounds was a little higher (～2.48). Absorption (UV–vis) properties of the doped with iodine branched imines were investigated additionally after heating in different temperatures from 50 to 200 °C. Intensity of photoluminescence of branched imines in relation to 9,10-diphenylanthracene was found in the range 0.2–1.0% and 2.7–43.7% in dependence on the excitation wavelengths. Current–voltage (I–V) measurements were performed on ITO/TiO₂/polymer/Al, ITO/polymer/Alq₃/Al and ITO/TiO₂/polymer/Alq₃/Al devices in the dark and during irradiation with light (under illumination 1000 W/m²). The sol–gel technique was applied to prepared TiO₂ layer. TiO₂ layers and devices were investigated by Atomic Force Microscopy (AFM). Moreover, properties of these branched polymers were compared with the linear polyazomethine based on 3,3′-dimethoxybenzidine and 4,4′-diformyltriphenylamine.     

Intelligent Processing of Stuttered Speech

The process of counting stuttering events could be carried out more objectively through the automatic detection of stop-gaps, syllable repetitions and vowel prolongations. The alternative would be based on the subjective evaluations of speech fluency and may be dependent on a subjective evaluation method. Meanwhile, the automatic detection of intervocalic intervals, stop-gaps, voice onset time and vowel durations may depend on the speaker and the rules derived for a single speaker might be unreliable when trying to consider them as universal ones. This implies that learning algorithms having strong generalization capabilities could be applied to solve the problem. Nevertheless, such a system requires vectors of parameters, which characterize the distinctive features in a subject's speech patterns. In addition, an appropriate selection of the parameters and feature vectors while learning may augment the performance of an automatic detection system.The paper reports on automatic recognition of stuttered speech in normal and frequency altered feedback speech. It presents several methods of analyzing stuttered speech and describes attempts to establish those parameters that represent stuttering event. It also reports results of some experiments on automatic detection of speech disorder events that were based on both rough sets and artificial neural networks.     

Copper complexing properties of melanoidins and marine humic material

Melanoidins, condensation products of sugars and amino acids, represent a key link in the transformation of polysaccharides to humic material in the marine environment. We investigated the complexing capacity of melanoidins that were prepared in deionized water and seawater and separated into different molecular mass fractions. The copper complexing properties of humic material isolated from marine lagoon sediments were determined for comparison. Melanoidins prepared using condensation times longer than two days exibit complexation properties towards copper ions that appear to depend on the basicity of the amino acid precursor and the molecular mass of the product. Pseudomelanoidins, prepared from glucose only, do not complex copper ions at all, regardless of the molecular mass. The highest copper complexing capacity value among melanoidins was measured for a glucose-lysine melanoidin with molecular mass fraction >10 kD (L(T)=2.1x10(-7) molCu(2+)/L). Melanoidin prepared from glucose and glutamic acid >10 kD was similar in complexing capacity to fulvic acid (1-20 kD molecular mass) isolated from lagoon sediments. The presence of calcium and magnesium ions and other macro and microconstituents in the seawater used to prepare melanoidins influences its complexing properties towards metal ions.     

Dynamic reconfiguration schemes for megabit BiCMOS SRAMs and performance evaluation

In this paper two dynamic configuration schemes are discussed for megabit BiCMOS static random access memories (SRAMs). Dynamic reconfiguration schemes allows failure detection at the chip level and automatic reconfiguration to fault free memory cells within the chip. The first scheme is a standby system approach where the I/O lines of the memory can be dynamically switched to spare bit slices in the SRAM. This scheme is implemented through a switching network at the memory interface. Every memory access is controlled by a fault status table (FST) which memorizes the fault conditions of each memory block. This FST is implemented outside the memory system. A second dynamic reconfiguration scheme for BiCMOS SRAMs is addressed through a graceful degradation approach. Basic design considerations and performance evaluation of megabit BiCMOS SRAMs using dynamic reconfiguration schemes are presented. The basic properties of the proposed schemes and a prototype VLSI chip implementation details are discussed. BiCMOS SRAM access time improvement of about 35%, chip area of 25%, and chip yield of 10% are achieved, respectively, as compared to conventional methods. A comparison of reliability improvement of 1 Mb BiCMOS SRAMs using dynamic configuration schemes is presented. These two dynamic reconfiguration schemes have considerable importance in reliability improvement when compared to conventional methods. The major advantage is that the size of reconfiguration of the system can be considerably reduced.     

Pattern of volatile compounds in dominant and subordinate male mouse urine

The urinary volatiles from dominant and subordinate male mice were chromatographically compared, both immediately and seven days after dominant-subordinate relationships between pairs were formed. Statistical comparison of the peak areas of volatile constituents present in male urine revealed that 16 urinary compounds exhibited substantial concentration differences depending upon social status of the animals. Urinary dihydrofurans, ketones, and acetates exhibited a significant, long-term (seven-day) decrease in the urine of subordinates when compared to control and dominant males. Two sesquiterpenic compounds, - and -farnesene, were elevated only in the dominant urine one week after dominance was established. 2-(sec-Butyl)-4,5-dihydrothiazole was found in higher concentration in bladder or excreted urine of dominant males when compared to subordinates. Of the 16 compounds subjected to statistical analysis, four exhibited hormonal dependency: - and -farnesene, dehydro-exo-brevicomin, and 2-(sec-butyl)-4,5-dihydrothiazole. Neither dehydro-exo-brevicomin nor 2-(sec-butyl)-4,5-dihydrothiazole was present in the urine of immature and castrated males. Testosterone treatment restores their presence in male urine. Also, - and -farnesene were absent in the urine of immature males and significantly reduced in the urine of castrated males. The absence of - and -farnesene in bladder urine suggests that one of the sex-accessory glands may be the site of their origin.     

Hyper-crosslinked sorbents for hemoperfusion

Pore structure changes of swelling sorbents, which were obtained from styrene and divinylbenzene (DVB) by additional crosslinking with α,α′-dichloro-p-xylene in the presence of tin chloride catalyst and in dichloroethane solution, were examined. It was found that the amount of dichloroxylene influences the swelling decrease and the increase of sorption ability of sorbents for chemical compounds with low molecular weight. Hemocompatibility was imparted to the sorbent and it was useful for hemoperfusion when a small amount of sulfonyl groups (about 0.2 mmol/g) had been introduced.     

Transdermal and buccal delivery of methylxanthines through human tissue in vitro

We examined the in vitro permeation of central nervous stimulants—caffeine, theophylline, and theobromine across human skin with the aid of six chemical enhancers. It was found that oleic acid was the most potent enhancer for all three methylxanthines. Further optimization studies with different solvents showed that caffeine transport could be enhanced to give flux values up to 585 μg/cm².hr^-1. Theobromine and theophylline delivery rates proved insufficient. An additional study involving a buccal tissue equivalent showed that this membrane was more permeable than skin for all model actives tested and would offer an alternate way of delivery.     

The polymerization mechanism of lactide initiated with zinc (II) acetylacetonate monohydrate

The paper presents the mechanism of lactide polymerization initiated with zinc (II) acetylacetonate monohydrate. However, the actual initiator of this reaction is the complex containing a metal-oxygen bond, formed by the exchange reaction of acetylacetonate ligand with deprotonated lactide derivative. The described reaction results in the release of free acetylacetonate and formation of transitional zinc complex with metal-oxygen bond connecting the zinc atom with derivative of lactide, incorporated - as a new, active in polymerization ligand. Polylactide chain propagation process, which constitutes the following stage of the reaction, is caused by a typical, well known, coordination-insertion ring opening polymerization. The proceeding polymerization maximum yield at the applied conditions does not exceed about 70% in benzene solution and 90% at bulk.