A Novel Flexible Hybrid Battery–Supercapacitor Based on a Self‐Assembled Vanadium‐Graphene Hydrogel

A novel flexible hybrid battery–supercapacitor device is proposed consisting of high specific surface area electrodes paired with an electrolyte, which contains a redox species that can exist in more than two oxidation states. The two initially equal half‐cells of the device consist of a reduced graphene oxide hydrogel which encapsulates vanadium ions, synthesized with a single‐step method. During charge, the oxidation state of the vanadium ions changes, resulting in two half‐cells with different potentials which considerably increases the energy density. The achieved maximum capacity of more than 225 mAh g^?1 is roughly eight times higher than that of comparable graphene hydrogel supercapacitors without vanadium content, but the potentiostatic charging time is only double. Operated as a supercapacitor, it retains 95% of the initial capacitance over 1000 cycles. As battery, the losses are more significant, retaining around 50% of the initial capacity. However, these losses during battery operation can be almost entirely restored by electric measures. The vanadium ion addition also improves the self‐discharge characteristics of the device. Moreover, the self‐discharge does not permanently damage the hybrid device since both half‐cells initially consist of the same vanadium graphene hydrogel and discharging resets it to initial conditions.     

Quantifying the influence of cold water intrusions in a shallow,coastal system across contrasting years: Green Bay,Lake Michigan

We present water column thermal structure for two climatically different years: 2012, which experienced abnormally warm spring and summer air temperatures preceded by a relatively low ice winter and 2013, which experienced cooler than average spring and average summer air temperatures and preceded by average ice conditions. Mean bottom water temperatures for the season and during cold water intrusions were significantly warmer in 2012 than 2013 leading to a significantly reduced stratified season in 2012. Cold water intrusions were driven into southern Green Bay by southerly winds while intrusions were terminated when winds switched to persistent northerly winds. 2012 observed a significant increase in northerly winds relative to 2013, decreasing cold water intrusion presence and duration but winds did not fully explain the difference in thermal conditions for southern Green Bay. These cold bottom waters drive stratification in polymictic southern Green Bay while dimictic waters were found to have significantly warmer bottom temperatures during 2012 and a deeper mixed layer. Our observations suggest that relatively shallow (<20?m), seasonally stratified systems may not increase in stratification strength and duration under a warming climate; rather, changing wind climatology and surface heat flux can inform the degree to which the mixing regime can be expected to change and impact stratification and thermal structure of coastal systems. We discuss the biogeochemical implications of different thermal regimes, particularly within the context of multiple drivers of physical water column structure in eutrophic, stratified coastal systems.     

Evidence of persistent,recurring summertime hypoxia in Green Bay,Lake Michigan

Six years (2009–2015) of temperature and dissolved oxygen profile data show hypoxic conditions are common in the bottom waters of southern Green Bay, Lake Michigan during the summer. Depleted oxygen concentrations (<5?mg?L^?1) affect nearly 70% of the 38 stations sampled representing an area of ~500–600?km². Stratification typically lasts 2+?months, from late June to early September, and some stations exhibit bottom water hypoxia (<2?mg?L^?1) at a frequency of nearly 25% when sampled during this period. A monitoring program initiated in 1986 by the Green Bay Metropolitan Sewerage District has provided a 23?year, recreational season record (May–September) of continuous (15?min interval) in situ bottom water oxygen and temperature measurements at the Entrance Light station of the Green Bay navigational channel. The duration of the hypoxic season ranges from 2?weeks to over 3?months at this shallow 7?m offshore site. This variability likely results from a combination of thermal stratification, oxygen consumption in deeper waters of the bay, and physical forcing mechanisms that drive cool, oxygen depleted, bottom waters on a southerly trajectory across this sensor. These data suggest the duration of hypoxic conditions may have increased during the stratified season in recent years. Hypoxia in the bay would also appear to be sensitive to relatively small changes in these forces, particularly changes in organic carbon loading and the duration of stratification.     

A fast boundary element based solver for localized inelastic deformations

We present a numerical method for the solution of nonlinear geomechanical problems involving localized deformation along shear bands and fractures. We leverage the boundary element method to solve for the quasi-static elastic deformation of the medium while rigid-plastic constitutive relations govern the behavior of displacement discontinuity (DD) segments capturing localized deformations. A fully implicit scheme is developed using a hierarchical approximation of the boundary element matrix. Combined with an adequate block preconditioner, this allows to tackle large problems via the use of an iterative solver for the solution of the tangent system. Several two-dimensional examples of the initiation and growth of shear-bands and tensile fractures illustrate the capabilities and accuracy of this technique. The method does not exhibit any mesh dependency associated with localization provided that (i) the softening length-scale is resolved and (ii) the plane of localized deformations is discretized a priori using DD segments.     

Pore Sizes and Filtration Rates from Two Alumina Slips

The relationship between filtration rate and the resultant green body microstructure was examined for aqueous alumina slips cast at two different deflocculation states. The volume loading of both slips was 40%. Slip viscosities of 500 and 60 mPa·s were produced by different tetrasodium pyrophosphate additions. The filtration rate of these slips varied by a factor of 2; however, mercury porosimetry results showed the same average pore size for both samples. Single and multiple small-angle neutron scattering results showed the specimen cast with the higher-viscosity slip to possess a bimodal pore size distribution. The body cast with the low-viscosity slip showed unimodal porosity and, consequently, the filtration is attributed to the toroidal region between the packed particles. These results showed that mercury porosimetry does not provide a pore size that predicts filtration behavior of slips with different degrees of dispersion.     

Mechanisms for tertiary creep of single crystal superalloy

During the thermal-mechanical loading of high temperature single crystal turbine components, all three creep—stages: primary, secondary and tertiary, manifest themselves and, hence, none of them can be neglected. The development of a creep law that includes all three stages is especially important in the case of non-homogeneous thermal loading of the component where significant stress redistribution and relaxation will result. Thus, local creep analysis is crucial for proper design of damage tolerant airfoils. We have developed a crystallographic-based constitutive model and fully coupled it with damage kinetics. The model extends existing approaches for cyclic and thermal-cyclic loading of anisotropic elasto-viscoplastic deformation behavior and damage kinetics of single-crystal materials, allowing prediction of tertiary creep and failure initiation of high temperature components. Our damage model bridges the gap between dislocation dynamics and the continuum mechanics scales and can be used to represent tertiary as well as primary and secondary creep.     

"Planes, trains, automobiles--and tea sets: Extremely intense interests in very young children": Correction to DeLoache, Simcock, and Macari (2007).

Reports an error in "Planes, trains, automobiles--and tea sets: Extremely intense interests in very young children" by Judy S. DeLoache, Gabrielle Simcock and Suzanne Macari (Developmental Psychology, 2007[Nov], Vol 43[6], 1579-1586). The DOI for the supplemental materials was printed incorrectly. The correct DOI is as follows: http://dx.doi.org/10.1037/0012-1649.43.6.1579.supp. (The following abstract of the original article appeared in record 2007-16709-024.) Some normally developing young children show an intense, passionate interest in a particular category of objects or activities. The present article documents the existence of extremely intense interests that emerge very early in life and establishes some of the basic parameters of the phenomenon. Surveys and interviews with 177 parents revealed that nearly one third of young children have extremely intense interests. The nature of these intense interests is described, with particular focus on their emergence, commonalities in the content of the interests, and the reactions of other people to them. One of the most striking findings is a large gender difference: Extremely intense interests are much more common for young boys than for girls. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Analysis of stresses during the freezing of solid spherical foods

An analytical model is presented to calculate thermal stresses and strains during the freezing of a spherical food, taking into account both the expansion during phase change and subsequent thermal contraction due to temperature decrease. The Young modulus and Poisson ratio are assumed to undergo a step change at the freezing point. The expansion due to phase change cause a uniform and virtually constant isotropic tensile stress in the unfrozen core. In the frozen shell, this expansion gives rise to tensile radial stress and compressive tangential stress. The thermal contraction subsequent to phase change causes reverse effects, i.e. uniform compressive stress in the unfrozen core and compressive radial stress in the frozen shell, while tangential stress is tensile on the outside and compressive on the inside of the frozen shell. The effect of thermal contraction is noticeable only at cryogenic temperatures.     

Air motion sensing hairs of arthropods detect high frequencies at near-maximal mechanical efficiency

Using measurements based on particle image velocimetry in combination with a novel compact theoretical framework to describe hair mechanics, we found that spider and cricket air motion sensing hairs work close to the physical limit of sensitivity and energy transmission in a broad range of relatively high frequencies. In this range, the hairs closely follow the motion of the incoming flow because a minimum of energy is dissipated by forces acting in their basal articulation. This frequency band is located beyond the frequency at which the angular displacement of the hair is maximum which is between about 40 and 600 Hz, depending on hair length (Barth et al. [1] Phil. Trans. R. Soc. Lond. B 340, 445–461 (doi:10.1098/rstb.1993.0084)). Given that the magnitude of natural airborne signals is known to decrease with frequency, our results point towards the possible existence of spectral signatures in the higher frequency range that may be weak but of biological significance.     

Evolution of Texture from a Single Crystal Ti-6Al-4V Substrate During Electron Beam Directed Energy Deposition

Additive manufacturing of Ti-6Al-4V commonly produces 〈001〉 _β -fiber textures aligned with the build direction. We have performed wire-feed electron beam directed energy deposition on the {112} _β plane of a single prior β-grain. The build initially grew epitaxially from the substrate with the preferred 〈001〉 growth direction significantly angled away from the build direction. However, continued layer deposition drove the formation of a 〈001〉 _β -fiber texture aligned with the build direction and the direction of the strongest thermal gradient.