The Thermodynamic Properties of Silicon Oxynitride

A critical assessment of thermal and equilibrium data for silicon oxynitride (Si₂N₂O) is presented. Selected values for the heat of formation of Si₂N₂O from the elements and the absolute entropy of Si₂N₂O at 298.15 K are ΔH⁰_f,298=−947.7 ± 5.4 kJ/mol and S⁰₂₉₈= 45.35 ± 0.4 J/mol·K, respectively. A table of thermodynamic functions for Si₂N₂Ofrom 298 to 2500 K, which has been calculated from the analysis of the literature data, is also presented.     

Scalable Realistic Rendering with Many‐Light Methods

Recent years have seen increasing attention and significant progress in many‐light rendering, a class of methods for efficient computation of global illumination. The many‐light formulation offers a unified mathematical framework for the problem reducing the full lighting transport simulation to the calculation of the direct illumination from many virtual light sources. These methods are unrivaled in their scalability: they are able to produce plausible images in a fraction of a second but also converge to the full solution over time. In this state‐of‐the‐art report, we give an easy‐to‐follow, introductory tutorial of the many‐light theory; provide a comprehensive, unified survey of the topic with a comparison of the main algorithms; discuss limitations regarding materials and light transport phenomena and present a vision to motivate and guide future research. We will cover both the fundamental concepts as well as improvements, extensions and applications of many‐light rendering.     

Measuring ranked list robustness for query performance prediction

We introduce the notion of ranking robustness, which refers to a property of a ranked list of documents that indicates how stable the ranking is in the presence of uncertainty in the ranked documents. We propose a statistical measure called the robustness score to quantify this notion. Our initial motivation for measuring ranking robustness is to predict topic difficulty for content-based queries in the ad-hoc retrieval task. Our results demonstrate that the robustness score is positively and consistently correlation with average precision of content-based queries across a variety of TREC test collections. Though our focus is on prediction under the ad-hoc retrieval task, we observe an interesting negative correlation with query performance when our technique is applied to named-page finding queries, which are a fundamentally different kind of queries. A side effect of this different behavior of the robustness score between the two types of queries is that the robustness score is also found to be a good feature for query classification.      

Applications, techniques, and microfluidic interfacing for nanoscale biosensing

Biosensors based on nanotechnology are rapidly developing and are becoming widespread in the biomedical field and analytical chemistry. For these nanobiosensors to reach their potential, they must be integrated with appropriate packaging techniques, which are usually based on nano/microfluidics. In this review we provide a summary of the latest developments in nanobiosensors with a focus on label-based (fluorescence and nanoparticle) and label-free methods (surface plasmon resonance, micro/nanocantilever, nanowires, and nanopores). An overview on how these sensors interface with nano/microfluidics is then presented and the latest papers in the area summarized.     

Collaborative writing in multiple discourse contexts

Research in computer-supported writing has traditionally compared electronic communication with oral, face-to-face communication to identify the benefits and weaknesses of each, as if they entailed dichotomous choices. In this article, we challenge that view and argue instead that any form of communication and its educational usefulness is shaped by the situation in which it is used, the backgrounds and goals of the participants, the institutional and technological setup, and the intended purpose of the medium. Three modes of communication in one graduate course are examined — oral discussion, synchronous written discussion on a local area network, and asynchronous written postings on an email list set up for the class. It was found that patterns of participation, topic introduction, and topic development differed across the three communication modes, but that the three were interwoven with each other and embedded within the larger classroom context and forms of knowledge creation in the class. Thus, rather than examining different communication media separately, researchers interested in understanding computer-supported collaborative writing need to look at how different media are used to create a meta-medium, which is established by the discourse community involved.     

Kirchhoff calculations of the coherent scatter from a series of very rough surfaces

Calculations are presented for the scattering of polarized light from a series of very rough one-dimensional gold-coated surfaces, as determined by the use of the Kirchhoff approximation with geometric shadowing. These surfaces have Gaussian autocorrelation functions with a 1/e width of 3.3 μm and Gaussian probability distributions of height with standard deviation varying between 0.25 and 1.73 μm. Calculations are performed for the scattering of light of wavelength 3.392 μm, so that the validity of the geometric-shadowing approximation and the Kirchhoff approximation itself are open questions. The values of the coherent (or specular) component of the scattered light for the four nonzero elements of the Mueller matrix (which fully describe the polarization properties of the scattered light) are calculated. Comparisons between the calculated results and experimental measurements on surfaces of the same parameters [Knotts and O'Donnell, J. Opt. Soc. Am. A 11, 697 (1994)] show good agreement up to approximately 70° incidence angle.     

Parametric study of the absorption cross section for a moderately conducting thin cylinder

Asystem has been developed to measure the absorption cross section for a single carbon fiber at 35 GHz as a functio of length, orientation, and diameter. Typical lengths of the fibers considered ranged from 1 to 20 mm, and diameters ranged from 3 to 8 μm. The results were compared with the modified integra equation calculations of Waterman and Pedersen that describe the scattering and absorption behavior for a wire of finite length and conductivity. Good agreement was found for all lengths, orientations, and diameters studied.     

Assessing abrasion performance of self-consolidating concrete containing synthetic fibers using acoustic emission analysis

The key objective of this investigation was to evaluate the abrasion resistance of self-consolidating concrete (SCC) with and without synthetic fibers (SynFs). The abrasion resistance of normal concrete was also investigated in this study for comparison. The abrasion test was performed on concrete specimens according to the rotating-cutter method along with continuous monitoring of acoustic emission (AE) using attached AE sensors. The effects of changing concrete type and incorporating various types (flexible and semi-rigid) and lengths of SynFs on the abrasion behaviour were investigated with the aid of AE analysis. AE signal characteristics such as amplitude, signal strength, number of hits, and duration were gathered during testing. Furthermore, the collected AE data was used to complete b-value analysis as well as intensity analysis resulting in three additional parameters: b-value, severity (S_r), and historic index (H(t)). The results showed that the AE parameters were directly correlated with the abrasion damage in all tested mixtures. Adding SynFs to all SCC mixtures enhanced their abrasion resistance. The flexible fibers variety exhibited better abrasion performance on average than the semi-rigid fibers. Meanwhile, longer fibers showed lower abrasion resistance than the shorter ones with the same type. The results also indicated that AE intensity analysis was able to determine the ranges for H(t) and S_r that identify the extent of damage due to abrasion of SynF-reinforced SCC.     

Valorisation of mango seed via extraction of starch: preliminary techno-economic analysis

Reducing environmental impacts and obtaining economic benefits based on utilisation of waste materials are drivers for the implementation of cleaner production policies and technologies in food processing industries. Starch is a very versatile material with a wide range of applications in the food, pharmaceutical, textile, paper, cosmetic and construction industries. In Ethiopia, starch is widely used in the textile industry. To meet the starch demand, the country imports approximately 45% of the starch used in the country. Consequently, it is imperative to find additional sources of starch that could substitute for the amount of starch that is currently being imported. Mango seeds, a waste material that is disposed of after consumption of mangos, were studied for potential use as an alternative resource for starch production. The results showed that starch extraction from mango seeds was facile and a good quality product was obtained. The present study is concerned with a techno-economic analysis for industrial production of starch from mango seeds. The study shows that extraction of starch from waste mango seeds is feasible: the project is financially viable with an accounting rate of return of 83% and a break-even analysis of 78% with a payback period of 2 years.