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71.
72.
Jon T. Carter Paul E. Krajewski Ravi Verma 《JOM Journal of the Minerals, Metals and Materials Society》2008,60(11):77-81
The hot blow forming of magnesium sheet offers significant opportunity for forming complex, lightweight parts for automotive
applications. This paper characterizes the elevated-temperature formability of AZ31 magnesium sheet materials and the effect
of processing conditions on the performance of these materials. In addition, magnesium sheet application development at General
Motors Corporation is reviewed. 相似文献
73.
Toshihiko Hoshide Junpei Fujita 《Journal of Materials Engineering and Performance》2008,17(5):627-632
Strength of ground ceramics may be affected by residual stress as well as surface flaws induced by grinding. Strength prediction
for ground ceramics is convenient for mechanical design of ceramic components. In this article, a numerical procedure based
on fracture mechanics was proposed to estimate strength distribution of ground ceramics by considering grinding-induced residual
stress. Bending strength and residual stress of ground ceramics were measured for three grinding-conditions. By comparison
of simulated results with experimental ones, it was revealed that strength characteristics in experiments were well simulated
by using the proposed procedure. 相似文献
74.
The aim of this study was to investigate the drug‐loading effects on release and mechanical properties of a scleroglucan gel, with the intention of considering them in delivery systems formulations. The rheological and kinetic properties of a 2 % w/w scleroglucan gel matrix loaded with 0, 0.02, 0.04, 0.06, 0.2 and 0.4 % w/w of theophylline (Th, used as a model drug) were investigated. Rheological measurements were performed in a controlled‐stress rotational‐shear rheometer under isothermal conditions. For theophylline release from the gel a flat Franz cell was used and the kinetic parameters were derived applying a semi‐empirical power law. The influence of scleroglucan molar weight on kinetic and rheological behaviour was also studied. Results suggest two possible effects of drug loading on the gel network: in the 0.04–0.06 % w/w Th range a plasticizing effect and in the 0.2–0.4 % w/w Th range a rigidization effect. In the first range mentioned, the changes in the gel structural properties tested by means of rheological measurements are coincident with changes in drug‐release kinetics. Copyright © 2005 Society of Chemical Industry 相似文献
75.
Omar Snchez Estrella Asp María C Martí Marlene Roeckel 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(11):1261-1267
Most of the kinetic studies on nitrification have been performed in diluted salts medium. In this work, the ammonia oxidation rate (AOR) was determined by respirometry at different ammonia (0.01 and 33.5 mg N‐NH3 L?1), nitrite (0–450 mg N‐NO2? L?1) and nitrate (0 and 275 mg N‐NO3? L?1) concentrations in a saline medium at 30 °C and pH 7.5. Sodium azide was used to uncouple the ammonia and nitrite oxidation, so as to measure independently the AOR. It was determined that ammonia causes substrate inhibition and that nitrite and nitrate exhibit product inhibition upon the AOR. The effects of ammonia, nitrite and nitrate were represented by the Andrews equation (maximal ammonia oxidation rate, rAOMAX, = 43.2 [mg N‐NH3 (g VSSAO h)?1]; half saturation constant, KSAO, = 0.11 mg N‐NH3 L?1; inhibition constant KIAO, = 7.65 mg N‐NH3 L?1), by the non‐competitive inhibition model (inhibition constant, KINI, = 176 mg N‐NO2? L?1) and by the partially competitive inhibition model (inhibition constant, KINA, = 3.3 mg N‐NO3? L?1; α factor = 0.24), respectively. The rAOMAX value is smaller, and the KSAO value larger, than the values reported in diluted salts medium; the KIAO value is comparable to those reported. Process simulations with the kinetic model in batch nitrifying reactors showed that the inhibitory effects of nitrite and nitrate are significant for initial ammonia concentrations larger than 100 mg N‐NH4+ L?1. Copyright © 2005 Society of Chemical Industry 相似文献
76.
Wladek T. Sobol L.John SchreinerLjubis̆a Miljković Maria E. Marcondes-HeleneLeonard W. Reeves M.Mik Pintar 《Fuel》1985
The first results of the analysis of bitumen and oil sands using the recently developed n.m.r. spingrouping technique are presented. The n.m.r. relaxation experiments were carried out on bitumen, and on natural and dried oil sands samples. The results indicate that the spin-grouping can resolve and quantify several components of the samples studied. The bitumen and bitumen fraction of the oil sands are resolved according to their spin-spin relaxation times into three major groups: solid-like (rigid), solid-like (mobile) and semi-liquid. The water in the oil sands exists in two different environments. Tentatively one environment is assigned to be the bridges between the sand grains, while the other is assigned to be the clay surface. One can conclude that with spin grouping of complex mixtures the decomposition (in which components are resolved according to their dynamic state) is possible. The accuracy of such resolution is of the order of a few per cent. 相似文献
77.
Gérard Battail 《电信纪事》1987,42(9-10):499-509
We propose to redefine weighted decoding of a redundant code as consisting of reestimating a given prior probability distribution in order to take into account the code constraints. The optimum solution of this problem results from using the « minimum cross-entropy » principle and is shown to coincide with the computation of the probabilities to be compared in order to perform maximum likelihood decoding when the prior distribution is exactly known. The principle however also holds when the prior distribution is approximate or biased, which explains the robustness of decoding with respect to weighting information. Such a redefinition also enables using the intermediate steps of decoding, in the case of codes associated by concatenation or product, as a source of weighting information for the subsequent steps. One is led for simplicity’s sake to an estimate of the posterior probability in separable form with respect to the information symbols ; its definition is given and certain of its applications are discussed. 相似文献
78.
Zirconium(IV) tungstoiodophosphate has been synthesized under a variety of conditions. The most chemically and thermally stable
sample is prepared by adding a mixture of aqueous solutions of 0·5 mol L−1 sodium tungstate, potassium iodate and 1 mol L−1 orthophosphoric acid to aqueous solution of 0·1 mol L−1 zirconium(IV) oxychloride. Its ion exchange capacity for Na+ and K+ was found to be 2·20 and 2·35 meq g−1 dry exchanger, respectively. The material has been characterized on the basis of chemical composition, pH titration, Fourier
transform infrared spectroscopy (FTIR) and thermogravimetric analysis. The effect on the exchange capacity of drying the exchanger
at different temperatures has been studied. The analytical importance of the material has been established by quantitative
separation of Pb2+ from other metal ions. 相似文献
79.
Jonathan P. Belnoue Giang D. Nguyen Alexander M. Korsunsky 《International Journal of Fracture》2007,144(1):53-60
This paper presents a new 1-D non-local damage-plasticity deformation model for ductile materials. It uses the thermodynamic
framework described in Houlsby and Puzrin (2000) and holds, nevertheless, some similarities with Lemaitre’s (1971) approach.
A 1D finite element (FE) model of a bar fixed at one end and loaded in tension at the other end is introduced. This simple
model demonstrates how the approach can be implemented within the finite element framework, and that it is capable of capturing
both the pre-peak hardening and post-peak softening (generally responsible for models instability) due to damage-induced stiffness
and strength reduction characteristic of ductile materials. It is also shown that the approach has further advantages of achieving
some degree of mesh independence, and of being able to capture deformation size effects. Finally, it is illustrated how the
model permits the calculation of essential work of rupture (EWR), i.e. the specific energy per unit cross-sectional area that
is needed to cause tensile failure of a specimen. 相似文献
80.
There are some foods that contain mutagenic or carcinogenic agents, some of which occur naturally and others that may be formed during preparation or cooking. Several foods such as legumes, also contain natural antimutagens and/or anticarcinogens. Lupine is one such legume that contains high amounts of protein (40%) and oils (14%). About 90 species of lupine have been reported throughout Mexico. However, the use of this crop as a source of food has been limited by the presence of antinutritional agents such as phenolic compounds (PC), carbohydrates (CH) and quinolizidinic alkaloids (Qas). It has also been suggested that consuming these compounds can affect human health and may even reduce the risk of disease. The objective of this work was to determine the effect of PC, CH and Qas, isolated and quantified from Lupinus campestris on the mutagenicity of 1-nitropyrene (1-NP) as a model mutagen and we used the Salmonella typhimurium tester strain YG1024 by the Kado microsuspension method. The results indicate that L. campestris seeds have 11 mg (+)catechin equivalent g(-1) seed coat; 120.3 mg g(-1) seeds and 2.13 mg g(-1) seeds of PC, CH and Qas, respectively. 1-NP mutagenicity was inhibited by 86% for PC, 76% for CH and 75% for Qas at concentrations of 200, 512 and 13.6 microg/tube, respectively. 相似文献