The Propensity of Wooden Crevices to Smoldering Ignition by Firebrands

Fire Technology - Fires occurring at the wildland-urban interface (WUI) have rapidly increased in frequency and severity over the past few decades. As a result of these extreme fires, multiple...     

Recent Advances in White Organic Light‐Emitting Materials and Devices (WOLEDs)

WOLEDs offer new design opportunities in practical solid‐state lighting and could play a significant role in reducing global energy consumption. Obtaining white light from organic LEDs is a considerable challenge. Alongside the development of new materials with improved color stability and balanced charge transport properties, major issues involve the fabrication of large‐area devices and the development of low‐cost manufacturing technology. This Review will describe the types of materials (small molecules and polymers) that have been used to fabricate WOLEDs. A range of device architectures are presented and appraised.     

Variable wall thickness scroll geometry modeling with use of a control volume approach

In a scroll-type compressor, compression is achieved through relative contact between two spiral curves. Since the scroll invention by Leon Creux (1905), multiple methods have been developed for calculating scroll geometry. What can generally be considered the most classical method, is defining each scroll curve as the involute of a circle. Gravesen and Henriksen (2001) introduced a new method to calculate scroll geometry by deriving each scroll curve from the radius of curvature parameterized with involute angle. This allows a wide range of involute geometries to be considered not included in the classical method. In this paper, Gravesen's method is extended to the tip region to include all tip geometries involved in a two arc configuration resulting in a more comprehensive scroll geometry definition. Lastly, with parametric representation of all scroll geometry, the pocket volume can be easily solved using a derived control volume approach.     

Contactless measurement of surface dominated recombination in gold- and aluminum-catalyzed silicon vapor-liquid-solid wires

Carrier lifetimes of Si micro/nanowires grown by the vapor-liquid-solid method are measured using an extension of the classic contactless photoconductivity decay method. The samples measured consist of a thin aggregated film of oxide passivated wires on a fused silica carrier. Au catalyzed wires in the 392-730 nm diameter range are studied. Recombination in these wires is controlled by the surface or near surface effects, not bulk Au impurities. The lifetimes of Au- and Al-catalyzed wires of comparable diameter are measured. The Al wires are found to have slightly longer lifetimes than those grown with Au at a comparable diameter. Across all samples, the lifetimes measured range was from 0.2 to 1.0 ns. The surface controlled nature of the recombination measured implies larger diameter wires will offer better performance in devices that rely on minority carrier transport.     

Barriers to access before initiation of hemodialysis: a single-center review

Guidelines recommend that > or =50% of patients starting dialysis have a fistula. We reviewed our experience in consecutive incident patients over a 1-year period. Only 30 of the 93 patients starting hemodialysis had a fistula that was accessed. Late referral (nephrology contact <90 days) was a significant issue in 48% (30/63) of the patients without a fistula. Most (n=21) of the late referrals were acute disease; only 9 were late referrals of chronic disease. Nephrology follow-up exceeded 200 days in the remaining (33/63) without this access. In the cohort with sufficient nephrology referral, we explored variables associated with a fistula (n=30) compared with those without one (n=33). In multivariate logistic regression analysis, peripheral vascular disease (odds ratio [OR] 0.026, 95% confidence interval [CI] 0.002-0.286) and rapid loss of estimated glomerular filtration rate (eGFR) (OR 0.745 per mL/min/1.73 m(2)/year, 95% CI 0.625-0.888) in the year preceding dialysis were significant negative predictors for a fistula. Patients without access experienced faster declines in GFR in the year preceding dialysis (12.1+/-9.9 vs. 4.7+/-3.5 mL/min 1.73 m(2) with access, p<0.001). Glomerular filtration rate loss in the 2 years before starting dialysis was the same between the 2 groups (-0.54+/-10.4 vs. 1.42+/-3.9 mL/min 1.73 m(2)). Age, sex, diabetes, other comorbidity, length of nephrology follow-up, eGFR at dialysis start, hemoglobin, and albumin were not significant. At our center, rapid loss of renal function in otherwise stable chronic kidney disease (CKD) patients is more important than late referral of CKD for the lack of access. Improvements in rapid referral for access creation could help reduce this barrier.     

Impulse-driven heated-droplet deposition interface for capillary and microbore LC-MALDI MS and MS/MS

An automated off-line liquid chromatography-matrix-assisted laser desorption ionization (LC-MALDI) interface capable of coupling both capillary and microbore LC separations with MALDI mass spectrometry (MS) and tandem mass spectrometry (MS/MS) has been developed. The interface is a combination of two concepts: analyte concentration from heated hanging droplets and impulse-driven droplet deposition of LC fractions onto a MALDI sample plate. At room temperature the interface allows the coupling of capillary LC separations (i.e., flow rate of <5 microL/min) with MALDI MS. With heating, it can be used to combine microbore LC operated at a relatively high flow rate of up to 50 microL/min with MALDI MS. The collected fractions can be analyzed by MALDI MS and MS/MS instruments, such as time-of-flight (TOF) and quadrupole-TOF MS. Performance of the interface was examined using several peptide and protein standards. It was shown that, using MALDI-TOF MS, [GLU1]-fibrinopeptide B could be detected with a total injection amount of 5 fmol to microbore LC. Chromatographic performance was also monitored. A peak width of 12 s at half-height for [GLU1]-fibrinopeptide B showed no evidence of band broadening due to the interface. The ability of the interface to mitigate ion suppression was studied using a mixture of 100 fmol of [GLU1]-fibrinopeptide B and 10 pmol of cytochrome c tryptic digest. Although fully suppressed under direct MALDI conditions, LC-MALDI analysis was able to detect the 100 fmol peptide with 10 s fraction collection. Finally, the ability to inject relatively large sample amounts to improve detectability of low-abundance peptides was illustrated in the analysis of phosphopeptides from alpha-casein tryptic digests. A digest loaded on column to 2.4 microg and analyzed by LC-MALDI MS/MS resulted in 82% sequence coverage and detection of all nine phosphoserine residues. It is concluded that, being able to handle both high- and low-flow LC separations, the impulse-driven heated-droplet interface provides the flexibility to carry out MALDI analysis of peptides and proteins depending on the information sought after, analysis speed, and sample size.     

Fabrication of electroabsorption optical modulators using laserdisordered GaInAs/GaInAsP multiquantum well structures

Electroabsorption optical modulators have been fabricated on GaInAs/GaInAsP multiquantum well structures whose bandgap had been increased by laser photoabsorption-induced disordering. Modulation depths of 20 dB have been obtained in material which has been bandgap blue shifted by as much as 120 nm, while samples shifted by 80 nm gave depths as high as 27 dB     

Advance measurement of gusts by laser anemometry

A coherent laser radar (or Doppler lidar) operating at a wavelength of 1.55 μm has been mounted on the nacelle of a 2.3 MW wind turbine in order to measure the wind speed in front of the blades at ranges up to 200 m. The lidar measures the component of wind speed along its beam direction but, since it rotates with the nacelle to point into the wind, this component normally differs negligibly from the actual wind speed. As an example to demonstrate the lidar's capabilities, we present samples of wind data gathered over an 18 h period in March 2003, illustrating the development of gusts that appears to be associated with the onset of solar ground heating. Wind speeds over the full period lay in the range 4-10 m s⁻¹, and the gusts were evident as a near-discontinuity in wind speed typically of order 1-2 m s⁻¹, but reaching values larger than 3 m s⁻¹. The typical timescale between gusts was of order 1 min. Improvements to this experiment are proposed that will provide more detailed information on spatial and temporal structure of such gusts.     

Monolithic integration in InGaAs-InGaAsP multiple-quantum-wellstructures using laser intermixing

The bandgap of InGaAs-InGaAsP multiple-quantum-well (MQW) material can be accurately tuned by photoabsorption-induced disordering (PAID), using a Nd:YAG laser, to allow lasers, modulators, and passive waveguides to be fabricated from a standard MQW structure. The process relies on optical absorption in the active region of the MQW to produce sufficient heat to cause interdiffusion between the wells and barriers. Bandgap shifts larger than 100 meV are obtainable using laser power densities of around 5 W·mm^-2 and periods of illumination of a few minutes to tens of minutes. This process provides an effective way of altering the emission wavelengths of lasers fabricated from a single epitaxial wafer. Blue shifts of up to 160 nm in the lasing spectra of both broad-area and ridge waveguide lasers are reported. The bandgap-tuned lasers are assessed in terms of threshold current density, internal quantum efficiency, and internal losses. The ON/OFF ratios of bandgap-tuned electroabsorption modulators were tested over a range of wavelengths, with modulation depths of 20 dB obtained from material which has been bandgap-shifted by 120 nm, while samples shifted by 80 nm gave modulation depths as high as 27 dB. Single-mode waveguide losses are as low as 5 dB·cm^-1 at 1550 mm. Selective-area disordering has been used in the fabrication of extended cavity lasers. The retention of good electrical and optical properties in intermixed material demonstrates that PAID is a promising technique for the integration of devices to produce photonic integrated circuits. A quantum-well intermixing technique using a pulsed laser is also demonstrated