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151.
152.
    
A UV‐curable polyurethane (PU)‐coating system containing phosphorus is formulated by the combination of photoinitiator, PU acrylate oligomer, and UV‐reactive phosphazene monomer. PU acrylate oligomer is prepared by the addition of 2‐hydroxyethylmethacrylate (HEMA) to NCO‐terminated PU prepolymer. UV‐reactive phosphazene monomer is derived from the HEMA substitution reaction to hexachlorocyclotriphosphazene (NPCl2)3. The curing reaction of this PU‐coating system is carried out by UV irradiation. The resultant UV‐cured PU‐coated films demonstrated better performance properties than those of original UV‐cured PU acrylate (UV‐PU) without UV‐reactive phosphazene monomer. Furthermore, their thermal properties are investigated by a thermogravimetric analyzer and a dynamic mechanical thermal analyzer, respectively. The combustion behaviors of these UV‐cured PU‐coated films are evaluated by the measurements of a limiting oxygen index and a cone calorimeter. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 1980–1991, 2002  相似文献   
153.
The stiffness of an elastic pivot, a kind of torsional hinge, must usually be small in the direction of axial rotation and high in all other directions. In some applications, such as the gimbal suspension of the tuned gyroscope in an inertial guidance system, the size of the elastic pivot is small, and consequently the pivot becomes very sensitive to machining error. In this paper, we model the machining error in terms of the position error and roll-pitch-yaw angle error of the electrode in the electric discharge machining process. In the corresponding design problem, we recommend design procedures that allow a compromise between product performance and manufacturability. This paper introduces different types of elastic pivots, analyzes machining error due to machining inaccuracy, and treats the shape optimization. We believe that the design-for-manufacturability methodology developed here will be helpful in the design of many other precision mechanical components.  相似文献   
154.
The migration behavior of C60 on Ni(111) has been inferred from its growth morphology at various substrate temperatures, as observed with scanning tunneling microscopy. The number density of islands increased and their average sizes decreased anomalously in the temperature range of approximately 573 K to approximately 973 K. This trend contradicts the prediction in conventional nucleation theory. At low and high temperatures, C60 commence nucleation on both sides of surface steps in a "bi-directional step flow" mode. However, anisotropy occurs within an intermediate temperature range, in which C60 nucleate predominantly at upper step edges. Surprisingly, in-situ growth measurements at this intermediate temperature range revealed that C60 actually start nucleating from lower step edges, with concomitant formation of Ni terraces underneath. These anomalous thermal dependence of diffusivity and the peculiar growth morphology of C60 on Ni(111) are attributed to C60-induced reconstruction of Ni(111) at higher temperature.  相似文献   
155.
Inorganic hole-transport layers (HTLs) are widely investigated in perovskite solar cells (PSCs) due to their superior stability compared to the organic HTLs. However, in p–i–n architecture when these inorganic HTLs are deposited before the perovskite, it forms a suboptimal interface quality for the crystallization of perovskite, which reduces device stability, causes recombination, and limits the power conversion efficiency of the device. The incorporation of an appropriate functional group such as sulfur-terminated surface on the HTL can enhance the interface quality due to its interaction with perovskite during the crystallization process. In this work, a bifunctional Al-doped CuS film is wet-deposited as HTL in p–i–n architecture PSC, which besides acting as an HTL also improves the crystallization of perovskite at the interface. Urbach energy and light intensity versus open-circuit voltage characterization suggest the formation of a better-quality interface in the sulfide HTL–perovskite heterojunction. The degradation behavior of the sulfide-HTL-based perovskite devices is studied, where it can be observed that after 2 weeks of storage in a controlled environment, the devices retain close to 95% of their initial efficiency.  相似文献   
156.
157.
    
Binary compound antimony sulfide (Sb2S3) with its nontoxic and earth‐abundant constituents, is a promising light‐harvesting material for stable and high efficiency thin film photovoltaics. The intrinsic quasi‐1D (Q1D) crystal structure of Sb2S3 is known to transfer photogenerated carriers rapidly along the [hk1] orientation. However, producing Sb2S3 devices with precise control of [hk1] orientation is challenging and unfavorable crystal orientations of Sb2S3 result in severe interface and bulk recombination losses. Herein, in situ vertical growth of Sb2S3 on top of ultrathin TiO2/CdS as the electron transport layer (ETL) by a solution method is demonstrated. The planar heterojunction solar cell using [hk1]‐oriented Sb2S3 achieves a power conversion efficiency of 6.4%, performing at almost 20% higher than devices based on a [hk0]‐oriented absorber. This work opens up new prospects for pursuing high‐performance Sb2S3 thin film solar cells by tailoring the crystal orientation.  相似文献   
158.
    
We expose a fundamental limitation of the self-tuning procedure for adaptive control of linear stochastic systems. Specifically, if the cost criterion measuring the performance of the unknown system is anything other than a minimum (output) variance criterion, then the procedure of estimating the unknown parameters of the linear system and then applying a control input which is optimal for the given cost criterion and the parameter estimates, will not self-tune to the optimal control law. Since our arguments are based on the analysis of an ordinary differential equation of Ljung, and since we do not, in our general context, have a proof that this O.D.E. represents the asymptotic behaviour of the system, further work is needed. An exception to the above situation is the class of systems with a large enough delay, for which self-tuning to the optimal, and indeed, convergence to the true parameters, cannot be ruled out.  相似文献   
159.
The objective of this study was to determine the die swell behavior of a polymer melt and to design a die for forming a polymeric extrudate with a desired shape using profile extrusion. Polystyrene pellets were chosen to perform the profile extrusion experiments. First, the polystyrene pellets were melted and pushed through a quarter ring profile. The profile of the swelled extrudate agreed with the numerical predictions. A modified die was designed to produce a quarter ring profile extrudate based on the direct extrusion problem (DEP) prediction. Polystyrene pellets were also melted and pushed through the modified die. The experimental results were close to the computational results. The melting temperature, die length, and melting residence time affect die swell behavior. The die swell ratio becomes smaller as the melting temperature and melting residence time are increased. As the die length is increased, the die swell ratio is lowered. According to the die geometry predictions, an extrudate with the desired profile can be made precisely.  相似文献   
160.
    
The existing IEEE802.11 a/b/g/n provides robust and relatively low cost wireless services but there only provide best effort services. IEEE802.11e provides Quality of service (QoS) to the real time applications but the bandwidth distribution is controlled by the IEEE802.11e and network administrator has no controls over the QoS mechanisms. We propose a non-disruptive and yet low-cost QoS and Fairness provisioning solution over existing best-effort WLAN networks with an Adaptive layer-3 buffer management (AL3BM) Scheme for small domestic wireless network. The existing WLAN networks or hotspots can continue their operation without any major disruption or costly upgrade. AL3BM is implemented in a network router that sits between the wired and wireless network to control the heavy downlink traffic. The network administrator can partially controls the bandwidth allocation through the AL3BM. Simulations have been carried out to examine the proposed scheme in providing services differentiation, and fairness. The simulation results show that AL3BM improves the performance of the wireless end users. Hardware testbed is configured and the experimental results show that AL3BM provides QoS to the WLAN.  相似文献   
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