Bio-Synthesized Nanoparticles in Developing Plant Abiotic Stress Resilience: A New Boon for Sustainable Approach

Agriculture crop development and production may be hampered in the modern era because of the increasing prevalence of ecological problems around the world. In the last few centuries, plant and agrarian scientific experts have shown significant progress in promoting efficient and eco-friendly approaches for the green synthesis of nanoparticles (NPs), which are noteworthy due to their unique physio-biochemical features as well as their possible role and applications. They are thought to be powerful sensing molecules that regulate a wide range of significant physiological and biochemical processes in plants, from germination to senescence, as well as unique strategies for coping with changing environmental circumstances. This review highlights current knowledge on the plant extract-mediated synthesis of NPs, as well as their significance in reprogramming plant traits and ameliorating abiotic stresses. Nano particles-mediated modulation of phytohormone content in response to abiotic stress is also displayed. Additionally, the applications and limitations of green synthesized NPs in various scientific regimes have also been highlighted.     

Microstructure and electrochemical properties of melt-spun Nd_(0.8)Mg_(0.2)(Ni_(0.8)Co_(0.2))_(3.8) hydrogen storage alloy

The effects of rapid solidification on the microstructure and electrochemical properties of Nd0.8Mg0.2(Ni0.8Co0.2)3.8 alloy were systematically investigated.The microstructure of alloys was characterized by scanning electron microscopy(SEM),X-ray diffractometer(XRD) and transmission electron microscopy(TEM).It was found that the melt-spun Nd0.8Mg0.2(Ni0.8Co0.2)3.8 ribbons became thinner and the average grain size of the ribbons became smaller with increasing wheel speed.A fraction of amorphous phase was observed for the ribbons melt-spun at high wheel speed(≥20 m/s).Microstructural characterization revealed that two phases:(Nd,Mg)2(Ni,Co)7 main phase(Ce2Ni7 type structure) and NdNi5 second phase(CaCu5 type structure),existed in the samples in cast state and melt-spun.The cycle stability of the melt-spun alloys was significantly enhanced as compared with cast alloy,and the sample prepared at wheel speed of 20 m/s exhibited good comprehensive electrochemical properties.     

On comparison of experimental and calculated neutron energy flux spectra at miniature neutron source reactor (MNSR)

Neutron energy spectrum in Miniature Neutron Source Reactor (MNSR), called Pakistan Research Reactor (PARR-2), is measured employing threshold neutron activation detectors. The calculated neutron spectrum was obtained through modeling the core in detail in three-dimensions employing the transport theory based code WIMS-D/4 and the diffusion theory based code CITATION which was also used as pre-information in the adjustment procedure. A Number of threshold detectors in the form of thin foils are used for spectrum measurements. Gamma activity of irradiated foils was measured with the help of a gamma spectroscopic system consisting of a high efficiency HPGe detector and 8000 channels PC based multi-channel analyzer. STAYNL computer code supplied by International Atomic Energy Agency (IAEA) was used for neutron spectrum adjustment. The group cross-section values and their covariance matrices were derived from the data given in preprocessed cross section libraries in ENDF–6 format of IRDF-90/NMF-G. The comparison between theoretical and experimental work shows good agreement.     

Statistical optimization of dilute acid pretreatment of pinus needles to be used as substrate for biofuel production

In this study response surface methodology (RSM) was applied to study the effect of H₂SO₄ concentration, temperature, and time on the production of reducing sugars, total sugars, and total phenolic compounds from pine needles. Three variables with three levels showed that maximum release of total phenolic compounds (31.20 ± 0.002 mM) was observed at 1% H₂SO₄ concentration, 130°C temperature for 75 min of residence time. Under these conditions, the predicted value of total phenolic compounds was 31.27 mM, which indicated that the model is valid, having negligible variation in observed and predicted values. These results suggested that this substrate could be potentially used as substrate for bioethanol production.     

Robustness and performance parameterization of smooth second order sliding mode control

Novel robustness and performance parameters are established for Smooth Super Twisting Algorithm (SSTA). The stability of SSTA is well established for arbitrary gains using homogeneity approach. The design and tuning of the controller parameters is a major issue and no analytic design method is available so far. A novel Lyapunov function is proposed and by the virtue of stability analysis, the stability bounds for a certain class of uncertainties are determined. In addition, the issue of finite time convergence is also explored, resulting in determination of the settling time as a function of the controller parameters. The proposed settling time formulation suggests a methodical approach to SSTA design in contrast to the available rules of thumb. Unlike the literature available for Higher Order Sliding Mode (HOSM) controllers, the proposed design framework is validated against a challenging problem of the Underground Coal Gasification (UCG) process control. Like the other process control problems the chosen problem is nonlinear and contains significant uncertainties.