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981.
Large-scale, freestanding, porous structures of vanadium pentoxide nanobelts (VPNs) were successfully prepared using the template-free freeze-drying method. The porous and multi-layered VPN macrostructures are composed of randomly oriented long nanobelts (over 100 μm) and their side length can be controlled up to a few tens of centimetres. Also, the bulk density and surface area of these macrostructures are 3-5 mg cm(-3) and 40-80 m(2) g(-1), respectively, which are similar to those of the excellent adsorbents. In addition, the removal efficiency measurements of ammonia molecules revealed that the VPN porous structures can adsorb the ammonia molecules with the combinations of van der Waals forces and strong chemical bonding by functional groups on the VPN surface. 相似文献
982.
Ho-chan Kim In Hwan Lee Tae Jo Ko 《The International Journal of Advanced Manufacturing Technology》2012,58(1-4):175-186
Recently, a new microengraving technology, microabrasive jet machining, has been studied as a machining technology for highly brittle materials. The technology implements the machining by using an abrasive jet and it uses mask structures to achieve microscale geometrical accuracy. The mask structure selectively blocks the abrasive jet at the portions of the surface that are not to be machined. Modeling and fabrication of the mask structure are thus key processes in microabrasive jet machining. Microstereolithography is believed to be a better means of mask fabrication for general planar and nonplanar workpieces. However, it is not easy to model a precise 3D mask structure from a given pattern image. Because of inconsistencies between the computer-aided design (CAD) model and the actual workpiece, mask structures modeled from workpiece CAD models often fall off. We therefore propose an automated modeling algorithm for the corresponding 3D nonplanar mask structure by using measured geometry directly. The algorithm takes the workpiece geometry as section images acquired from computer tomography and generates the CAD mask model directly from the section and mask images. Application software was developed to verify the algorithm and was tested by verification and actual cases. 相似文献
983.
984.
Process modeling of hybrid machining system consisted of electro discharge machining and end milling
Jean Bosco Byiringiro Min Yeop Kim Tae Jo Ko 《The International Journal of Advanced Manufacturing Technology》2012,61(9-12):1247-1254
This paper presents a novel hybrid machining process (HMP) that combines cutting action with machining using discharge pulses. Working conditions for a machine tool capable of combining micro-electro discharge machining (EDM) with milling is still an ill-defined problem relying on heuristics because there is insufficient knowledge of the discharge mechanism and the effects of machining parameters. The proposed HMP that combines micro-EDM and milling processes was applied to a steel alloy (AISI 1045) as the workpiece and end mill tungsten carbide as the tool electrode. Test results obtained from a number of experiments showed that the developed HMP yields reasonable machining time and surface roughness. Significant controlling variables for the machining response were identified and ranked using the Taguchi method. Furthermore, the response surface method was used to develop an empirical model based on the correlation between input variables and output responses. 相似文献
985.
986.
Peptide/protein aggregation is implicated in many amyloid diseases. Some amyloidogenic peptides/proteins, such as those implicated in Alzheimer’s and Parkinson’s diseases, contain multiple amyloidogenic domains connected by “linker” sequences displaying high propensities to form turn structures. Recent studies have demonstrated the importance of physicochemical properties of each amino acid contained in the polypeptide sequences in amyloid aggregation. However, effects on aggregation related to the intramolecular distance between amyloidogenic domains, which may be determined by a linker length, have yet to be examined. In the study presented here, we created peptides containing two copies of KFFE, a simple four-residue amyloidogenic domain, connected by GS-rich linker sequences with different lengths yet similar physicochemical properties. Our experimental results indicate that aggregation occurred most rapidly when KFFE domains were connected by a linker of an intermediate length. Our experimental findings were consistent with estimated entropic contribution of a linker length toward formation of (partially) structured intermediates on the aggregation pathway. Moreover, inclusion of a relatively short linker was found to inhibit formation of aggregates with mature fibril morphology. When the results are assimilated, our study demonstrates that intramolecular distance between amyloidogenic domains is an important yet overlooked factor affecting amyloid aggregation. 相似文献
987.
Ko HH Chen HT Yen FL Lu WC Kuo CW Wang MC 《International journal of molecular sciences》2012,13(2):1658-1669
The preparation of TiO(2) nanocrystallite powders coated with and without 9 mol% ZnO has been studied for cosmetic applications in sunscreens by a co-precipitation process using TiCl(4) and Zn(NO(3))(2)·6H(2)O as starting materials. XRD results show that the phases of anatase TiO(2) and rutile TiO(2) coexist for precursor powders without added ZnO (T-0Z) and calcined at 523 to 973 K for 2 h. When the T-0Z precursor powders are calcined at 1273 K for 2 h, only the rutile TiO(2) appears. In addition, when the TiO(2) precursor powders contain 9 mol% ZnO (T-9Z) are calcined at 873 to 973 K for 2 h, the crystallized samples are composed of the major phase of rutile TiO(2) and the minor phases of anatase TiO(2) and Zn(2)Ti(3)O(8). The analyses of UV/VIS/NIR spectra reveal that the absorption of the T-9Z precursor powders after being calcined has a red-shift effect in the UV range with increasing calcination temperature. Therefore, the TiO(2) nanocrystallite powders coated with 9 mol% ZnO can be used as the attenuate agent in the UV-A region for cosmetic applications in sunscreens. 相似文献
988.
Hyun Seung Lee Ko Hoon Kim Sung Hwan Kim Jae Nyoung Kim 《Advanced Synthesis \u0026amp; Catalysis》2012,354(13):2419-2426
An efficient synthesis of tetrasubstituted olefins was achieved via a palladium‐catalyzed, chelation‐assisted oxidative Heck arylation protocol from trisubstituted olefins bearing a tether with a directing group in a completely stereo‐ and regioselective manner. The stereo‐ and regioselectivity as well as excellent yields of tetrasubstituted olefins originated from the stabilization of a palladium intermediate by chelation between the palladium center and a directing group. 相似文献
989.
Baran Can Sağlam Sibel Koçak Mustafa Murat Koçak ÖZgür Topuz 《Microscopy research and technique》2012,75(11):1534-1538
The aim of this study was to evaluate the effects of sodium hypochlorite (NaOCl), chlorhexidine digluconate (CHX), and mixture of tetracycline, citric acid, and detergent (MTAD) solutions on the surfaces of nickel titanium (NiTi) rotary files with scanning electron microscopy (SEM) and atomic force microscopy (AFM). Irrigation solutions including 2.5% NaOCl, 5% NaOCl, 2% CHX, and MTAD were used. Four new ProTaper rotary NiTi files (F3) were immersed in each four irrigation solutions for 10 min, separately. One untreated NiTi file was used as a control specimen. The surface analysis was performed with SEM and AFM. The surface analysis in AFM was performed on 12 different regions located between first and second millimeters from the tip. SEM images were taken with different magnifications. No surface alteration was recorded under SEM evaluation. AFM revealed that the root mean square (RMS) values of all treated specimens were statistically higher than the control sample (P < 0.05). The sample which was treated with CHX showed lowest RMS values in test groups. All tested solutions caused surface alterations. CHX demonstrated limited surface alterations when compared to the other tested solutions. Microsc. Res. Tech. © 2012 Wiley Periodicals, Inc. 相似文献
990.
Allyl isothiocyanate (AITC) is a well-recognized antimicrobial agent but, application of AITC to food systems is limited due to its high volatility and strong odor. This study was performed to overcome the volatility of AITC by encapsulation using gum Arabic and chitosan and to investigate the effect of microencapsulated AITC as a natural additive on the shelf-life and quality of Kimchi. AITC loaded microparticles were prepared using gum Arabic and chitosan and were added to Kimchi at various concentrations (0-0.02%, w/w). The titratable acidity, pH, microbial changes, and sensory test of Kimchi were examined for 15days at different fermentation temperatures (4 and 10°C). The pH of Kimchi containing AITC microparticles was significantly higher than that of control and the higher the quantity of added AITC, the higher the pH became. The titratable acidity of Kimchi increased during storage especially, titratable acidity of control increased significantly higher than those of Kimchi with added AITC microparticles. The number of Leuconostoc and Lactobacillus species in Kimchi decreased with an increase in the concentration of AITC. The addition of AITC induced reduction of sour taste and improvement of the texture of Kimchi during fermentation. However, as the content of AITC increased, the scores of overall acceptability decreased due to the odor of AITC. These results indicate that addition of AITC (less than 0.1%) to Kimchi is an effective way of enhancing the shelf-life of Kimchi without reducing quality. 相似文献