Simultaneous sulfide and acetate oxidation under denitrifying conditions using an inverse fluidized bed reactor

BACKGROUND: Simultaneous removal of sulfur, nitrogen and carbon compounds from wastewaters is a commercially important biological process. The objective was to evaluate the influence of the CH₃COO^?/NO₃^? molar ratio on the sulfide oxidation process using an inverse fluidized bed reactor (IFBR). RESULTS: Three molar ratios of CH₃COO^?/NO₃^? (0.85, 0.72 and 0.62) with a constant S^2?/NO₃^? molar ratio of 0.13 were evaluated. At a CH₃COO^?/NO₃^? molar ratio of 0.85, the nitrate, acetate and sulfide removal efficiencies were approximately 100%. The N₂ yield (g N₂ g^?1 NO₃^?‐N consumed) was 0.81. Acetate was mineralized, resulting in a yield of 0.65 g inorganic‐C g^?1 CH₃COO^?‐C consumed. Sulfide was partially oxidized to S⁰, and 71% of the S^2? consumed was recovered as elemental sulfur by a settler installed in the IFBR. At a CH₃COO^?/NO₃^? molar ratio of 0.72, the efficiencies of nitrate, acetate and sulfide consumption were of 100%, with N₂ and inorganic‐C yields of 0.84 and 0.69, respectively. The sulfide was recovered as sulfate instead of S⁰, with a yield of 0.92 g SO₄^2?‐S g^?1 S^2? consumed. CONCLUSIONS: The CH₃COO^?/NO₃^? molar ratio was shown to be an important parameter that can be used to control the fate of sulfide oxidation to either S⁰ or sulfate. In this study, the potential of denitrification for the simultaneous removal of organic matter, sulfide and nitrate from wastewaters was demonstrated, obtaining CO₂, S⁰ and N₂ as the major end products. Copyright © 2008 Society of Chemical Industry     

Ni/Pillared Clays as Catalysts for the Selective Catalytic Reduction of Nitrogen Oxides by Propene

Different and alternative methods for the preparation of Ni/pillared clays based on impregnation and encapsulation procedures are reported. Several nickel precursors and metal loadings are considered in order to evaluate their influence on the structural, textural and catalytic properties of the resulting solids. The behaviour of the optimum solids as catalysts has been proved in the selective catalytic reduction of nitrogen oxides with propene, and the relevance of the oxidant nature was checked by changing the composition of the oxidant mixture. Of all the factors studied, the nature of the nickel precursors appears as the most important one, owing to the formation of different active nickel species during the synthesis procedure.     

New technical facilities for equipping power industry plants with automatic control systems

The specific features of SPPA-T3000, a new instrumentation and control system intended for automation of processes in power engineering, are briefly described. Distinctive features of the system architecture, central to which is using the model of web systems, are singled out.     

Semi-solid rapid compression testing of spray-formed hypereutectic Al-Si alloys

The rheology of Al-30Si-5Cu and Al-30Si-5Cu-2Mg spray-formed alloys has been characterized after holding at various times and temperatures, using semisolid rapid compression to obtain load-displacement curves. Microstructures were examined after partial remelting and compression in an attempt to understand the flow behavior. The initial resistance to flow generally increased with holding time at temperature. This increase was attributed to the increased strength of a three-dimensional (3-D) solid silicon network present in these alloys in the semisolid state, with the initial resistance to flow smaller in the magnesium-containing alloys. With increased temperature, the initial resistance decreased due to increased liquid content and grain spheroidization. The viscosity vs shear rate response was studied using the approach of Laxmanan and Flemings. The materials shear thinned rapidly during the test conditions, in which the shear rate rapidly increased from approximately 2.5 to 92 s⁻¹. The results were fitted to a power-law model, and the viscosities showed a drop of approximately two to four orders of magnitude when extrapolated to a shear rate of 1000 s⁻¹ (a typical value in actual component manufacture). The rapid compression test, which is close to conditions present in component manufacture, was shown to have more in common with a shear rate jump experiment, rather than steady-state viscometry.     

Hiding biometric data

With the wide spread utilization of biometric identification systems, establishing the authenticity of biometric data itself has emerged as an important research issue. The fact that biometric data is not replaceable and is not secret, combined with the existence of several types of attacks that are possible in a biometric system, make the issue of security/integrity of biometric data extremely critical. We introduce two applications of an amplitude modulation-based watermarking method, in which we hide a user's biometric data in a variety of images. This method has the ability to increase the security of both the hidden biometric data (e.g., eigen-face coefficients) and host images (e.g., fingerprints). Image adaptive data embedding methods used in our scheme lead to low visibility of the embedded signal. Feature analysis of host images guarantees high verification accuracy on watermarked (e.g., fingerprint) images.     

Standby power system VRLA battery reserve life estimation scheme

This paper presents a valve-regulated lead acid (VRLA) battery reserve life estimation scheme. The scheme is adaptive in both type and frequency of involvement. The scheme is based on capacity trending with the support of a number of state-of-health (SOH) indicators. These SOH indicators include accumulated thermal stress, float voltage, and indicators acquired from the start-of-discharge (coup de fouet) region. An implementation test case is given, indicating that the scheme is capable of providing an accurate estimation of reserve life long before the end of life. Furthermore, the estimation accuracy improves as the end of battery life approaches.     

Effect of Thin Film Thicknesses and Materials on the Response of RTDs and Microthermocouples

Fabrication and thermal characterization of a resistance temperature detector (RTD) heater and microthermocouples (MTs) on silicon substrates have been reported in this paper. The influence of film thickness and nickel-gold (Au) electroplating on RTD on its steady-state temperature with respect to its steady-state electrical power input and resistance is studied. Further, the thermal effects of multiple thermocouples in a thermopile as well as the effects of Au layers in the contact pads of the thermopiles on their open-circuit Seebeck voltage are studied. Therein lies the novelty of this paper. The in situ operating relationships for the RTD heater and the MT are provided     

Logistic Regression Analysis of Customer Satisfaction Data

Variation exists in all processes. Significant work has been done to identify and remove sources of variation in manufacturing processes resulting in large returns for companies. However, business process optimization is an area that has a large potential return for a company. Business processes can be difficult to optimize due to the nature of the output variables associated with them. Business processes tend to have output variables that are binary, nominal or ordinal. Examples of these types of output include whether a particular event occurred, a customer's color preference for a new product and survey questions that assess the extent of the survey respondent's agreement with a particular statement. Output variables that are binary, nominal or ordinal cannot be modeled using ordinary least‐squares regression. Logistic regression is a method used to model data where the output is binary, nominal or ordinal. This article provides a review of logistic regression and demonstrates its use in modeling data from a business process involving customer feedback. Copyright © 2006 John Wiley & Sons, Ltd.