Structural effects on the interactions of benzene and naphthalene sulfonates with activated carbon cloth during adsorption from aqueous solutions

Interactions of benzene and naphthalene sulfonates with activated carbon cloth (ACC) during adsorption from aqueous solutions were investigated. Systematically chosen sulfonates were sodium salt of benzene sulfonic acid (NaBS), disodium salt of 1,3-benzene disulfonic acid (Na₂BDS), sodium salt of 1-naphthalene sulfonic acid (NaNS), disodium salt of 1,5-naphthalene disulfonic acid (Na₂NDS) and trisodium salt of 1,3,(6 or 7)-naphthalene trisulfonic acid (Na₃NTS). The adsorption behaviors of these adsorbates from solutions in water and in 0.01 M H₂SO₄ onto the ACC were monitored by in-situ UV–visible spectroscopic technique. The order of rates and extents of adsorption of sulfonates were explained in terms of acidity of the medium and structural factors influencing the interactions between sulfonates and the ACC surface. Kinetic data of adsorption were treated according to pseudo first-order, pseudo second-order, Elovich and intra-particle diffusion models. The best model representing the experimental kinetic data was found to be the pseudo second-order model. Adsorption isotherms of the sulfonates onto the ACC were derived at 30 °C. Isotherm data were found to fit the Freundlich model better than the Langmuir model.     

Kinetic and equilibrium studies on the removal of acid dyes from aqueous solutions by adsorption onto activated carbon cloth

Removal of acid dyes Acid Blue 45, Acid Blue 92, Acid Blue 120 and Acid Blue 129 from aqueous solutions by adsorption onto high area activated carbon cloth (ACC) was investigated. Kinetics of adsorption was followed by in situ UV-spectroscopy and the data were treated according to pseudo-first-order, pseudo-second-order and intraparticle diffusion models. It was found that the adsorption process of these dyes onto ACC follows the pseudo-second-order model. Adsorption isotherms were derived at 25 degrees C on the basis of batch analysis. Isotherm data were treated according to Langmuir and Freundlich models. The fits of experimental data to these equations were examined.     

Effects of Ozone Treatment on Microbiological Quality and Physicochemical Properties of Turkey Breast Meat

ABSTRACT

The effects of ozone treatment (1 × 10^?2 kg m^?3, for up to 8 h) on quality parameters of turkey meat were investigated. Ozone was effective in inactivating microorganisms. Approximately 2.9, 2.3 and 1.9 log reductions were achieved in the counts of total aerobic mesophilic bacteria, Enterobacteriaceae and yeast-mold, respectively. Ozone caused significant changes in carbonyl contents, thiobarbituric acid reactive substances, color and pH values of the samples. Water holding capacity and cooking yield of treated samples increased significantly (p < .05). This is the first report demonstrating that quality parameters of turkey breast meat are markedly affected by ozone treatment.     

A systematic study on the changes in properties of an activated carbon cloth upon polarization

The effects of polarization on properties of activated carbon cloth (ACC) have been investigated systematically. The polarization-treated ACC samples were prepared by polarizing them in Na₂SO₄ or KH₂PO₄/KOH buffer solutions at potentials from −1.5 to 5.0 V. The properties, such as surface area, pore size distribution (PSD), total pore volume, amount and nature of the surface functional groups and surface acidity, of pristine and polarization-treated ACC samples were determined. The samples were also characterized electrochemically by determining the properties such as specific capacitance and potential at point of zero charge (E_PZC). Anodic polarization in different electrolytes was found to cause oxidation on ACC. Although the surface textural properties did not change considerably, the changes took place in chemical and electrochemical properties upon anodic polarization were found to be important. The increase in surface acidity shifted the pH_PZC from 7.40 to 3.21 and E_PZC from 164 to 355 mV. The optimum potential range, considered to be safe for polarization of ACC, was determined as −1.5 to +0.8 V.     

Analyzing lifetime of energy harvesting underwater wireless sensor nodes

Underwater Wireless Sensor Networks (UWSNs) are utilized to monitor underwater environments that pose many challenges to researchers. One of the key complications of UWSNs is the difficulty of changing node batteries after their energy is depleted. This study aims to diminish the issues related to battery replacement by improving node lifetime. For this goal, three energy harvesting devices (turbine harvester, piezoelectric harvester, and hydrophone harvester) are analyzed to quantitate their impacts on node lifetime. In addition, two different power management schemes (schedule‐driven and event‐driven power management schemes) are combined with energy harvesters for further lifetime improvement. Performance evaluations via simulations show that energy harvesting methods joined by power management schemes can improve node lifetime substantially when actual conditions of Istanbul Bosporus Strait are considered. In this respect, turbine harvester makes the biggest impact and provides lifetime beyond 2000 days for most cases, while piezoelectric harvester can perform the same only for low duty cycle or event arrival values at short transmission ranges.     

Lipid oxidation inhibiting capacities of blackseed essential oil and rosemary extract

Lipid oxidation is the main deterioration process that occurs in vegetable oils containing lipid molecules with polyunsaturation. The aim of the present study was to investigate the possible effects of blackseed (Nigella sativa L.) essential oil (BEO) and rosemary (Rosmarinus officinalis L.) extract (RE) on stabilization of sunflower oil under accelerated storage conditions. RE was obtained by soxhlet extraction using methanol, whereas BEO was hydrodistilled from the blackseed extract obtained by extraction using petroleum ether (b.p. 40–60°C). The results indicate that both extracts stabilize sunflower oil to a certain extent, the extent being greater with RE than with BEO based on measurements of peroxide value, p‐anisidine value, amount of nonoxidized linoleic acid in saponified oil samples by HPLC‐DAD, concentration of conjugated diene hydroperoxide, and UV light absorption. The oil stabilizing effect of BEO against lipid oxidation, especially at concentrations of 0.06 and 0.1 g/100 g oil was found to increase as the temperature increased, according to principal component analysis results. Based on its strong lipid oxidation inhibiting capacity, RE can be used as a potential natural extract for stabilizing sunflower oil against oxidation. BEO, at carefully selected concentrations, can be suggested as an alternative supplement of plant origin for improving oil stabilization. Practical applications: Sunflower oil is a widely used vegetable oil for cooking and frying, and has a high linoleic acid content of about 40–70%. Here we show that sunflower oil can be stabilized by adding rosemary and blackseed extracts. The treatment can be useful especially in applications which require heating the oil to high temperatures.     

Effect of dispersed phase feed time on the droplet size of Pickering emulsions produced in a stirred tank

The aim of this study was to investigate the effect of feed time of the oil phase on the average droplet size of Pickering emulsions produced in stirred tanks. Three types of impellers were tested: RT, up-pumping PBT (PBTU), and down-pumping PBT (PBTD). All the impellers were tested at two sizes, T/3 and T/2. All configurations were compared at constant tip speed, power per mass, and impeller Reynolds number. The droplet diameters were measured in Mastersizer® 3,000 (Malvern). The results showed that an increase in feed time causes a reduction in the average droplet size. At lower impeller speeds and higher feed times, the effect is more pronounced. It was found that some other geometric parameters also have an impact on the average droplet size.     

A new active position sensing method for ropeless elevator

Traditional cable driven elevators perform poorly in high-rise buildings because the weight of the cable limits the payload, and its elasticity degrades control performance. Further, it is not mechanically possible to include several elevator cars in the same hoistway because of the cable. However such multi-car elevator systems are desirable since they reduce passenger waiting time and reduce the space requirements of the elevator system. A promising solution is to use long armature linear motors spanning the hoistway to directly drive elevator cages. In such applications, the mover position sensing method must be explicitly addressed since most active position sensing methods require traveling cables, which are also an obstacle for multi-car elevator systems.In this paper, the linear-motor active position sensing method is formally introduced and the principle of operation, design and real-time operation methods are presented. The proposed method is used to measure the position of the mover of a long armature permanent magnet linear synchronous motor requiring no active components on the mover, thus traveling cables are eliminated. The principle of operation is inspired by linear variable differential transformer: A magnetic shunt positioned at a fixed distance ahead of the mover deforms the magnetic field created by one of the armature coils. The deformation can be determined by measuring the induced voltages on the neighboring coils, and the position of the shunt, and thus the mover, can be calculated.A design method for the optimal dimensions of the shunt for a given armature to provide long measurement range and small maximum position error is presented, accompanied by a real-time measurement algorithm that will enable the motor to be driven using the method. Finally the method is verified by simulations and experimental results conducted on a full scale linear-motor elevator prototype that was constructed in the laboratory.     

Dynamic bitrate allocation of interactive real-time streamed multi-view video with view-switch prediction

In multi-view video (MVV), the real-world scene is usually captured by more than two cameras positioned in an array. A viewer can consume MVV using either a non-interactive or an interactive transmission method. In the context of interactive MVV streaming, view switching may cause a long delay due to the frequent requests by the viewer. In this paper, we consider the use case of real-time interactive MVV (IMVV) streaming, where the view switching delay problem has a significant user experience impact. Our proposed method compress and send all the captured views using a dynamic bitrate allocation method. Also, a novel prediction algorithm has been used to choose possible views that the user might switch to. The predicted view switching is mapped to a hidden Markov model, and the transition probability is solved using Zipf distribution. The experimental results of the proposed method show a superior performance on an objective metric and view-switching delay for better viewing quality over the existing method.     

A kinetic study of oxidation development in sunflower oil under microwave heating: Effect of natural antioxidants

The antioxidative effects of carnosic acid and sesamol on sunflower oil under temperature-controlled microwave heating were investigated as a function of time and temperature. The concentration of conjugated diene hydroperoxide and p-anisidine value were determined spectrophotometrically, as measures of oxidation, during microwave heating of sunflower oil with or without added antioxidants at 40 °C, 60 °C and 80 °C. The kinetics of hydroperoxide formation was examined on the basis of previously proposed mechanisms and found to be of the half-order with respect to the concentration of conjugated diene hydroperoxide. The amounts of added antioxidants remaining in sunflower oil after different microwave heating periods at different temperatures were determined by HPLC-DAD. The results were interpreted in terms of antioxidative effects of carnosic acid and sesamol. Carnosic acid was found to be a more effective antioxidant than sesamol for sunflower oil.