A mass balance model describing multiyear fate of organochlorine compounds in a high Arctic lake

Data collected over a 3-year study of a high arctic watershed and lake are used to understand the fate of organochlorine compounds (OCs) and form the basis of a mass balance contaminant fate model. The model uses the fugacity/aquivalence approach to describe OC dynamics between air, stream inflows and outflow, the water column, and surficial sediments. The steady-state model results indicate that stream inflows contributed from 96 to >99% of total chemical loadings, but 57-98% of total loadings were lost from the lake via the outlet, the percentage of which is controlled by the hydrologic regime of the high arctic lake. Conversely, only 0.4-3.4% of loadings were retained within the sediments due to the high export rate, minimal scavenging from the water column and low organic carbon fraction of the sediments. Using the unsteady-state model, which includes year-round processes, degradation was estimated to account for losses of 7-32% for the more persistent OCs and 42-50% for the less persistent OCs (alpha-HCH, gamma-HCH, and endosulfan I). If loadings were eliminated, water column concentrations would decline with half-lives <1 year for less persistent OCs and 1-2 years for the more persistent OCs, whereas the half-lives for OCs in sediment are 8-25 years.     

Anomalous Resistance Hysteresis in Oxide ReRAM: Oxygen Evolution and Reincorporation Revealed by In Situ TEM

The control and rational design of redox‐based memristive devices, which are highly attractive candidates for next‐generation nonvolatile memory and logic applications, is complicated by competing and poorly understood switching mechanisms, which can result in two coexisting resistance hystereses that have opposite voltage polarity. These competing processes can be defined as regular and anomalous resistive switching. Despite significant characterization efforts, the complex nanoscale redox processes that drive anomalous resistive switching and their implications for current transport remain poorly understood. Here, lateral and vertical mapping of O vacancy concentrations is used during the operation of such devices in situ in an aberration corrected transmission electron microscope to explain the anomalous switching mechanism. It is found that an increase (decrease) in the overall O vacancy concentration within the device after positive (negative) biasing of the Schottky‐type electrode is associated with the electrocatalytic release and reincorporation of oxygen at the electrode/oxide interface and is responsible for the resistance change. This fundamental insight presents a novel perspective on resistive switching processes and opens up new technological opportunities for the implementation of memristive devices, as anomalous switching can now be suppressed selectively or used deliberately to achieve the desirable so‐called deep Reset.     

Time correlated fluorescence characterization of an asymmetrically focused flow in a microfluidic device

In this study, we explore and model the behavior of a prototype microfluidic device which employs two non-mixing fluids (sheath and inlet fluids) displaying an asymmetric focused flow, in the presence of a fluorescent dye. Fluorescence correlation spectroscopy is employed, allowing the precise measure of flow speeds across the channels and of the concentration profile of the central focused flux along the flow direction. The system is modeled via a standard Navier–Stokes finite-element approach, coupled to convection–diffusion equations for the solute. Simulations reproduce accurately the shape, the position, and the width of the velocity and concentration profiles along the central channel and across the transversal and vertical sections of the microfluidic device. The observed asymmetric flow with respect to the center of the channel is reproduced numerically with an error in the position determination smaller than 1%.     

Semi-physical identification of dynamic properties in a thermohydraulic channel

The aim of this work is to investigate whether it is possible to extract information from process noise measurements by combining physical knowledge with system identification methods. This could be used for implicit measurements of process variables, tuning the model in a multidimensional parameter space, or simply for increasing our knowledge of the dynamical process, for example BWR stability.     

Database Repairs and Analytic Tableaux

In this article, we characterize in terms of analytic tableaux the repairs of inconsistent relational databases, that is databases that do not satisfy a given set of integrity constraints. For this purpose we provide closing and opening criteria for branches in tableaux that are built for database instances and their integrity constraints. We use the tableaux based characterization as a basis for consistent query answering, that is for retrieving from the database answers to queries that are consistent with respect to the integrity constraints.     

Tableau-based characterization and theorem proving for default logic

In this paper, we present a new method for computing extensions and for deriving formulae from a default theory. It is based on the semantic tableaux method and works for default theories with a finite set of defaults that are formulated over a decidable subset of first-order logic. We prove that all extensions (if any) of a default theory can be produced by constructing the semantic tableau ofone formula built from the general laws and the default consequences. This result allows us to describe an algorithm that provides extensions if there are any, and to decide if there are none. Moreover, the method gives a necessary and sufficient criterion for the existence of extensions of default theories with finitely many defaults provided they are formulated on a decidable subset of FOL.This work was completed while the author was at CNRS, Marseille.     

Regional business cycles in Italy

There is clear evidence for differences in the structure of the Italian regional business cycle in the period 1951-2004: the relationship with the national business cycle is closer in the North than in the South. The interaction between regional cycles shows considerable variation over time. There is a change in the timing of the turning points and the strength of the relationship. In the 1950s and the early 1960s, the cycle in the North leads the cycle in the South. Comovement is strongest in the period 1965-1975. After 1975, the cycles start to drift out of phase, again with the North leading the South.     

Long-term effects of acceleration on the social-emotional adjustment of mathematically precocious youths.

The study of Mathematically Precocious Youth (SMPY) identified over 2,000 12–14 year-olds who scored as well as a random sample of high school females on the Scholastic Aptitude Test. SMPY encouraged these students to accelerate their education; over 50% did. Their social development at age 18 and at age 23 was then assessed. We investigated the effects of amount and type of educational acceleration (grade skipping and subject matter) on psychosocial indices (self-esteem, locus of control, self-acceptance/identity, and social interaction). No gender differences were significant. Accelerants as well as nonaccelerants reported high self-esteem and internal locus of control. Acceleration did not affect social interactions or self-acceptance/identity and it also did not relate to social and emotional difficulties. (PsycINFO Database Record (c) 2010 APA, all rights reserved)