采用动态邻域扩展算法的非一致CA低功耗确定TPG

针对确定内建自测试向量发生器设计中常存在着对冗余向量依赖,导致测试应用时间增长,并产生额外的测试功耗等问题,提出一种新的低功耗确定测试向量发生器的综合算法.该向量发生器采用非一致细胞自动机的结构实现,利用基于模拟退火的动态邻域扩展算法寻找优化的细胞自动机的拓扑连接关系.对标准组合电路仿真实验的结果表明,所综合出的向量发生器可有效地产生给定的低功耗确定向量集,并且不影响原有的故障覆盖率和测试时间.     

Delphi环境下目标规划图解法算法程序的开发

作为目标规划算法平台的一个重要组成部分,研究了多目标线性规划中的目标规划图解法算法程序的开发,以方便该方法在各领域的应用。首先,介绍了目标规划的原理、建立目标规划模型的步骤。然后,介绍目标规划图解法的计算步骤以及在Del-phi环境下开发目标规划图解法的流程和具体方法。最后,通过实例对目标规划图解法算法程序的正确性进行了验证。所开发的算法程序直观简捷,方便工程人员的使用。     

基于移动Agent的电子商务交易平台研究

针对传统电子商务平台存在的问题,提出了一个以移动Agent为中介服务的电子商务交易平台,阐述了该平台各组成部分的功能.实验采用价格优先和数量优先的购买策略,分析了该平台中移动Agent的性能,实验仿真结果表明移动Agent的引入提高了平台处理客户信息的速度,缩短了达成交易的时间并降低了网络的通信量.     

基团立体屏蔽效应对取代咪唑离子液体酸性的影响

影响取代咪唑阳离子C2-H酸性(pKa)的重要因素有二:H原子所带的部分正电荷和取代基的立体屏蔽效应,前者可用C2-H的1H NMR化学位移δC2-H度量,后者用基团拓扑立体效应指数TSEI衡量.咪唑阳离子C2-H的pKa可由以下方程估算:pKa=58.10-4.208δC2-H+1.659TSEI该式的标准偏差只有0.28 pKa单位,估算结果与文献报导的pKa值相吻合.表明如要精确估算pKa,必须考虑取代基立体屏蔽效应;当希望用碱性较低的亲核试剂脱除取代咪唑阳离子的C2-H形成卡宾时,应采用芳香基取代的咪唑离子;若使用取代咪唑离子液体作溶剂,并且在碱性较强的条件下进行有机反应,则最好选择立体屏蔽效应大的非芳香基取代的咪唑离子.     

基于DSP平台的激光二极管控制系统

介绍了以DSP芯片TMS320F2812为核心设计的控制平台、利用半导体制冷器和光功率传感器调节激光二极管工作温度和发射功率的控制系统;设计了具有良好性能的模拟通道,提出了针对特定调节对象的PID算法.结合优化设计的执行单元实现了很好的控制效果,有效地提高了激光二极管系统的稳定性和可靠性;设计的控制系统在环境温度-10℃～50℃时能够达到±0.03℃的控制精度.     

Phosphofructokinase from mantle tissue of Mytilus galloprovincialis. Purification and effects of phosphorylation on the enzymatic activity

Phosphofructokinase purified from mantle tissue of the sea mussel Mytilus galloprovincialis, was phosphorylated "in vitro" by the catalytic subunit of cyclic AMP-dependent protein kinase. The incorporation of phosphate gave rise to an activation of the enzyme by increasing its affinity for fructose-6-phosphate, by decreasing its sensitivity to the inhibition by ATP and by enhancing the effect of allosteric activators (5'-AMP and fructose-2,6-bisphosphate). In addition, the effects of phosphorylation on the catalytic activity are pH-dependent.     

Single-Atom Metal Sites Anchored Hydrogen-Bonded Organic Frameworks for Superior “Two-In-One” Photocatalytic Reaction

Photoredox catalysis is a green solution for organics transformation and CO₂ conversion into valuable fuels, meeting the challenges of sustainable energy and environmental concerns. However, the regulation of single-atomic active sites in organic framework not only influences the photoredox performance, but also limits the understanding of the relationship for photocatalytic selective organic conversion with CO₂ valorization into one reaction system. As a prototype, different single-atomic metal (M) sites (M²⁺ = Fe²⁺, Co²⁺, Ni²⁺, Cu²⁺, and Zn²⁺) in hydrogen-bonded organic frameworks (M-HOF) backbone with bridging structure of metal-nitrogen are constructed by a typical “two-in-one” strategy for superior photocatalytic C N coupling reactions integrated with CO₂ valorization. Remarkably, Zn-HOF achieves 100% conversion of benzylamine oxidative coupling reactions, 91% selectivity of N-benzylidenebenzylamine and CO₂ conversion in one photoredox cycle. From X-ray absorption fine structure analysis and density functional theory calculations, the superior photocatalytic performance is attributed to synergic effect of atomically dispersed metal sites and HOF host, decreasing the reaction energy barriers, enhancing CO₂ adsorption and forming benzylcarbamic acid intermediate to promote the redox recycle. This work not only affords the rational design strategy of single-atom active sites in functional HOF, but also facilitates the fundamental insights upon the mechanism of versatile photoredox coupling reaction systems.     

A 2.20 eV Bandgap Polymer Donor for Efficient Colorful Semitransparent Organic Solar Cells

Semitransparent organic solar cells (ST-OSCs) have attracted increasing attention due to their promising prospect in building-integrated photovoltaics. Generally, efficient ST-OSCs with good average visible transmittance (AVT) can be realized by developing active layer materials with light absorption far from the visible light range. Herein, the development of ultrawide bandgap polymer donors with near-ultraviolet absorption, paired with near-infrared acceptors, is proposed to achieve high-performance ST-OSCs. The key points for the design of ultrawide bandgap polymers include constructing donor–donor type conjugated skeleton, suppressing the quinoidal resonance effect, and minimizing the twist of conjugated skeleton via noncovalent conformational locks. As a proof of concept, a polymer named PBOF with an optical bandgap of 2.20 eV is synthesized, which exhibited largely reduced overlap with the human eye photopic response spectrum and afforded a power conversion efficiency (PCE) of 16.40% in opaque device. As a result, ST-OSCs with a PCE over 10% and an AVT over 30% are achieved without optical modulation. Moreover, colorful ST-OSCs with visual aesthetics can be achieved by tuning the donor/acceptor weight ratio in active layer benefiting from the ultrawide bandgap nature of PBOF. This study demonstrates the great potential of ultrawide bandgap polymers for efficient colorful ST-OSCs.