Optimization of Green Multiple Emulsions Processing to Improve Their Physical Stability

The effect of processing protocol on physical stability and the microstructure of water‐in‐oil‐in‐water multiple emulsions containing a mixture of two amphiphilic copolymers with opposed hydrophilic‐lipophilic balance as emulsifiers and a green solvent, 2‐ethylhexyl lactate, as the dispersed phase, has been assessed. Emulsions were obtained in at least two steps: a homogenization step by using a rotor‐stator device, followed by one or two homogenization steps carried out in a high‐pressure device that used microfluidizer technology. To study the microstructure and physical stability of these emulsions, a combination of different techniques, such as transmitted‐light optical microscopy, globule size distribution, viscous flow tests, and multiple light scattering measurements, were performed.     

Comparison of two size-differentiating air samplers for detecting airborne swine viruses under experimental conditions

Detection and quantification of dilute viral aerosols, as encountered outside animal housing facilities, requires methods that are able to detect small numbers of viruses in large volumes of air. This study compared the performance of two size-differentiating cascade impactors; an Andersen 8-stage (ACI; 28.3 L/min) and a high volume Tisch (TCI; 1,133 L/min) to assess sampling efficiency for detecting porcine reproductive and respiratory syndrome virus (PRRSV) and influenza A virus (IAV). Samples of particles sorted by aerodynamic diameter were analyzed by quantitative polymerase chain reaction (qPCR) and collection efficiency was assessed by particle size. Collection media (minimum essential medium [MEM] and beef extract [BE]), elution technique (active versus passive), and sampling times (10, 20, and 30 min) were variables assessed for the TCI sampler. Extraction efficiency was 35% higher with BE as compared to that of MEM (p = 0.0007); active extraction technique was 19% more efficient than the passive technique (p = 0.03); time of sampling did not significantly affect the amount of virus recovered. The ACI sampler was more efficient in detecting both viruses from small and medium sized airborne particles (≤3 μm) as compared to the TCI sampler (p < 0.001). The latter sampler, however, was more efficient at IAV detection from large airborne particles (>3 μm) (p = 0.0025) indicating the potential of this sampler in detecting the presence of small amounts of viruses in aerosols under field conditions.

© 2017 American Association for Aerosol Research     

The Extended Community-Level Effects of Genetic Variation in Foliar Wax Chemistry in the Forest Tree <Emphasis Type="Italic">Eucalyptus globulus</Emphasis>

Genetic variation in foundation trees can influence dependent communities, but little is known about the mechanisms driving these extended genetic effects. We studied the potential chemical drivers of genetic variation in the dependent foliar community of the focal tree Eucalyptus globulus. We focus on the role of cuticular waxes and compare the effects to that of the terpenes, a well-studied group of secondary compounds known to be bioactive in eucalypts. The canopy community was quantified based on the abundance of thirty-nine distinctive arthropod and fungal symptoms on foliar samples collected from canopies of 246 progeny from 13 E. globulus sub-races grown in a common garden trial. Cuticular waxes and foliar terpenes were quantified using gas chromatography - mass spectrometry (GC-MC). A total of 4 of the 13 quantified waxes and 7 of the 16 quantified terpenes were significantly associated with the dependent foliar community. Variation in waxes explained 22.9% of the community variation among sub-races, which was equivalent to that explained by terpenes. In combination, waxes and terpenes explained 35% of the genetic variation among sub-races. Only a small proportion of wax and terpene compounds showing statistically significant differences among sub-races were implicated in community level effects. The few significant waxes have previously shown evidence of divergent selection in E. globulus, which signals that adaptive variation in phenotypic traits may have extended effects. While highlighting the role of the understudied cuticular waxes, this study demonstrates the complexity of factors likely to lead to community genetic effects in foundation trees.     

Porosity‐dependent properties of Nb‐doped Pb(Zr,Ti)O3 ceramics

In the present work, it is shown how the controlled porosity can be exploited to obtain a compromise between a reduced permittivity down to a few hundreds and maintaining a high tunability level as in the dense material, to fulfill requirements for tunable applications. Nb‐doped Pb(Zr,Ti)O₃ ceramics with porosity in the range 5%‐30% have been prepared by direct sintering method. X‐ray diffraction analysis and Rietveld refinement indicated a co‐existence of tetragonal and monoclinic phases in the porous ceramics. Dielectric properties revealed a gradual reduction in permittivity when increasing the porosity level, while maintaining low dielectric losses below 3%. The ferroelectric switching behavior is also influenced by the porosity level: a continuous reduction in the saturation and remnant polarization is observed with increasing porosity. The nonlinear dielectric properties of all the investigated ceramics preserve a high level of tunability in comparison with one of the dense material, irrespective of the porosity level, while zero field permittivity was decreased below 1000. An optimum behavior is found for the ceramic sample with 25% porosity, which shows a high tunability, smaller losses, and moderate dielectric constant (ε ~600).     

Structural features of iron‐phosphate glass

This paper reports a study and discusses the role of Fe ions in the inhibition of corrosion of iron phosphate glasses. The structure of the 40Fe₂O₃–60P₂O₅ (mol%) glass, having a confirmed dissolution rate in aqueous solution at 90°C superior to borosilicate glasses, was investigated. Samples were crystallized at characteristic temperatures defined by differential thermal analysis and analyzed by X‐ray diffraction. Crystalline phases of Fe₂Fe[P₂O₇]₂ and Fe₄[P₂O₇]₃ were detected. The hyperfine parameters from the Mössbauer spectrum indicate that both Fe²⁺ and Fe³⁺ ions are in octahedral coordination, and 18% of the Fe³⁺ ions in the starting batch are reduced to Fe²⁺ ions after melting. The broad and symmetric spectra centered in g≈2.0 from the EPR measurements indicate the presence of two or more Fe interacting ions occupying sites of relatively high local symmetry.     

Mathematical Modeling of Drying Kinetics for Apricots: Influence of the External Resistance to Mass Transfer

The drying curves of halved and deseeded apricots obtained during convective drying at different temperatures (from 50 to 90°C) have been examined, and a diffusional model, solved by a finite elements method, has been proposed to simulate the drying kinetics. The importance of taking into account both the internal and the external resistances to mass transfer when modeling the drying curves is discussed. Due to the geometry of halved apricots as a hemisphere losing water only through the flat section, the mass transfer coefficient (k_c) was not correctly estimated through an empirical correlation. Only the identification of this coefficient from the experimental results allowed an accurate simulation, decreasing the mean relative error from 12.3±3.8% when k_c was calculated through the Pasternak and Gauvin correlation to 2.9±1.0% when k_c was identified.     

Effect of Processing Conditions on Drying Kinetics and Particle Microstructure of Carrot

The drying of carrot particles (6 mm × 6 mm × 12 mm) was studied in a tunnel dryer; a vacuum-freeze dryer, either with or without infrared radiation; a pulsed fluidized-bed dryer assisted by microwave radiation; and combinations of these methods. The effect of two freezing rates (quick freezing in liquid nitrogen and slow freezing in a household freezer) was also studied.

The drying kinetics for these drying methods were determined and modeled, and the dried products were subjected to texture (hardness), color, and rehydration analysis, as well as 2D and 3D image analysis of pictures from scanning electron microscope.

The combination of freeze drying with other dehydration techniques reduces the drying time by 6–70%, although, in general, the structural damage increases with respect to freeze drying alone. The hybrid drying systems did not show significant differences in drying times either for quick- or slow-frozen samples. The combination of freeze drying followed by conventional drying reduces the drying time between 23 and 40% on average.

The Page empirical model represents adequately the entire drying process for combined methods, with specific parameters for each drying zone. The values of effective diffusivity calculated with the simplified constant diffusivity model agree with those reported in the literature.     

Phytal: A Candidate Sex Pheromone Component of the Moroccan Locust Dociostaurus maroccanus

Outbreaks of locusts cause enormous economic losses to agriculture in many countries. To develop environmentally friendly strategies for their control, much research has been focused on the factors that influence locust biology, particularly infochemical‐mediated interactions. We present herein the identification and synthesis of both Z and E isomers of phytal (3,7,11,15‐tetramethylhexadec‐2‐enal, 1 ), which are involved in chemical communication and behaviour of the Moroccan locust, Dociostaurus maroccanus, a serious agricultural pest. The compound was identified by comparison of its chromatographic and spectrometric features and microchemical reactions with those of a synthetic sample. The natural compound was shown to have the R,R configuration by chiral HPLC analysis, and its structure is unique as an insect pheromone component. Both isomers of phytal are produced by sexually mature adult males and elicit electroantennographic responses in antennae of both sexes. In two‐choice olfactometer bioassays, males and females significantly preferred the stream enriched with racemic phytal to the control. In contrast, hydrogenated phytal was behaviourally inert. Both isomers of phytal are specific to D. maroccanus as they are absent in the closely related, habitat‐sharing species Dociostaurus jagoi and Calliptamus wattenwylianus. Legs and wings are the main release sites of the compound: approximately 90 % of that emitted by living individuals. In biosynthetic studies, phytal appears to proceed from oxidation of phytol ( 2 ) after injection of deuterated phytol into the abdomen of the insect or after administration in the diet. Our results demonstrate that phytal is a candidate sex pheromone component of the Moroccan locust; it is produced by mature males, and might be eavesdropped upon by conspecific males.     

Interference of EDTA in the treatment of metal plating wastewater by biosorption

BACKGROUND: The applicability of biosorption for the treatment of metal plating wastewater is adversely affected by the presence of complexing agents. To investigate this limitation on the removal of copper(II) onto peat, batch and column experiments were carried out using EDTA as the model complexing agent. The influence of pH and copper(II):EDTA mass ratios were evaluated for copper(II) concentrations between 5 and 100 mg Cu(II) dm^?3. RESULTS: EDTA negatively affected the copper(II) uptake of peat for pH > 5. Batch and column experiments showed that copper(II)‐EDTA complexes were not sorbed by peat. The leaks of copper(II) detected from the beginning of the column operation matched the copper(II)‐EDTA concentration in the feed solutions. To overcome the interference of EDTA, a novel approach based on the combination of peat + activated carbon was proposed. Nearly complete removal of copper(II) was maintained over 70 h in the treatment of a solution containing 20 mg Cu(II) dm^?3 with 11% of copper(II)‐EDTA complexes. CONCLUSION: A new mass transport model coupling copper(II) speciation in the feed and mass transfer rate‐controlled process simulated the copper(II) breakthrough curves in the presence of EDTA and could be used to successfully predict the breakthrough point. This work demonstrated that biosorption can also be applied for the treatment of wastewater containing complexing agents with the proper combination of sorbent materials. © 2012 Society of Chemical Industry