Hydrogen production by photocatalytic membranes fabricated by supersonic cluster beam deposition on glass fiber filters

Photoactive membranes coated with TiO₂ and Pt/TiO₂ nanostructured thin films were produced by one-step deposition of gas phase nanoparticles on glass fiber filters. Pt/TiO₂ nanoparticles (0–1.5 wt.% Pt content) were produced by flame spray pyrolysis, starting from liquid solutions of the Ti and Pt precursors, and then expanded in a supersonic beam to be deposited on the filters. The nanostructured coatings were composed of crystalline nanoparticles (mainly anatase phase), without any need of post-deposition annealing. The so obtained photocatalytic membranes were tested in hydrogen production by photo-steam reforming of ethanol in an expressly set-up diffusive photoreactor. The reaction rate was found to increase with increasing the Pt content in the photoactive material, up to 1.5 wt.% Pt. The use of these membranes allowed a significant increase of the hydrogen production rate compared to that obtained with the same photoactive Pt/TiO₂ films deposited on a quartz substrate.     

A hierarchical structure for surface approximation

Hierarchical triangulation is a method for point selection and surface representation where the surface is approximated at successively finer levels of detail by triangular patches whose projections in the horizontal plane are nested. A tree data structure for this representation can be constructed in O(n²) worst case and O(n log n) average case time, where n is the number of data points considered. Efficient algorithms for approximation of the elevation of an arbitrary point, contour extraction, and conversion of the hierarchical structure into an ordinary triangulated irregular network, are demonstrated. The convergence and the optimality of the approximation and the relationship of the hierarchical triangulation to a structured graph representation are examined.     

Residual stress measurement on Titanium Grade 5 and Inconel 625 thin dissimilar welded joints by contour method

Journal of Materials Science - Residual stress assessment is a key factor in engineering design owing to its impact on engineering properties of materials, structural components and welded joints....     

Manipulation and tracking of superparamagnetic nanoparticles using MRI

The use of magnetic fields in magnetic resonance imaging (MRI) for the tracking and delivery of chemotherapeutics bound to superparamagnetic nanoparticles offers a promising method for the non-invasive treatment of inoperable tumours. Here we demonstrate that superparamagnetic magnetite nanoparticles fabricated by an easily scalable method can be driven and tracked in real time at high velocities in vitro using MRI hardware. Force balance calculations are consistent with the magnetic properties of individual 10 nm diameter particles that move collectively as micron sized agglomerates with hydrodynamic diameter similar to that inferred from zero-magnetic-field dynamic light scattering measurements.     

Structure and thermal properties of heat treated plasma sprayed ceria–yttria co-stabilized zirconia coatings

Thick plasma sprayed thermal barrier coatings are suitable for thermal and hot corrosion protection of metal components in land-based turbine and diesel engines. In this work, ceria–yttria co-stabilized zirconia coatings were deposited by atmospheric plasma spraying in a mixture of non-transformable tetragonal t′ and cubic c zirconia phases. Free-standing coatings were isothermally annealed at 1315 °C for different times and their crystal structure was studied by XRD. No phase decomposition occurred. Columnar grains grew in the molten splats with increasing annealing time according to a preferential direction and, after 50 h of heat treatment, they were partially replaced by equiaxed grains. Both in-plane and out-of-plane thermal expansion coefficients (CTEs) were measured from coating expansion during heating. The CTE was slightly sensitive to thermal exposure in out-of-plane direction, whereas it kept almost constant in plane direction. The specific heat capacity Cp of annealed coatings, measured by differential scanning calorimetry (DSC), decreased in comparison with as-sprayed coating, due to high-temperature sintering.     

Preparation of nanotubes-clay hybrid systems by iron-catalyzed isobutane decomposition

Nanotubes-clay hybrid systems are synthesized by decomposition of isobutane at 700 °C over as-purchased and iron-loaded montmorillonite catalysts. The changes produced by the variations of total iron content (2–17 wt.%) and of reduction-temperature (500 °C or 700 °C) in catalyst surface properties, as well as, in reaction yield and crystalline quality of C deposits are discussed. A growth mechanism is proposed accounting for the bi-functional behavior of catalyst and the role, played by the clay support acidity with regard to the process selectivity and the resulting crystallinity degree of reaction products, is demonstrated. The decrease of number of catalyst acid sites, by reduction at 700 °C or by sodium exchange reaction, inhibits the formation of highly disordered carbonaceous nanostructures, responsible for metal deactivation and scarce selectivity at small iron loads. It is worth noting that catalysts prepared with sodium-exchanged clay allow obtaining crystallinity degrees higher than those ever reported in literature for similarly grown nanotubes.     

Mapping average equivalized income using robust small area methods

Measures of economic well‐being are often needed for geographically small areas, as economic indicators may be distributed unevenly among the subsets of relatively small regions. We consider small area estimation of average equivalized income. Disposable household income data are usually available only for a sample of households, typically too small to provide reliable estimates for small regions. We consider a small area estimation technique that is robust to outliers, produces results consistent with design weighted estimates obtained for larger areas and yield maps with approximately no shrinkage. The proposed methodology is applied to the Local Labour Systems in Tuscany (Italy).     

Integrated ambient ozone evaluation by passive samplers and clover biomonitoring mini-stations

An ozone monitoring network was set up using passive samplers and biological mini-stations of two clones of white clover (Trifolium repens L. cv. Regal), NC-R (O(3)-resistant) and NC-S (O(3)-sensitive). This paper reports on a pilot study performed in the period June-October 1999 in the Rome municipal area by using five biomonitoring mini-stations and ozone passive samplers with a new nitrite based design. This combined methodology can be used to obtain information on the biological implications of the injury due to tropospheric ozone. The two techniques can integrate data for the short-medium period and can be placed in different urban and rural sites, proving to be a very useful tool for ozone concentration mapping.