Rheological and fusion behaviors of PVC micro‐ and nano‐composites evaluated from torque rheometer data

The effects of calcium carbonate (CaCO₃) particle size on the fusion and rheological behaviors of rigid poly(vinyl chloride) (PVC) composites prepared in a Haake torque rheometer were investigated by means of torque data recorded during processing. Increasing the number of particles in the same blend volume by decreasing the particle size resulted in increasing frictional forces. This increase led in turn to increased fusion torque and decreased fusion time and temperature. The power‐law‐index values of the composites increased with decreasing particle size except for 25‐nm CaCO₃. The viscosities of all composites were found to decrease with shear rate; therefore, high pseudoplasticity was observed. At a particular rotor speed, viscosity of the composites decreased with decreasing particle size except for 25‐nm CaCO₃. The overall results showed that the particle size of CaCO₃ altered the fusion characteristics and rheological behavior of PVC. J. VINYL ADDIT. TECHNOL., 2010. © 2010 Society of Plastics Engineers     

Crossflow filtration of iron(III), copper(II), and cadmium(II) aqueous solutions with alginic acid/cellulose composite membranes

The removal of Fe(III), Cu(II), and Cd(II) ions from aqueous solutions was investigated with a crossflow filtration technique. Alginic acid (AA)/cellulose composite membranes were used for retention. In the filtration of Fe(III) solutions, the effects of the crossflow velocity, applied pressure, AA content of the membranes, and pH on the retention percentage and the permeate flux were examined. The maximum retention percentage was found to be 89% for a 1 × 10^?4M Fe(III) solution at the flow velocity of 100 mL/min and the pressure of 60 kPa with 0.50% (w/v) AA/cellulose composite membranes at pH 3. Aqueous solutions of Cu(II) and Cd(II) were filtered at the flow velocity of 100 mL/min and pressure of 10 kPa. The effects of the AA content of the membranes and pH of the waste medium on the retention percentage and the permeate flux were determined. For 1 × 10^?4M Cu(II) and Cd(II) solutions, the maximum retention percentages were found to be 94 and 75%, respectively, at pH 7 with 0.50% (w/v) AA/cellulose composite membranes. When metal‐ion mixtures were used, the retention percentages of Fe(III), Cu(II), and Cd(II) were found to be 89, 48, and 10%, respectively, at pH 3 with 0.50% (w/v) AA/cellulose composite membranes. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Synthesis and Photopolymerizations of New Crosslinkers for Dental Applications

Summary: Five new crosslinkers for use in dental composites were synthesized. Four are based on TBHMA: 1 via reaction of TBBr and Bisphenol A; 2 by hydrolysis of t‐butyl groups of the first monomer to give a diacid derivative; 3 by conversion of the first monomer to an amide derivative using benzyl amine; 4 by conversion of the first monomer to amide derivative using APTES. The AHM‐based monomer 5 was synthesized from the Michael addition of APTES to AHM. The photopolymerization behaviors of the synthesized monomers with Bis‐GMA, TEGDMA and HEMA were investigated using photodifferential scanning calorimetry at 40 °C using DMPA as photoinitiator. The polymerization rates and degrees of conversion for mixtures of any of the monomers 1 – 4 with Bis‐GMA:TEGDMA were found to be similar to Bis‐GMA:TEGDMA, higher than Bis‐GMA:HEMA, and also higher than mixtures with Bis‐GMA:HEMA. The incorporation of TBHMA‐based monomers into the conventional resin mixture (Bis‐GMA and TEGDMA) reduced the polymerization shrinkages. Monomer 5 and its mixtures polymerized much faster and to higher degrees of conversion than the other investigated systems, however, this system exhibited the largest volume shrinkage.

Structures of some of the new crosslinkers synthesized.     

Dynamic analysis of large-scale SSI systems for layered unbounded media via a parallelized coupled finite-element/boundary-element/scaled boundary finite-element model

An algorithm for a parallelized coupled model based on finite element method (FEM), boundary element method (BEM), and scaled boundary FEM (SBFEM) for harmonic and transient dynamic response of large-scale 2D structures embedded in or on layered soil media is presented. The BEM and SBFEM are used for modelling the dynamic response of the unbounded media. The standard FEM is used for modelling the finite region and the embedded structure. The objective of the development of this parallelized coupled model is to use the power of high performance computing, and to take into account the advantages and evade the disadvantages of the above mentioned numerical methods for modelling of the unbounded media in soil-structure interaction (SSI) systems. The development of the parallel algorithm for this model is essential for solving arbitrarily shaped large-scale SSI problems, which cannot be solved within reasonable elapsed times by a serial algorithm. The efficiency of the proposed parallel algorithm and the validity of the coupled model are shown by means of three numerical examples, indicating the excellent accuracy and applicability of the parallel algorithm with considerable time-savings in large-scale problems.     

CMS Hadronic EndCap Calorimeter Upgrade Studies for SLHC “Čerenkov Light Collection From Quartz Plates”

Due to an expected increase in radiation damage under super-LHC conditions, we propose to substitute the scintillator tiles in the original design of the hadronic endcap (HE) calorimeter with quartz plates. Quartz is shown to be radiation hard. Using wavelength shifting fibers, it is possible to collect efficiently the Cerenkov light generated in quartz plates. This paper summarizes the results from various test beams, bench tests, and Geant4 simulations done on methods of collecting light from quartz plates, as well as radiation hardness tests on quartz material.     

艾哈迈德·阿德南·萨伊贡艺术中心,伊兹密尔,土耳其

<正>一座建筑的性能应当如何来衡量?除了通过统治当代建筑舆论的美学、技术以及经济价值来进行描述之外,我们还能够如何来阐释一座建筑,尤其是一座致力于庇护那些渴望展现自己的艺术家的建筑?有人会问成功的表演是如何实现的,表演者是如何进行伪装的、又是如何展现自己的?根据海德格尔的理论,当我们看不到钉子的时候,铁锤的表现才是成功的;钉子本身的出现通常表明出现了问题。     

Effect of replacing disc cutters with chisel tools on performance of a TBM in difficult ground conditions

A summary of a research program covering a period of two years on the performance of a TBM in a very complex and difficult geology is presented in this study. The formations in the study area varied from alluvium, sludge, mudstone, shale and limestone to quartzite with strengths from soft to very hard. The dykes frequently intruded the sedimentary rocks resulting in different degrees of weathering and fracturing in the country rock causing tremendous delays in progress rate of the TBM. The disc cutters started cutting inefficiently in clayey medium strength ground with extreme water income, at where also excessive disc consumptions started due to insufficient friction between the disc cutters and very soft (sludgy) formation, and it was decided to replace all disc cutters with chisel tools (ripper, scraper). Before making this important decision that could affect totally the excavation efficiency and production rate, some theoretical estimations were performed using the Evans’ cutting theory after some modifications based on the previous experimental studies for relieved cutting mode and wear flat, front ridge and vee-bottom angles found in complex shapes of chisel tools to estimate deterministically the torque and thrust requirements of the TBM.Field measurements of the torque and thrust requirements of the TBM equipped with the chisel tools validated the theoretical considerations and the deterministic model used for predicting the performance. Statistical analysis indicated that the model could be used reliably for performance prediction. This study also gave a unique opportunity to compare the performance of disc cutters and chisel tools used on the same TBM at variety of grounds and to analyze the effect of replacing disc cutters with chisel tools on the performance of the TBM. The field measurements indicated that the chisel tools were superior to the disc cutters in especially soft to medium strength rocks.     

SELECTING A TEMPERATURE TIME HISTORY FOR PREDICTING FATIGUE LIFE OF MICROELECTRONICS SOLDER JOINTS

Temperature cycling tests are standard industry practice for determining the thermomechanical fatigue life of solder joints. Industry-standard temperature profiles usually start from room temperature, then go to a high temperature, then to a cold temperature, and then back to room temperature. In addition, most of the time, the temperature profile contains dwell times at the highest and lowest temperatures. The dwell time at a high temperature corresponds to the on-state storage of the device, and the cold-temperature dwell time simulates the off-state storage of the device. In this study, the actual temperature history of a Ball Grid Array (BGA) package in a laptop computer was measured in situ. Experimental reliability studies were conducted using the in situ measured temperature history as well as industry-standard temperature history. This article presents the influence of temperature history on solder joint fatigue life. In order to measure deformations in the solder joint under cycling loading, a new Moire interferometry grating replication technique was developed to be able to measure strain field during fatigue testing.     

Effect of property variations on the mixing of laminar supercritical water streams in a T-junction

The effect of variation of supercritical water properties with temperature and pressure on the mixing characteristics of streams having different temperatures in a T shaped channel is investigated numerically by considering steady, low Reynolds number flows with the assumption of negligible bouyancy effects. The Reynolds number of the cold stream in the range 0.1 to 100, inlet temperature of hot stream varying from 300 K to 800 K, the ratio of mass flow rate of cold stream to total mass flow rate in the range of 0.1 to 0.90 and the operating pressures from 25 MPa to 45 MPa at a cold fluid inlet temperature of 293.15 K are considered as parameters controlling the mixing of hot and cold streams. The effect of property variations on the outcome of the mixing is more important for low Reynolds numbers and hot fluid inlet temperatures above the pseudo-critical temperature and result in a non-uniform temperature distribution in the outlet section.     

SpyDetector: An approach for detecting side-channel attacks at runtime

International Journal of Information Security - In this work, we first present a low-cost, anomaly-based semi-supervised approach, which is instrumental in detecting the presence of ongoing...