Ion Chromatographic Determination of Free Cyanide in Different Classes of Bottled Natural Mineral Water Consumed in Turkey

An ion chromatographic method for the quantitative determination of free cyanide in bottled natural mineral waters were measured in terms of selectivity, linearity, the limit of detection, limit of quantification, repeatability, precision, and accuracy. Chromatographic separation of free cyanide ions was accomplished with an anion-exchange column and detected by pulsed amperometric detection with a silver working electrode. The method was found to be selective, linear (r² = 0.999) at a concentration range of 0.5 to 134 μg L^?1, precise, and accurate. Recovery values of free cyanide in all classes of natural mineral water varied from 65.9 ± 1.6 to 95.2 ± 0.7 at different spiking levels (5–70 μg L^?1). Parameters (total dissolved solids, mineral interferences, and added sodium hydroxide) affecting the recovery values were studied in this project. The limit of detection and limit of quantification were found to be 0.295 and 0.983 μg L^?1, respectively. The proposed method was applied to 27 different brands of commercially available bottled natural mineral water products sold in Turkish markets. These natural mineral waters were classified as: (i) very low mineral concentration, (ii) low mineral concentration, (iii) intermediate mineral concentration, and (iv) high mineral concentration based on their total dissolved solids contents according to European Union Directive (Directive 80/777/EEC). Levels of free cyanide residues in the samples ranged from > limit of detection to 6.12 μg L^?1. The highest average concentration of free cyanide residues was found in the class of “high mineral concentration waters.” However, the determined free cyanide values in all of the tested natural mineral water samples were found to be within the limits of European Union legislation.     

Lead(II) Adsorption from Aqueous Solution by Poly(ethylene terephthalate)-g-Acrylamide Fibers

In this study, a reactive fibrous adsorbent was prepared by graft copolymerization of Acrylamide (AAm) onto poly(ethylene terephthalate) (PET) fibers and the adsorption properties of Pb(II) ion from aqueous solution by the reactive fibers were examined by batch equilibration technique. The effects of graft yield, pH, adsorption time, initial ion concentration and adsorption temperature on the adsorption amount of Pb(II) ion was studied. The results show that the adsorption amounts of Pb(II) ion increased with grafting yield, shaking time, initial ion concentration and adsorption temperature. Adsorption of Pb(II) ion was strongly affected by pH. A Lagergren pseudo-second-order was the model that best described the adsorption mechanism. It was found that the adsorption isotherm of the Pb(II) ion fit Langmuir-type isotherms. From the Langmuir equation the adsorption capacity was found as 39.57 mg/g fiber for Pb(II) ion for the copolymer with a graft yield of 15.7%. Quantitative desorption of Pb(II) from reactive fibers were found to be 96% by 5 M HNO₃. Five adsorption–desorption cycles demonstrated that the reactive fibers were suitable for repeated use without considerable change in adsorption capacity. The results of the thermodynamic study indicated that the adsorption processes was endothermic and spontaneous.     

The elements of forming traditional Turkish cities: Examination of houses and streets in historical city of Erzurum

When the historical parts of cities—which are the cultural mosaics and which reflect the feelings, thoughts, tendencies, life experiences and the accumulations of the periods in which they were built—begin to disappear, it affects the historical identities of the cities negatively. Investigating, learning, documenting and transferring to the future the values of these spaces, which are bridges between past and future, are vitally important for the maintenance of the cities. This analytical study carried out in Üç Kümbetler and its vicinity in the historical city of Erzurum—where historical and traditional urban elements such as religious buildings, traditional houses, streets, and fountains are intense—aimed at fulfilling these ends.     

Robust microencapsulated phase change materials in concrete mixes for sustainable buildings

For passive building applications, phase change materials (PCMs) are microencapsulated to avoid leakage of PCM from concrete structure. The primary challenge of using microencapsulated PCM (MPCM) is its weak shell structure. New MPCMs with different shell compositions to prevent breakage during mixing in fresh concrete are needed. In this study, free radical polymerization method to microencapsulate capric acid–myristic acid mixture as PCM with two different methyl methacrylate co‐polymers is proposed to produce robust MPCMs for building applications. Two new microcapsules (MPCM‐1 and MPCM‐2) having latent heats of 91.9 and 97.3 J/g were synthesized. SEM analyses showed the size of microcapsules being in the range of 400–850 nm for MPCM‐1 and 250–475 nm for MPCM‐2. Analyses also reveal that the shells of MPCMs were not harmed, as they were added into concrete mixes. The microsphere's geometry was preserved, and distribution was homogeneous. The MPCMs were also studied under thermal tests of 1000 heating/cooling cycles. No significant changes in thermal properties were observed after thermal cycling tests. Copyright © 2016 John Wiley & Sons, Ltd.     

Energetic and exergetic aspects of cotton stalk production in establishing energy policies

Exergy analysis is important for energy resource utilization, because exergy, which is a way to a sustainable future, is a part of the energy analysis. Exergy analysis starts to play a role in several countries in developing energy policy. This paper deals with the exergetic assessment of the cotton stalk (CS) production. In this regard, Turkey, which is one of the eight countries producing 85% of the world's cotton, is given as an application country first. Energy and exergy relations used in the analysis are then presented. Finally, the Turkish CS production in 2003 is evaluated using energy and exergy analyses method, while the results obtained are discussed. The values for the net energy and exergy gained are obtained to be about 49,146 and 59,395 MJ/ha, respectively. Turkey's total energy and exergy are estimated to be 75.45 and 81.87 PJ. It may be concluded that this amount of energy is equal to 7.77% and 2.38% of Turkey's primary energy production and consumption in the same year, respectively. The overall mean energy and exergy efficiencies of the cotton production in the year studied are found to be 33.06% and 33.12%, respectively. It is also expected that the results of this study will be helpful in developing highly applicable and productive planning for energy policies.     

The durability properties of polypropylene fiber reinforced fly ash concrete

This paper reports of a comprehensive study on the durability properties of concrete containing polypropylene fiber and fly ash. Properties studied include unit weight and workability of fresh concrete, and compressive strength, modulus of elasticity, porosity, water absorption, sorptivity coefficient, drying shrinkage and freeze–thaw resistance of hardened concrete. Fly ash content used in concrete mixture was 0%, 15% and 30% in mass basis, and fiber volume fraction was 0%, 0.05%, 0.10% and 0.20% in volume basis.     

Transplantectomy today: indications and complications

Analysis of the indications for transplantectomy and its complications over a 12-year period. Over a total of 159 failure grafts, we performed 53 transplantectomies (33.3%). The percentage of complications was 16.9%. Three patients died (5.6%) during the more or less immediate post-operative period. In our experience, consistent and prolonged maintenance of immunosuppression should avoid the need for transplantectomy in a high percentage of grafts. Only 15 transplantectomies were made on 104 failure grafts after 6 months (14.4%). Our short but successful experience with embolization of 2 rejected grafts confirms the validity of this conservative alternative versus conventional surgical transplantectomy in selected cases.     

Assessing landscape perception of urban rocky habitats

The urban landscape structure and its changing characteristics have produced various effects on natural and human systems of its own and surroundings [Gilbert OL. The ecology of urban habitats. London: Chapman & Hall; 1991 [1]; Rebele F. Urban ecology and special features of urban ecosystems. Global Ecology and Biogeography Letters 1994;4:173–87 [2]; Rees WE. Urban ecosystems: the human dimension. Urban Ecosystems 1997;1:63–75 [3]; Pickett STA, Cadenasso ML, Grove JM, Nilon CH, Pouyat RV, Zipperer WC, et al. Urban ecological systems: linking terrestrial ecological, physical, and socioeconomic components of metropolitan areas. Annual Review of Ecology and Systematics 2001;32:127–57 [4]; Hope D, Gries C, Zhu WX, Fagan WF, Redman CL, Grimm NB, et al., Socioeconomics drive urban plant diversity. Proceedings of the National Academy of Sciences of the United States of America 2003;100(15):8788–92 [5]; Pickett STA, Cadenasso ML, Grove JM. Resilient cities: meaning, models, and metaphor for integrating the ecological, socio-economic, and planning realms, Landscape and Urban Planning 2004;69(4):369–84 [6]; Luck M, Jianguo Wu J. A gradient analysis of urban landscape pattern: a case study from the Phoenix metropolitan region, Arizona, USA. Landscape Ecology 2002:17(4):327–39 [7]; Angold PG, Sadler JP, Hill MO, Pullin A, Rushton S, Austin K, et al., Biodiversity in urban habitat patches. Science of the Total Environment 2006;360(1–3):196–204 [8]]. By environmental literature conducted recently, it has been evidently comprehended that urban life quality for mankind and others can be improved by serving these systems with green and living elements. This study is to investigate urban rocky habitats that have special natural characteristics and that can be implicated for urban green areas. But these habitats have been considered as nature splits withstanding against the urban pressures by means of the unplanned build-up activities foremost, and road construction, poor quality or neglected remnants. Therefore, this study presents the environmental perception and preferences of urban rocky habitats which are threatening within excessive urbanization and human use of natural areas in the context of the city of Trabzon, Turkey. So, a total of 20 habitats selected from urban and surroundings were surveyed by using a questionnaire and landscape assessment approach. With surveying performed on 204 participants, visual preferences, landscape attributes and proposed management options for urban nature conservation were determined. The χ²${\chi }^2$-test results revealed clearly that the demographic and expertise status of the participants were correlated with the preferences for types of rocky habitat scene and management options. The scenes with natural elements and less human disturbance obtained higher scores on visual preferences than any of the urban rocky scenes lacking these characteristics. Also, in the quantitative phase, factor analysis based on principal component structure revealed the ‘visual and spatial effects’, the ‘usage and arrangement’, the ‘naturalness and ecological value’, and the ‘functionality’ components of the scenes. Consequently, some implications for the effective and efficient planning and development of urban nature conservation by assisting the better understanding of the various patterns of landscape preference, choice and satisfaction in habitats under the present study were suggested.