An investigation of phase transformation behavior in sputter-deposited PtMn thin films

Sputter-deposited, equiatomic PtMn thin films have application in giant magnetoresistive spin valves, tunneling magnetoresistive spin valves, and magnetic random access memory. However, the as-deposited films are found to be a disordered A1 phase in a paramagnetic state rather than an antiferromagnetic phase with L1₀ structure, which is needed for device operation. Therefore, a postannealing step is required to induce the phase transformation from the asdeposited A1 face-centered-cubic phase to the antiferromagnetic L1₀ phase. The A1 to L1₀ metastable transformation was studied by x-ray diffraction and differential-scanning calorimetry. An exothermic transformation enthalpy of −12.1 kJ/mol of atoms was determined. The transformation kinetics were simulated using the Johnson-Mehl-Avrami analysis.     

Influence of diurnal and seasonal temperature variations on the detection of corrosion in reinforced concrete by acoustic emission

Chloride rich reinforced concrete prisms were coupled to chloride-free prisms and exposed to diurnal and seasonal temperature cycles typical of those found in the UK. Acoustic emissions (AE) and galvanic currents were continuously monitored and correlated with ambient temperature. AE and galvanic currents were found to emulate the evolution of temperature in the diurnal cycles, although no specific relationship between AE and galvanic current could be obtained. The influence of seasonal variations in galvanic current had no obvious influence on AE Energy per second over the range of corrosion rates studied. The findings suggest that AE is more sensitive to short term (diurnal) changes in corrosion rates than the longer (seasonal) effects. It was hypothesised that this is due to transitory changes in the internal microclimate of the concrete.     

Application of Graham scan algorithm in binary phase diagram calculation

Graham scan, a computational geometric algorithm for finding a two-dimensional convex hull, is introduced to calculate binary phase diagrams. This algorithm is modified and applied to find the convex hull of discrete points in the space of Gibbs energy vs mol fraction. The modified Graham scan algorithm has a very low computational cost, which improves efficiency in binary phase diagram calculation.     

Towards high accuracy calibration of electron backscatter diffraction systems

For precise orientation and strain measurements, advanced Electron Backscatter Diffraction (EBSD) techniques require both accurate calibration and reproducible measurement of the system geometry. In many cases the pattern centre (PC) needs to be determined to sub-pixel accuracy. The mechanical insertion/retraction, through the Scanning Electron Microscope (SEM) chamber wall, of the electron sensitive part of modern EBSD detectors also causes alignment and positioning problems and requires frequent monitoring of the PC. Optical alignment and lens distortion issues within the scintillator, lens and charge-coupled device (CCD) camera combination of an EBSD detector need accurate measurement for each individual EBSD system.This paper highlights and quantifies these issues and demonstrates the determination of the pattern centre using a novel shadow-casting technique with a precision of ∼10 μm or ∼1/3 CCD pixel.     

Providing Flexible Process Support to Project-Centered Learning

While business process definition is becoming more and more popular as an instrument for describing human activities, there is a growing need for software tools supporting business process abstractions to help users organize and monitor their desktop work. Tools are most effective when they embed some knowledge about the process, e.g., in terms of the typical activities required by the process, so that users can execute the activities without having to define them. Tools must be lightweight and flexible, so as to enable users to create or change the process as soon as there is a new need. In this article, we first describe an application-independent approach to flexible process support by discussing the abstractions required for modeling, creating, enacting, and modifying flexible processes. Then, we show our approach at work in the context of project-centered learning. In this application, learners are challenged to perform concrete tasks in order to master specific subjects; in doing so, they have to conduct significant projects and cope with realistic (or even real-life) working conditions and scenarios. Often, students are geographically dispersed or under severe timing constraints, because these activities intertwine with their normal university activity. As a result, they need communication technology in order to interact and workflow technology in order to organize their work. The developed platform provides a comprehensible, e-learning-specific set of activities and process templates, which can be combined through a simple Web interface into project-centered collaboration processes. We discuss how the general paradigm of flexible processes was adapted to the learning concept, implemented, and experienced by students.     

Support environment for active rule design

The lack of tools for rule generation, analysis, and run-time monitoring appears one of the main obstacles to the widespreading of active database applications. This paper describes a complete tool environment for assisting the design of active rules applications; the tools were developed at Politecnico di Milano in the context of the IDEA Project, a 4-years Esprit project sponsored by the European Commission which was launched in June 1992. We describe tools for active rule generation, analysis, debugging, and browsing; rules are defined in Chimera, a conceptual design model and language for the specification of active rules applications. We also introduce a tool for mapping from Chimera into Oracle, a relational product supporting triggers.Most of the tools described in this paper are fully implemented and currently in operation (beta-testing) within the companies participating to the IDEA Project, with the exception of two of them (called Argonaut-V and Pandora), which will be completed by the end of 1996.Research presented in this paper is supported by Esprit project P6333 IDEA, and by ENEL contract VDS 1/94: Integrity Constraint Management     

Students’ perceptions of teaching technologies, application of technologies, and academic performance

This study examined business students’ perceptions of four objectives (i.e., Enjoyment, Learning, Motivation, and Career Application) across five teaching technologies (i.e., Projector, PowerPoint, Video, the Internet, and Lecture), business professors’ effective application of technologies, and students’ academic performance. We collected data from 215 students at a regional state university in the USA. We developed Students’ Perceptions of Technology Scale, SPOTS, specifically for the present study, used the most rigorous criteria, and investigated reliability, convergent and discriminant validity, exploratory and confirmatory factor analysis, and measurement invariance of this scale. Mean scores revealed that Video conveyed the highest amount of Enjoyment. PowerPoint provided the highest amount of Learning and Motivation. The Internet provided the highest Career Application for future jobs. Younger students preferred Video, whereas older students favored Lecture. Regression results showed that the use of Video for Learning, Projector and Lecture for Enjoyment, PowerPoint for career and Motivation, and the Internet for Learning contributed to professors’ teaching effectiveness. Students’ high ratings for professors’ effective use of the Lecture method and low expectation for the use of a Projector predicted their self-reported GPA (academic performance). Professors may use a different mix of technologies in the classroom and use them creatively in order to promote the most Learning for students and satisfy students’ Learning needs and objectives.     

Bayesian sample-size determination for two independent Poisson rates

Because of the high cost and time constraints for clinical trials, researchers often need to determine the smallest sample size that provides accurate inferences for a parameter of interest. Although most experimenters have employed frequentist sample-size determination methods, the Bayesian paradigm offers a wide variety of sample-size determination methodologies. Bayesian sample-size determination methods are becoming increasingly more popular in clinical trials because of their flexibility and easy interpretation inferences. Recently, Bayesian approaches have been used to determine the sample size of a single Poisson rate parameter in a clinical trial setting. In this paper, we extend these results to the comparison of two Poisson rates and develop methods for sample-size determination for hypothesis testing in a Bayesian context. We have created functions in R to determine the parameters for the conjugate gamma prior and calculate the sample size for the average length criterion and average power methods. We also provide two examples that implement our sample-size determination methods using clinical data.