Development of a continuous respirometer

A continuous oxygen uptake meter or continuous respirometer was developed which produced a rapid and reliable response to systemic shocks. The respirometer basically is a 101. Plexiglas laboratory activated sludge unit with a variable volume air tight side car. The feed enters the completely mixed aeration basin and is pumped into the side car. The side car is the site of the oxygen uptake measurements as indicated by a continuously monitoring dissolved oxygen probe. The system was most sensitive to changes in influent concentrations when run at an F/M = 0.1. Response time for a change in DO of 0.1 ppm was less than 4 min. The continuous respirometer was tested employing both synthetic and raw industrial wastes.     

Experimental study on the life prediction of servo motors through model-based system degradation assessment and accelerated degradation testing

The advent of smart factories has resulted in the frequent utilization of industrial robots within factories to increase production automation and efficiency. Due to the increase in the number of industrial robots, it has become more important to prevent any unexpected breakdowns of the factory. As a result, the lifespan prediction of machinery has become a crucial factor because such failures can be directly associated with factory productivity resulting in significant losses. Most of the failures occur within one of the core components of the robot arm, the servo motor, and thus we will focus on the analysis of the servo motor in this study. However, sensor attachment to such equipment is considered difficult due to the dynamic movement of the robot arm, meaning that internal instrumentation should be utilized during analysis. In addition, no definite measure to determine the degradation of the motor exists, and thus a new degradation index is proposed in this study. Therefore, in this study, the lifespan of the servo motor will be estimated through accelerated degradation testing methods based on a new system degradation assessment method, which estimates the fault of the system using observer-based residuals with encoder data obtained from internal instrumentation.     

UNI-Copter: A portable single-rotor-powered spherical unmanned aerial vehicle (UAV) with an easy-to-assemble and flexible structure

Journal of Mechanical Science and Technology - This paper presents the design and modeling of the UNI-Copter, a portable spherical unmanned aerial vehicle (UAV) that is powered by a single rotor....     

Advanced Chamfering Technology for Edge Strengthening

Damage‐free chamfering method for strengthening a glass edge was introduced and its effect on the edge property was discussed in detail. The chamfered surface was evaluated using an optical microscope, a confocal LSM, and a birefringence measurement system. The mechanical properties were characterized by measuring hardness, Young's modulus, and bending strength. The results revealed that the cut edge of 0.55t thin glass sheet containing median cracks and chips was exfoliated uniformly to a thickness of 200 μm, and a smooth edge surface was created (Ra = 0.03 μm). We also reported that the chamfered surface had a compressive stress enabling hardness and Young's modulus increase, and the edge strength improved from 117 to 199 MPa.     

A physical strategy for the preparation of isotactic polypropylene spheres with microsphere and bead–string spherulite morphologies

This study mainly focuses on the formation of isotactic polypropylene (iPP) blend morphologies with microspheres and distinct bead–string spherulites. iPP microspheres have been prepared by a simple and convenient strategy through either an isothermal or a nonisothermal crystallization process based on the macrophase‐separated structure in molten state of iPP/olefin block copolymer (OBC) blend. The dimension of the iPP spheres can be adjusted easily from about 1 µm to >10 µm by controlling the compatibility and annealing conditions. It was found that any of the following three parameters, the molecular structure of OBC (particularly the octene content), molecular weight of iPP, and annealing condition can be rescaled with others in controlling the dimension of the iPP microspheres. The mechanism of the formation of iPP microspheres was studied in detail. Surprisingly, the typical spinodal decomposition morphology with interconnected or thin sheet structure is the precursor of these microspheres. During the subsequent annealing process, it breaks up and further coarsens into spherical structure. In addition, distinct spherulites with a bead–string substructure have been obtained during the isothermal crystallization. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40863.     

Copper‐Catalyzed Aerobic Formation of Unstable Sulfinyl Radicals for the Synthesis of Sulfinates and Thiosulfonates

Copper‐catalyzed aerobic coupling of thiols and alcohols affords sulfinates and thiosulfonates. These products are assumed to form via sulfinyl radicals which are not commonly found in oxidative coupling reactions of thiols. A reaction mechanism involving sulfinyl radicals is proposed, and mass and electron paramagnetic resonance (EPR) experimental results are provided.

     

Copper(I) Bromide‐Dimethyl Sulfide‐Catalyzed Direct Sulfanylation of 4‐Hydroxycoumarins and 4‐Hydroxyquinolinones with Arylsulfonylhydrazides and Selective Fluorescence Switch‐ On Sensing of Cadmium(II) Ion in Water

An efficient protocol for the direct sulfanylation of various 4‐hydroxycoumarins and 4‐hydroxyquinolinones in good yield with arylsulfonylhydrazides as sulfanylating agents was developed via copper(I) bromide⋅dimethyl sulfide‐catalyzed S–O, S–N bond cleavage and C–S cross‐coupling reactions. A highly selective fluorescence turning‐on sensing of cadmium(II) ions in water using the synthesized 3‐sulfanyl‐4‐hydroxycoumarin derivative was also investigated.

     

Disparities in exploitative and exploratory patenting performance across regions: Focusing on the roles of agglomeration externalities

We try to identify the determinants of regional variation in both exploitative and exploratory innovative competencies. Hereby, we focus on how a knowledge-creation mechanism with specialized externalities differs from one with diversified externalities. Innovative competence in the US is measured by local patenting performance; exploitative and exploratory patenting performances are distinguished by the degree of backward citation. Based on the extended knowledge-production function, including the two agglomeration externalities, our findings show that specialized externalities are associated with exploitation, while diversified externalities are positively related with both exploration and exploitation, regardless of industrial sectors.