Study on the long‐term thermal‐oxidative aging behavior of polyamide 6

The long‐term thermal‐oxidative aging behavior of polyamide 6 (PA6) was studied by comparison with the stabilized sample in this work. The variation of mechanical properties of the pure and the stabilized samples of PA6 with aging time at 110°C, 130°C, and 150°C were investigated, respectively. The aging mechanism of PA6 under heat and oxygen was studied in terms of the reduced viscosity, crystallization behavior, dynamic mechanical behavior, and chemical composition through the methods of polarized light microscopy (PLM), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), X‐ray photoelectron energy spectrum (XPS), and so on. The results indicated that at the initial stage of aging, the molecular crosslinking reaction of PA6 dominated resulting in the increase of the mechanical strength, reduced viscosity, and the glass transition temperature of the sample. And the molecular degradation dominated in the subsequent aging process resulting in the decrease of the melting temperature, the increase of the crystallinity, and the formation of the oxides and peroxides products. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Thermal stabilization effect of biphenol monoacrylate on polyamide 6

Biphenol monoacrylate (AL) was combined with a traditional hindered phenolic‐based binary antioxidant system to form a ternary stabilization system for the purpose of further improving the thermal–oxidative stability of polyamide 6 (PA6). The thermal stabilization effect of the antioxidant AL on PA6 was studied in terms of the reduced viscosity, the chemical structure, the yellow index, and the mechanical properties. The results showed that the antioxidant AL, with the proper chemical structure, could improve the thermal stability of PA6 effectively through a unique bifunctional stabilizing mechanism. The interaction of the molecules of PA6 with the antioxidant AL was investigated. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Global adaptive control of nonlinearly parametrized systems

In this paper, we consider global adaptive control of nonlinearly parametrized systems in parametric-strict-feedback form. Unlike previous results, we do not require a priori bounds on the unknown parameters, which is as in the linear parametrization case. We also allow unknown parameters to be time-varying provided they are bounded. Our proposed adaptive controller is a switching type controller, in which the controller parameter is tuned in a switching manner via a switching logic. Global stability results of the closed-loop system have been proved.     

STUDY OF STRUCTURAL FEATURE OF PEAT, LIGNITE AND HUMIC ACID BY SOLID STATEl3C NMR SPECTROSCOPY

Four low rank coals (peat and lignite) and their derived humic acids have been investigated by the^l3C CP/MAS/TOSS NMR technique. The NMR analysis indicates that the peat contains a significant amount of unaltered plant components including cellulose, hemicellulose, lignin, waxes, and resins.

Variable contact time and dipolar dephasing experiments were performed on each sample. The data from above experiments, together with normal CP/MAS integration over selected chemical shift range, were used to derive 12 parameters of carbon skeletal structure including the aromaticity.From the ratio of aromatic bridgehead carbons, f_a^cp, to the aromatic peripheral carbons, f^cpxBp as measured by NMR, the aromatic cluster size may be estimated for each coal.     

精密数显转台研制

光电传感和精密刻划技术 ,是开发精密数显转台的主要技术基础。本文详细介绍基本原理、结构要求、功能特点、工艺试验和精度测试等。样机系列表明 ,其精度和性能基本达到和部分指标超过 (国家 )部颁一级精度的标准。     

聚烯烃塑料改性的研究进展

聚乙烯、聚丙烯以优良的力学性能、热性能、加工性能等成为最主要的聚烯烃塑料品种,大量用于生产薄膜、管材和板材。通过改性可获得高刚性、高强度、高耐热、低成本的聚烯烃塑料。综述了近年来聚乙烯和聚丙烯在接枝、交联、填充、共混等方面的改性进展,并指出了研究方向和发展趋势。     

大庆油田深层岩石力学特性参数的试验研究

通过对岩石可钻性、硬度、抗压强度等参数的测量 ,对大庆油田深井不同深度、不同层位、不同岩性的具有广泛代表性的岩心进行试验。并通过线性回归分析 ,建立了适用性较广的钻井岩石力学特性参数预测模型 ,为深井钻头选型提供了依据。     

广州新机场启用不久就漏水说明了什么?

2004年8月22日上海《新闻晨报》报导：“20日下午，广州一场暴雨让刚刚启用半个月的新白云国际机场航站楼就发现屋顶漏水，候机厅内下起了小雨，旅客和机场安检人员都被淋湿。据机场监理部门介绍，该机场航站楼顶部呈弧形，其中部屋盖使用的是国际先进的PTFE张拉膜。雨水主要是从屋顶的天沟里渗进来的。另有消息说，在同样位置上过去也出现过漏雨。”     

特大型油罐整体一次性控爆拆除

本文介绍了特大型油罐整体一次性控制爆破拆除方案及其实施方法，这一方法与水压爆破拆除和常规钻孔爆破拆除方法相比，具有工效高，安全性好的突出优点。