Properties of poly(n‐butyl methacrylate) prepared by reverse atom transfer radical polymerization in an aqueous dispersed system

Reverse atom transfer radical polymerization (ATRP) of n‐butyl methacrylate (BMA) in waterborne media using Cu(II) complexes with azo initiators (i.e., reverse ATRP) was conducted. The influence of several factors, such as surfactant, catalyst, and reaction time, on the stability of the emulsion, the particle size, the morphology of the emulsion particles, and the control of the polymerization was investigated. The results showed great differences between ATRP and conventional emulsion polymerization, especially the nucleation mechanism and the kinetics. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1542–1547, 2003     

用加权余量法计算球形催化剂的有效因子

本文利用加权余量法计算了等温球形催化剂的有效因子,并对催化反应n=1,2的两种情况与其它简化法进行了比较.文中取Dirac函数作为权函数,形式简单,在袖珍计算器上就能完成计算.其结果:当n=1时,与解析解非常接近;当n=2时,优于其它三种简化解法,很接近数值解.     

Transformation of β-Ni(OH)2 to NiO nano-sheets via surface nanocrystalline zirconia coating: Shape and size retention

Shape and size of the synthesized NiO nano-sheets were retained during transformation of sheet-like β-Ni(OH)₂ to NiO at elevated temperatures via nano-sized zirconia coating on the surface of β-Ni(OH)₂. The average grain size was 6.42 nm after 600 °C treatment and slightly increased to 10 nm after 1000 °C treatment, showing effective sintering retardation between NiO nano-sheets. The excellent thermal stability revealed potential application at elevated temperatures, especially for high temperature catalysts and solid-state electrochemical devices.     

铟（Ⅲ）－钼酸铵－罗丹明B显色反应体系的研究及其应用

铟（Ⅲ）与钼酸铵和罗丹明Ｂ在ＰＶＡ存在下的酸性水溶液中形成离子缔合物而产生显色反应，该体系的灵敏度高，摩尔吸光系数ε＝２．４４×１０５Ｌ·ｍｏｌ－１ｃｍ－１，离子缔合物稳定性好，至少稳定４８ｈ。研究了显色体系的光度特性和３０多种共存离子的影响，该法应用于纯锡中痕量铟的测定，结果满意。     

PVC／PU合金的制备与研究

叙述了选择混炼型聚氨酯(PU)与分子量适中的Ⅱ型聚氯乙烯(PVC)树脂制备PVC/PU合金的过程,讨论了PVC/PU共混比、填充剂、硫化体系、共混工艺等因素对PVC/PU合金性能的影响。结果表明:选择PVC/PU=60/40(质量比),硫化剂TD15份,白炭黑30份,混炼温度140—160℃,可制得性能优良的PVC/PU合金。动态力学性能实验显示了PVC/PU合金有较好的相容性。     

超临界流体技术应用研究

超临界流体技术具有许多传统技术所没有的快速，高效，低能耗，污染少等优点，在材料制备，医药工业，生物工程，食物，环境，化工等许多方面展现了广阔的应用前景。综述了其在萃取，材料制备和作为反应介质等方面的应用。     

Cu2O/Cu Cermet as a Candidate Inert Anode for Al Production

Cu₂O/ x Cu ( x =0–25 wt%) cermets were evaluated as a novel partially inert anode for aluminum (Al) production. The physical and mechanical properties, including the compressive strength, flexural strength, thermal expansion coefficient, thermal conductivity, and dc electrical conductivity were tested at room temperature and at temperatures up to 950°C. The coefficient of thermal expansion, compressive strength, flexural strength, thermal conductivity, and electrical conductivity of Cu₂O/Cu cermets increased with increasing Cu content. High-temperature electrical conductivity measurements showed that with increasing temperature, the electrical conductivity increased when the Cu content was below the percolation threshold, while it decreased when the Cu content was above the percolation threshold. A relatively stable CuAlO₂ layer formed on the cermet surface during electrochemical testing, and the corrosion rate of this anode was estimated to be about 1.8–1.9 cm/year in Al production.     

Fabricating Water-Insoluble Polyelectrolyte into Multilayers with Layer-by-layer Self-assembly

Summary A water insoluble azo-containing polyelectrolyte (PEAPB6P-AC) was successfully fabricated into multilayer films based on the layer-by-layer adsorption technique by using N, N-dimethylformamide (DMF) as the assembling media. The multilayer growth and structure were studied with UV-vis spectroscopy, and the multilayer surface were imaged with Atomic Force Microscopy and compared with that fabricated in water. The results show that assembling PEAPB6P-AC in DMF can effectively eliminate the hydrophobic aggregation of the azo units and consequently results in a much smoother multilayer surface than that fabricated in water. This improvement to the layer-by-layer adsorption technique, which can avoid some major difficulties faced when assembling hydrophobic polyelectrolytes in aqueous solutions, seems to be a versatile way to fabricate high quality multilayer films when using the hydrophobic even water-insoluble polyelectrolytes as assembling units.     

企业核心竞争力关键要素——质量

介绍了如何体现产品质量及如何控制产品质量。     

PARAMETER ESTIMATION IN EXPONENTIAL MODELS

Abstract. In this paper the problems of parameter estimation and order determination of an exponential (EX) model are studied in the time domain. In order to estimate the parameters, the parameter equations of an EX model are given in terms of the autocorrelation function, which is similar to the Yule-Walker equations of an autoregressive moving-average model. Estimates of parameters are obtained with the aid of the parameter equations and theorems are proved relating the convergence rate and asymptotic distribution of the estimates. We present two kinds of methods for estimating the order and prove that the estimates of the order are consistent.