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991.
992.
993.
反应挤出法制备马来酸酐接枝POE 总被引:8,自引:1,他引:8
采用双螺杆挤出机反应挤出制备马来酸酐接枝乙烯-1-辛烯共聚物(POE-g-MAH)。通过红外光谱分析(FTIR)、化学滴定等方法,揭示MAH过氧化二异丙苯(DCP)及供电子体(EDS)对接枝物的接枝率(GD)、凝胶率、熔体指数(MI)的影响规律。MAH和DCP的加入使MI降低,GD增大;过量的MAH使激发态的MAH猝灭,导致能引发接枝反应的激发态MAH和大分子自由基的数量减少,从而使MI上升及GD下降。在高剪切、短停留时间的挤出机中,EDS会使接枝物的性能恶化。与传统的EPDM-g-MAH增韧尼龙相比,PA/POE-g-MAH复合材料的强度保持相当,而韧性明显提高。 相似文献
994.
In this study, a thiirane resin was synthesized by the reaction of corresponding epoxy resin with KSCN. The synthetic conditions influencing the conversion of epoxy group were systematically investigated, such as the reaction temperature, reaction media, reaction time and the ratio of KSCN to epoxy group. It was found that the conversion of epoxy group increased with the increasing reaction temperature, improving the solubility of the mediate, extending reaction time, and the enhancing ratio of salt (KSCN) to epoxy group. Wherein, the reaction temperature and the ratio of the KSCN to epoxy group were more effective. For example, when the molar ratio of KSCN to epoxy group was equal to 2.0, the conversion of epoxy group got the maximum value, 0.65. In addition, the hot plate method was used to measure the gelling time of the resultant thiirane resin at different temperatures. It was found that the gelling time was reduced to 47–85% times as the corresponding epoxy resin depending on the conversion of the epoxy group, and the curing activation energy was diminished from 39 kJ/mol of epoxy resin to 17 kJ/mol. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 4023–4027, 2006 相似文献
995.
坦克装甲车辆用橡胶履带板的研究开发 总被引:1,自引:0,他引:1
探讨了坦克装甲车辆用橡胶履带板(TTRP)的损坏摸式及其机理,从胶料配合,性能测试等方面评 TTRP的研究开发进展,并对我国TTRP的研究提出了建议。 相似文献
996.
高岭土尾砂综合利用工艺研究 总被引:1,自引:0,他引:1
高岭土是制瓷工业的主要原料,在开采用加工过程中生产大量尾砂,污染环境且导致资源浪费,通过本试验研究,从尾砂中分选出工业上可综合利用的长石,云母等系列产品,并实现了无尾矿选矿新工艺。 相似文献
997.
The graft polymerization of methyl methacrylate and butyl acrylate onto poly(vinyl chloride‐co‐vinyl acetate) with atom transfer radical polymerization (ATRP) was successfully carried out with copper(I) thiocyanate/N,N,N′,N′,N″‐pentamethyldiethylenetriamine and copper(I) chloride/2,2′‐bipyridine as catalysts in the solvent N,N‐dimethylformamide. For methyl methacrylate, a kinetic plot of ln([M]0/[M]) (where [M]0 is the initial monomer concentration and [M] is the monomer concentration) versus time for the graft polymerization was almost linear, and the molecular weight of the graft copolymer increased with increasing conversion, this being typical for ATRP. The formation of the graft polymer was confirmed with gel permeation chromatography, 1H‐NMR, and Fourier transform infrared spectroscopy. The glass‐transition temperature of the copolymer increased with the concentration of methyl methacrylate. The graft copolymer was hydrolyzed, and its swelling capacity was measured. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 183–189, 2005 相似文献
998.
999.
Chunnuan Ji Rongjun Qu Cheng Bo Cao Huo Chen Qiang Xu Changmei Sun Chunhua Wang Huafang Yuan Jun Zhou 《应用聚合物科学杂志》2006,102(6):6054-6059
A novel chelating resin containing sulfoxide and diethylene glycol, poly{4‐vinylbenzyl‐[2‐2‐(hydroxyethyl)ethoxyl]sulfoxide} (PVESO) was synthesized using chloromethylated polystyrene (PS‐Cl) as material. Its structure was characterized by elemental analysis, infrared spectra, and scanning electron microscopy (SEM). The adsorption capacities of the resin for Hg2+, Ag+, Cu2+, Zn2+, and Pb2+ at various pH values were determined. The maximum adsorption capacities for Hg2+ and Ag+ were 1.56 and 0.75 mmol g?1 respectively. The resin had high selectivity for Hg2+ and Ag+ over the pH range 1.0–7.0. The adsorption capacities for Hg2+ and Ag+ under competitive condition were also determined by batch experiment method. In addition, the adsorption kinetics of the resin towards Hg2+ at different temperatures was also investigated. The results showed that the adsorption rate was governed by film diffusion at 20°C and 25°C, by particle diffusion at 30°C and 35°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 6054–6059, 2006 相似文献
1000.
Ji‐Sun Im Ju‐Hyung Lee Seung‐Kook An Ki‐Won Song Nam‐Ju Jo Jang‐Oo Lee Kohji Yoshinaga 《应用聚合物科学杂志》2006,100(3):2053-2061
A new type of polyimide/silica (PI/SiO2) hybrid composite films was prepared by blending polymer‐modified colloidal silica with the semiflexible polyimide. Polyimide was solution‐imidized at higher temperature than the glass transition temperature (Tg) using 3,3′,4,4′‐biphenyltetracarboxylic dianhydride (BPDA) and 4,4′‐diaminodiphenyl ether (ODA). The morphological observation on the prepared hybrid films by scanning electron microscopy (SEM) pointed to the existence of miscible organic–inorganic phase, which resulted in improved mechanical properties compared with pure PI. The incorporation of the silica structures in the PI matrix also increased both Tg and thermal stability of the resulting films. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2053–2061, 2006 相似文献