Seed-mediated grown platinum nanocrystal: A correlation between seed volume and catalytic performance of formic acid and ethanol oxidation

Platinum (Pt) nanocrystals of cubic and octopod structures were synthesized via seed-mediated solvothermal growth with monoethanolamine as the solvent. The combination of nanocube and octopod structures was formed using 0.025 ml seeds loading, while increasing the seeds volume to 0.050 ml and 0.100 ml produced nanocube as the primary product. The octopod structure evolves from the overgrown nanocube via kinetic growth mechanism. Pt nanocube formed with 0.050 ml seeded solution has the potential to serve as a catalyst in formic acid oxidation by virtue of its high electrochemical surface area of 10.93 m²/g, over that of Pt black at 8.62 m²/g and resistance to poisonous CO. Nonetheless, it is less catalytically active in ethanol oxidation as depicted by the small electrochemical surface area of 8.64 m²/g and low current density in longer period.     

Unambiguously Enhanced Ultraviolet Luminescence of AlGaN Wavy Quantum Well Structures Grown on Large Misoriented Sapphire Substrate

High‐quality epitaxy consisting of Al_1?xGa_xN/Al_1?yGayN multiple quantum wells (MQWs) with sharp interfaces and emitting at ≈280 nm is successfully grown on sapphire with a misorientation angle as large as 4°. Wavy MQWs are observed due to step bunching formed at the step edges. A thicker QW width accompanied by a greater accumulation of gallium near the macrostep edge than that on the flat‐terrace is observed on 4° misoriented sapphire, leading to the generation of potential minima with respect to their neighboring QWs. Consequently, a significantly enhanced photoluminescence intensity (at least ten times higher), improved internal quantum efficiency (six times higher at low excitation laser power), and a much longer carrier lifetime are achieved. Importantly, the wafer‐level output‐power of the ultraviolet light emitting diodes on 4° misoriented substrate is nearly increased by 2–3 times. This gain is attributed to the introduction of compositional inhomogeneities in AlGaN alloys induced by gallium accumulation at the step‐bunched region thus forming a lateral potential well for carrier localization. The experimental results are further confirmed by a numerical modeling in which a 3D carrier confinement mechanism is proposed. Herein, the compositional modulation in active region arising from the substrate misorientation provides a promising approach in the pursuit of high‐efficient ultraviolet emitters.     

Passively Q-switched erbium-doped fibre laser using cobalt oxide nanocubes as a saturable absorber

We demonstrate a Q-switched Erbium-doped fibre laser (EDFL) utilizing cobalt oxide (Co₃O₄) nanocubes film based saturable absorber (SA) as a passive Q-switcher. Co₃O₄ nanocubes are embedded into a polyethylene oxide film to produce a high nonlinear optical response, which is useful for SA application. It has saturation intensity and modulation depth of 3 MW/cm² and 0.35%, respectively. The proposed laser cavity successfully generates a stable pulse train where the pulse repetition rate is tunable from 29.8 to 70.92 kHz and the pulse-width reduces from 10.9 to 5.02 μs as the 980 nm pump power increases. This result indicates that the Co₃O₄ is excellent for constructing an SA that can be used in producing a passively Q-switched fibre laser operating at a low pump intensity. To the best of our knowledge, this is the first demonstration of Co₃O₄ film based fibre laser.     

Charge-trapping effects caused by ammonia in carbon nanotubes

Hysteretic behaviors caused by low-concentration ammonia gas are found in single-walled carbon nanotube based field-effect transistors. The transfer curves are found to shift towards negative gate voltage when the gate voltage is swept forwardly upon introducing ammonia. In contrast, no significant change in the transfer curves is observed for the backward sweeping of the gate voltage. This phenomenon is repeatable even after the devices are annealed in dry air at 200 degrees C for 2 hrs. Our findings can be interpreted in terms of additional charge traps induced by the adsorbed ammonia molecules. The observed hysteretic behavior enables the devices to work as memory cells, in which the carbon nanotube field-effect transistors act as readout and ammonia molecules play roles of charge storage.     

The indispensability of dispensable indexes

The design of new indexes has been driven by many factors, such as data types, operations, and application environment. The increasing demand for database systems to support new applications such as online analytical processing (OLAP), spatial databases, and temporal databases has continued to fuel the development of new indexes. In this paper, we summarize the major considerations in developing new indexes, paying particular attention to progress made in the design of indexes for spatial, temporal databases, and object-oriented databases (OODB). Our discussion focuses on the general concepts or features of these indexes, thus presenting the building blocks for meeting the challenges of designing new indexes for novel applications to be encountered in the future     

Current equalization in SPWM FACTS controllers at lowest switchingrates

This paper shows that sinusoidal pulsewidth modulation (SPWM) flexible AC transmission system (FACTS) controllers can be synthesized by employing the phase-shifted triangle carrier technique to multiconverters at a switching rate of only three pulses. The options of parallel, series and series/parallel module connections are examined for current equalization. This paper presents simulation and experimental results     

S-parameter based technique for simultaneous switching noiseanalysis in electronic packages

A method based on S-parameters is developed for the analysis of simultaneous switching noise (SSN) in electronic packages. A two-port Z matrix of the package pin/trace, and the coupling between the pins/traces are modeled by analytical equations. SSN is analyzed as a function of the number of switching drivers and switching time. Frequency domain measurements are performed to demonstrate the accuracy of the model. The modeling methodology is applied to both leaded and area array packages     

Efficient Join Processing Using Partial Precomputation

In this paper, we generalize conventional join indexes to a cluster-based join index, in which objects are grouped into clusters based on proximity. Each record of our join index represents a pair of clusters in which the join condition is satisfied by some members of the cluster. This strategy is especially useful for spatial and high-dimensional databases because of their typically large data volume and complex operations. Our approach leverages on the structure of R-trees by exploiting the internal nodes of an R-tree in effectively determining the precomputed clusters which can be used in our join index. By varying the size of the cluster, we are able to fine-tune the join index to achieve a balance between update cost and retrieval cost to suit individual applications. Different implementations of the join index are examined to determine how the join index can be efficiently maintained. To this end, we also conduct a number of experiments on intersection join and window queries, and the results confirm that semi-precomputation of join results is a robust and cost effective approach to join processing.     

A Hybrid Fast Multipole Pseudo-Spectral Time Domain Method

The major computation cost of pseudo-spectral method comes from the evaluation of differentiation matrix multiplication. In the past, uniform or Chebyshev collocation points are used for sampling. The differentiation matrix multiplication was evaluated by fast Fourier transform (FFT) or fast cosine transform (FCT), in order to reduce the computation complexity from O(N²) to O(N log(N)). However, the intrinsic properties of FFT or FCT may cause the wraparound effect and Gibbs phenomenon. Moreover, FFT or FCT is not applicable to other collocation points such as Legendre and Hermite. In order to improve the accuracy and applicability of the pseudo-spectral method, the fast multipole method (FMM) is exploited to substitute the FFT or FCT. By making use of the similarity of the N-body problem and the collocation problem, a new FMM-based pseudo-spectral time domain method is developed in this paper.     

An improved prediction of series resistance in spiral inductormodeling with eddy-current effect

Based on an earlier study by Kuhn and Ibrahim (see IEEE J. Trans. Microwave Theory Tech., vol. 49, no. 1, p. 31-38, 2001) on current crowding, an improved expression incorporating the skin effect for the prediction of series resistance in spiral inductor modeling has been derived. A modified model for the spiral inductor, which accounts for the eddy-current effect, is thus proposed. Relatively good agreements between the measured data and the results generated from the model are obtained