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排序方式: 共有1175条查询结果,搜索用时 15 毫秒
11.
Simona Caudo Gabriele Centi Chiara Genovese Siglinda Perathoner 《Topics in Catalysis》2006,40(1-4):207-219
Homogeneous (Cu2+ ions) and heterogeneous (Cu2+-pillared clay) Fenton-like catalysts have been compared in the conversion of p-coumaric acid. The performances of the two classes of catalysts are similar for an analogous amount of copper, but there are
some relevant differences in terms of (i) the presence of an induction time, (ii) the turnover frequency, (iii) the efficiency
in the use of H2O2, (iv) the initial attack of p-coumaric acid (hydroxylation on the aromatic ring or oxidative attack on the double bond of the lateral chain), and (v) the
effect of dissolved oxygen on the removal of total organic carbon (TOC). These differences were interpreted in terms of reaction
network of generation of radical oxygen species and of organics conversion. The possible formation of a surface peroxo adduct
coordinated to a copper binulcear site was also evidenced for the solid heterogeneous catalyst. 相似文献
12.
Chiara Damiani Dario Pescini Riccardo Colombo Sara Molinari Lilia Alberghina Marco Vanoni Giancarlo Mauri 《Natural computing》2014,13(3):321-331
Constraint-based modeling is largely used in computational studies of metabolism. We propose here a novel approach that aims to identify ensembles of flux distributions that comply with one or more target phenotype(s). The methodology has been tested on a small-scale model of yeast energy metabolism. The target phenotypes describe the differential pattern of ethanol production and O2 consumption observed in “Crabtree-positive” and “Crabtree-negative” yeasts in changing environment (i.e., when the upper limit of glucose uptake is varied). The ensembles were obtained either by selection among sampled flux distributions or by means of a search heuristic (genetic algorithm). The former approach provided indication about the probability to observe a given phenotype, but the resulting ensembles could not be unambiguously partitioned into “Crabtree-positive” and “Crabtree-negative” clusters. On the contrary well-separated clusters were obtained with the latter method. The cluster analysis further allowed identification of distinct groups within each target phenotype. The method may thus prove useful in characterizing the design principles underlying metabolic plasticity arising from evolving physio-pathological or developmental constraints. 相似文献
13.
The Alder ene functionalization reaction of double bonds containing macromolecules such as polyisobutene oligomer (PIB) and a styrene-butadiene-styrene triblock copolymer (SBS) samples with maleic anhydride (MAH) or diethyl maleate (DEM) as enophiles is described. The analysis of the products by means of different techniques assesses the addition of the polar molecules to the reactive vinylidene units of the polymer with functional degrees (FD) depending on the type of enophile and polymer reactivity. The role of the reaction conditions and the use as Lewis acids as catalysts are discussed in terms of their influence on the addition reaction extent and on the polymer molecular weight. 相似文献
14.
Cecilia Laschi Gioel Asuni Eugenio Guglielmelli Giancarlo Teti Roland Johansson Hitoshi Konosu Zbigniew Wasik Maria Chiara Carrozza Paolo Dario 《Autonomous Robots》2008,25(1-2):85-101
This paper presents a sensory-motor coordination scheme for a robot hand-arm-head system that provides the robot with the capability to reach an object while pre-shaping the fingers to the required grasp configuration and while predicting the tactile image that will be perceived after grasping. A model for sensory-motor coordination derived from studies in humans inspired the development of this scheme. A peculiar feature of this model is the prediction of the tactile image. The implementation of the proposed scheme is based on a neuro-fuzzy module that, after a learning phase, starting from visual data, calculates the position and orientation of the hand for reaching, selects the best-suited hand configuration, and predicts the tactile feedback. The implementation of the scheme on a humanoid robot allowed experimental validation of its effectiveness in robotics and provided perspectives on applications of sensory predictions in robot motor control. 相似文献
15.
Chiara Braghin Natasha Sharygina Katerina Barone-Adesi 《Formal Aspects of Computing》2011,23(5):627-648
This article describes an approach for the automated verification of mobile systems. Mobile systems are characterized by the
explicit notion of location (e.g., sites where they run) and the ability to execute at different locations, yielding a number of security issues. To
this aim, we formalize mobile systems as Labeled Kripke Structures, encapsulating the notion of location net that describes the hierarchical nesting of the threads constituting the system. Then, we formalize a generic security-policy specification language that includes rules for expressing and manipulating the code location. In contrast to many other approaches, our technique
supports both access control and information flow specification. We developed a prototype framework for model checking of
mobile systems. It works directly on the program code (in contrast to most traditional process-algebraic approaches that can
model only limited details of mobile systems) and uses abstraction-refinement techniques, based also on location abstractions,
to manage the program state space. We experimented with a number of mobile code benchmarks by verifying various security policies.
The experimental results demonstrate the validity of the proposed mobile system modeling and policy specification formalisms
and highlight the advantages of the model checking-based approach, which combines the validation of security properties with
other checks, such as the validation of buffer overflows. 相似文献
16.
17.
Eugenio CapraAuthor Vitae Chiara FrancalanciAuthor Vitae 《Journal of Systems and Software》2011,84(1):144-161
Open Source (OS) was born as a pragmatic alternative to the ideology of Free Software and it is now increasingly seen by companies as a new approach to developing and making business upon software. Whereas the role of firms is clear for commercial OS projects, it still needs investigation for projects based on communities. This paper analyses the impact of firms’ participation on popularity and internal software design quality for 643 SourceForge.net projects. Results show that firms’ involvement improves the ranking of OS projects, but, on the other hand, puts corporate constraints to OS developing practices, thus leading to lower structural software design quality. 相似文献
18.
Multimodal support to group dynamics 总被引:1,自引:1,他引:0
Fabio Pianesi Massimo Zancanaro Elena Not Chiara Leonardi Vera Falcon Bruno Lepri 《Personal and Ubiquitous Computing》2008,12(3):181-195
The complexity of group dynamics occurring in small group interactions often hinders the performance of teams. The availability
of rich multimodal information about what is going on during the meeting makes it possible to explore the possibility of providing
support to dysfunctional teams from facilitation to training sessions addressing both the individuals and the group as a whole.
A necessary step in this direction is that of capturing and understanding group dynamics. In this paper, we discuss a particular
scenario, in which meeting participants receive multimedia feedback on their relational behaviour, as a first step towards
increasing self-awareness. We describe the background and the motivation for a coding scheme for annotating meeting recordings
partially inspired by the Bales’ Interaction Process Analysis. This coding scheme was aimed at identifying suitable observable
behavioural sequences. The study is complemented with an experimental investigation on the acceptability of such a service.
相似文献
Fabio Pianesi (Corresponding author)Email: |
Massimo ZancanaroEmail: |
Elena NotEmail: |
Chiara LeonardiEmail: |
Vera FalconEmail: |
Bruno LepriEmail: |
19.
Antonino Valenza Chiara Borsellino Luigi Calabrese Guido Di Bella 《Applied Composite Materials》2006,13(4):217-235
Composite materials are widely employed in sailing sports, a possible application is for the mast pole or other sail poles. In the paper the attention is focused on the spinnaker poles mechanical performances; in particular the focus is on axial and ring compressive properties of three different carbon fibre/epoxy resin spinnaker poles, to investigate both the diameter and stacking sequence effect on the mechanical performance of the structure. Starting from the stacking sequence used in the production of a particular spinnaker pole, the effect of a lamina at 0° in the middle of wall thickness is investigated with the purpose to obtain a more stiff structure. Moreover to test the proposed stacking sequence on different size products, a prototype with lower diameter is realized. To properly evaluate axial and ring stiffness, axial compression test and ring stiffness one are performed. Then a numerical model is developed to support the design of the finished product: A simple and versatile numerical analysis (FEA with software ANSYS), by simulating ring stiffness and pull-direction compression tests, is carried out in elastic regime. Such model should be suitable for designing and/or verifying the mechanical performance of pole structures, even though differing from those above described, for materials, geometry and stacking sequence. 相似文献
20.
Chiara Trincianti Vincenzo Meleca Edoardo La Porta Maurizio Bruschi Giovanni Candiano Andrea Garbarino Xhuliana Kajana Alberto Preda Francesca Lugani Gian Marco Ghiggeri Andrea Angeletti Pasquale Esposito Enrico Verrina 《International journal of molecular sciences》2022,23(10)
Peritoneal dialysis (PD) represents the dialysis modality of choice for pediatric patients with end-stage kidney disease. Indeed, compared with hemodialysis (HD), it offers many advantages, including more flexibility, reduction of the risk of hospital-acquired infections, preservation of residual kidney function, and a better quality of life. However, despite these positive aspects, PD may be associated with several long-term complications that may impair both patient’s general health and PD adequacy. In this view, chronic inflammation, caused by different factors, has a detrimental impact on the structure and function of the peritoneal membrane, leading to sclerosis and consequent PD failure both in adults and children. Although several studies investigated the complex pathogenic pathways underlying peritoneal membrane alterations, these processes remain still to explore. Understanding these mechanisms may provide novel approaches to improve the clinical outcome of pediatric PD patients through the identification of subjects at high risk of complications and the implementation of personalized interventions. In this review, we discuss the main experimental and clinical experiences exploring the potentiality of the proteomic analysis of peritoneal fluids and extracellular vesicles as a source of novel biomarkers in pediatric peritoneal dialysis. 相似文献