Bayesian assessing for a repairable system with standby imperfect switching and reboot delay

System performance measures of a repairable system are studied from a Bayesian viewpoint with different types of priors assumed for unknown parameters, in which the system consists of two active components and one warm standby. There is a failure probability q that switches from standby state to active state. Time-to-failure of components is assumed to be an exponential distribution. The reboot time and repair time are also exponential distributions. When time-to-failure, time-to-repair and reboot time are with uncertain parameters, a Bayesian assessing is adopted to evaluate system performance measures. Monte Carlo simulation is used to derive the posterior distribution for the steady-state availability and the mean time-to-system failure. Some numerical experiments are performed to illustrate the results derived in this article.     

Effects of structures of pyrolyzed corrin,corrole and porphyrin on oxygen reduction reaction

The effects of the structures of various pyrolyzed cobalt-based macrocyclic compounds, which are pyrolyzed cobalt-corrin compounds (py-Co-Corrin/C), pyrolyzed cobalt-corrole compounds (py-Co-Corrole/C) and pyrolyzed cobalt-porphyrin compounds (py-Co-Porphyrin/C), on their activities in the oxygen reduction reaction (ORR) are studied. Following the pyrolysis, py-Co-Corrin/C has a higher ORR activity than py-Co-Corrole/C and py-Co-Porphyrin/C, which their electron-transfer numbers are 3.90, 3.87 and 3.37 at 0.3 V, respectively. According to the analysis of near edge X-ray absorption fine structure in N K-edge, only py-Co-Corrin/C has the Co–N₄ chelate and poly-aromatic hydrocarbons when pyrolyzed at high temperature. The X-ray absorption spectra reveal the oxidation states of central cobalt in cobalt-based macrocyclic compounds which are changed from high to low. Also, the atomic distances of cobalt to its neighbors vary among all of the samples. The experimental results suggest that the structure and the coordination of cobalt-based macrocyclic compounds strongly affect their ORR activities.     

Exact solutions for plastic responses of orthotropic strain-hardening rotating hollow cylinders

This paper presents exact solutions for plastic responses of plastically orthotropic strain-hardening rotating hollow cylinders. Hill’s yield criterion and the Voce hardening law were adopted. The concept of sequential limit analysis was employed to deal with the strain-hardening behavior by updating the yield criterion and the deformed configuration sequentially. First, exact solutions of the plastic angular velocity were acquired by solving both static and kinematic limit analysis problems. The existence of closed-form exact solutions for some cases was also illustrated. Moreover, the global hardening behavior was analytically evaluated. The corresponding distributions of plastic stress components and equivalent plastic strain were also developed. Second, the elastic–plastic capability of the commercial finite-element code ABAQUS was employed for rigorous validations of analytical solutions. Finally, good agreement is observed between analytical solutions and numerical results.     

Novel 1,3,4-oxadiazole derivatives as efficient sensitizers for dye-sensitized solar cells: A combined experimental and computational study

We have synthesized and characterized donor–π–spacer–acceptor type molecules in which 1,3,4-oxadiazoles are π-spacers, triphenylamines are the donors and cyanoacetic acid are the acceptors for use as sensitizers in dye-sensitized solar cells (DSSCs). Detailed absorption, emission, electrochemical, photoelectrochemical and computational studies have been carried out on five novel derivatives. The dyes have an absorption range of 377–388 nm, and an emission in the range of 494–540 nm. There is a large charge transfer from the donor side to the acceptor side on excitation. The propeller shape of the triphenylamine and the bulky substituents on it help in reducing the dye-aggregation on TiO₂ surface. The dyes exhibited good overall conversion efficiency (2.79–3.21%). Plane wave calculations indicate that the dye has a reasonably strong binding to the TiO₂ surface and the generated DOS picture shows an overlap of the molecular orbitals of the dye and the TiO₂ bands. We conclude that the dyes have a promising role as sensitizers in DSSC.     

Calibration and on-line data selection of multiple optical flow sensors for odometry applications

This work proposes a calibration method and a computational algorithm to integrate the data of multiple optical flow sensors for two-dimensional trajectory measurements. Optical flow sensors offer a different kind of odometer as compared to the wheel encoder. Using multiple sensors can reduce the effect of measurement uncertainties. Since all sensors are mounted on a rigid body, their measurement data must obey a certain relation, which is utilized in this work. Additionally, mathematical formulae are developed to realize the computation. Analytical results show that the calibration procedure can be cast as an optimization problem given measurement data. Furthermore, the rigid-body relation is formulated as a null-space constraint using the calibrated parameters. Unreliable sensor measurements can be removed during operation by accessing the error distance to the null space. Experimental results are presented to support the proposed methods.     

Drop printing of pharmaceuticals: Effect of molecular weight on PEG coated‐naproxen/PEG 3350 solid dispersions

Solid dispersions have been used to enhance the bioavailability of poorly water‐soluble active pharmaceutical ingredients (APIs). However, the solid‐state phase, compositional uniformity, and scale‐up problems are issues that need to be addressed. To allow for highly controllable products, the drop printing (DP) technique can provide precise dosages and predictable compositional uniformity of APIs in two‐/three‐dimensional structures. DP was used to prepare naproxen (NAP)/polyethylene glycol 3350 (PEG 3350) solid dispersions with PEG coatings of different molecular weights (MWs). A comparison of moisture‐accelerated crystallization inhibition by different PEG coatings was assessed. Scanning electron microscopy, second harmonic generation microscopy, and differential scanning calorimetry analysis were performed to characterize the morphology and quantify the apparent crystallinity of NAP within the solid dispersions. Thermogravimetric analysis was employed to measure the water content within each sample. The results suggest that the moisture‐accelerated crystallization inhibition capability of the PEG coatings increased with increasing MW of the PEG coating. Besides, to demonstrate the flexibility of DP technology on manufacturing formulation, multilayer tablets with different PEG serving as barrier layers were also constructed, and their dissolution behavior was examined. By applying DP and appropriate materials, it is possible to design various carrier devices used to control the release dynamics of the API. © 2015 American Institute of Chemical Engineers AIChE J, 61: 4502–4508, 2015     

Measurement of heat/mass transfer at second stage vane endwall according to step heights

Journal of Mechanical Science and Technology - Recently, domestic gas turbines are primarily operated under partial loads. Hence, thermal expansion of components decreases, leading to a...