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1.
Liquid–liquid two‐phase epoxidation from cyclohexene and cyclooctene in aqueous potassium peroxymonosulfate (commercially available as Oxone®) solution was studied as an application in pollution prevention. To avoid potential emissions of volatile organic compounds an aqueous solution was employed to replace the usual chlorinated solvents used in epoxide production. A droplet column reactor and stirred tank reactor were used to investigate two‐phase synthesis of epoxide. An aqueous Oxone® solution was used to oxidize a dispersion of alkene droplets and form epoxide. The study of aqueous epoxidation in both reactors showed that the epoxidation of alkenes can be represented as a first order reaction with respect to alkene. The salting out effect of Oxone® concentration was studied in both reactors and found to be very similar at optimal conditions. In comparing the two reactors, it was found that the droplet column reactor produces larger quantities of product per unit reactor volume for the same reaction time. The objective of this study is to provide an alternative reactor design and synthesis route that can meet pollution prevention goals. Copyright © 2004 Society of Chemical Industry  相似文献   
2.
This study investigates the ozonation of CI Reactive Black 5 (RB5) by using the rotating packed bed (RPB) and completely stirred tank reactor (CSTR) as ozone contactors. The RPB, which provides high gravitational force by adjusting the rotational speed, was employed as a novel ozone contactor. The same ozone dosage was separately introduced into either the RPB or the CSTR for the investigation, while the experimental solution was continuously circulated within the apparatus consisting of the RPB and CSTR. The decolorization and mineralization efficiencies of RB5 in the course of ozonation are compared for these two methods. Moreover, the dissolved and off‐gas ozone concentrations were simultaneously monitored for the further analysis. As a result, the ozone mass transfer rate per unit volume of the RPB was significantly higher because of its higher mass transfer coefficient and gas–liquid concentration driving force. Furthermore, ozonation kinetics was found to be independent of the gravitational magnitude of an ozone gas–liquid contactor. Therefore, the results suggest employing RPBs as ozone‐contacting devices with the advantage of volume reduction. The experimental results, which can be used for further modeling of the ozonation process in the RPB, also show the requirement of correct design for the RPB. Consequently, the present study is useful for the understanding of practical application of RPBs. Copyright © 2004 Society of Chemical Industry  相似文献   
3.
We present a method to obtain complete information of femtosecond pulses. By measuring triple-optical autocorrelation directly with third-harmonic generation, without spectral information, a temporal pulse shape can be obtained by analytical calculation without direction-of-time ambiguity. Combining the resulting optical pulse shape with its corresponding optical spectrum, the exact phase and color variations in time can all be recovered with a Gerchberg-Saxton algorithm through an iterative calculation with an O(n) complexity.  相似文献   
4.
Recent advances in control systems analysis and design have implied new uses for the Lyapunov equation of the form AX+XAT+Q=0. Implementation requirements for the incorporation of the use of Lyapunov equations in practical design, however, point out the need for a set of specialized numerical procedures. This special set of numerical procedures must efficiently solve large, sparse Lyapunov equations, solve sets of Lyapunov equations that differ only in the coefficient matrix Q, and provide good low rank estimates of the Lyapunov equation solution X in the case where low rank approximations are applicable. Discussions of the motivations for the solution of these problems and of candidate solution approaches are provided  相似文献   
5.
Several types of ink are used in web offset printing. However, heatset inks predominate in general commercial work. In these inks, the vehicle consists of resin dissolved in a solvent, and drying takes place mainly by evaporation. In heatset web offset printing, the printed web is passed through dryers, which raise the temperature of the web enough to cause evaporation of the solvent. leaving only the resin to bind the pigment into a film and to the paper.

Since the solvents used in the heatset inks vary in boiling range from approximately 232° C to 316° C, and the solvent selected depends on the printing conditions, it is necessary to determine the vapor pressure values of heatset inks versus web temperatures for drying calculations. The isoteniscope method is limited to only the vapor pressure measurement of liquids. It cannot be used for materials such as heatset inks. To overcome this difficulty, an apparatus was designed and con- structed by TEC Systems for directly measuring the vapor pressure versus temperature of heatset inks from approximately 21°C to 316°C. In this paper, TEC's apparatus, test procedure developed, and typical test results for pure solvents and heatset inks will be described.  相似文献   
6.
For pt.I see ibid., vol.39, no.3, p.258-67 (1992). The winding of fiber optic filament in the hoop, or precision, pattern is considered. Various automatic control options that have been designed and tested are described. The controllers are designed to regulate the fiber lag angle, which is the angle at which the feed filament approaches the take-up spool. Successful, flawless winding is directly related to accurate lag regulation. The contributions are distinguished by the fact that the automatic winding rate is 10 to 30 times greater than that achieved before by operator-assisted winding  相似文献   
7.
Poly(2,4‐dimethyl‐1,4‐phenylene oxide) (PPO), poly(benzo[1,2‐d:5,4‐d′]bisoxazole‐2,6‐diyl‐1,4‐phenylene) (PBO) and poly(benzo[1,2‐d:4,5‐d′]bisthiazole‐2,6‐diyl‐1,4‐phenylene) (PBZT), which are polymers with extended conjugated structures, undergo a self‐sensitized photo‐induced electron‐transfer reaction. A second component is not required. This article presents many similar observations on these polymers when they are exposed to light and evidence to support the proposed photo‐induced electron‐transfer mechanism. Methods to stabilize these polymers against photo‐oxidation are also described. Workers investigating other conjugated polymeric systems may find the experimental methods, observations and polymer stabilization approaches discussed in this review useful. Copyright © 2005 Society of Chemical Industry  相似文献   
8.
Studies the anomalous variations of the OFF-state leakage current (IOFF) in n-channel poly-Si thin-film transistors (TFTs) under static stress. The dominant mechanisms for the anomalous IOFF can be attributed to (1) IOFF increases due to channel hot electrons trapping at the gate oxide/channel interface and silicon grain boundaries and (2) IOFF decreases due to hot holes accumulated/trapped near the channel/bottom oxide interface near the source region. Under the stress of high drain bias, serious impact ionization effect will occur to generate hot electrons and hot holes near the drain region. Some of holes will be injected into the gate oxide due to the vertical field (~(V_Gstress V_Dstress)/T OX) near the drain and the others will be migrated from drain to source along the channel due to lateral electric field (~V_Dstress/LCH)  相似文献   
9.
In this paper, we present an analytical model to evaluate the hidden station effect on the performance of the IEEE 802.11 Distributed Coordination Function (DCF) in both non-saturation and saturation condition. DCF is a random channel-access scheme based on Carrier Sense Multiple Access with Collision Avoidance (CSMA/CA) method and the exponential backoff procedure. DCF is widely used and can support both wireless network with an access point and ad hoc wireless network because of its random channel-access method. On the other hand, this method unavoidably suffers the hidden station effect that causes significant performance degradation. As shown in this paper, hidden stations occur frequently in real-world settings, and the performance impact on the 802.11 DCF is a significant concern, but it has not been adequately studied. We study this problem through a spatial–temporal analysis and a Markov chain model. Our model generalizes the existing work on the performance modeling of 802.11 DCF for both non-saturation and saturation conditions. The scenario of no hidden station can be considered as a special case in our model. The performance of our model is evaluated by comparison with ns-2 simulations.  相似文献   
10.
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