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91.
This paper studies the first-principles calculations of the effect of hydrostatic pressure on the structural, electronic and magnetic properties of Ga0.75Cr0.25As dilute magnetic semiconductor in zb (B3) phase. High-pressure behaviour of Ga0.75Cr0.25As has been investigated between 0 and 100 GPa. The calculations have been performed using DFT as implemented in code SIESTA using LDA + U as an exchange-correlation (XC) potential. The study of band structures shows half-metallic ferromagnetic nature with 100% spin polarization. Under application of external pressure, the valence band and conduction band are shifted from their positions which lead to modification of electronic structure. 相似文献
92.
K. Seema N. M. Umran Ranjan Kumar 《Journal of Superconductivity and Novel Magnetism》2016,29(2):401-408
This paper presents the effect of disorder on electronic, magnetic, and optical properties of Co2CrZ (Z = Al, Si, Ga, Ge) Heusler alloy using density functional theory. Binary mixing is the most common form of atomic disorder in these compounds. We have considered three types of disorders: DO 3, A2, and B2 disorder which corresponds to X-Y, X-Z, and Y-Z mixing, respectively. After structural optimization, we found that A2 disorder has high formation energy and is most unlikely to occur. The half-metallic nature of the alloy is destroyed in the presence of DO 3 and A2 disorder. The destruction of half-metallicity is due to reconstruction of energy states. B2 disorder retains the half-metallic nature of the alloy but spin-polarization value is reduced slightly as compared to the ordered alloy. In addition, the optical properties such as dielectric function, refractive index, absorption spectra, optical conductivity, reflectivity, and energy loss function of these alloys have also been investigated. 相似文献
93.
Choong Jin Yang Ph.D. Ranjan Ray Ph.D. 《JOM Journal of the Minerals, Metals and Materials Society》1989,41(9):42-45
A rapid solidification melt spinning technique has been developed to produce amorphous powders of Fe-Nd-B alloys modified with hafnium diboride. The amorphous powders are consolidated by the hot extrusion technique into bulk magnets of various cross sections. Consolidated magnets show ultrafine grain structure stabilized by ultrafine submicron hafnium diboride particles. The extruded magnets develop strong texture-induced magnetic anisotropy which leads to attractive energy product values of up to 16MGOe. Significant improvement in coercivity is also achieved due to ultrafine grain structure of the extruded magnets. 相似文献
94.
The online version of the original article can be found at 相似文献
95.
Meenoti M. Patel Ranjan M. Bhatt 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1992,53(3):253-263
Alkaline peroxide pretreatment for the delignification of rice straw was optimised by varying the concentrations of H2O2 and NaOH and changing the temperature and duration of the pretreatment. Changes in the lignin content, content of total carbohydrates and weight loss were measured during the pretreatments. Maximum delignification of 62% was obtained by pretreating rice straw at 50°C for 5h with 1.5% (w/v) NaOH and 1% (v/v) H2O2, The preferential loss of hemicellulose and lignin from the straw resulted in an increase in the cellulose content of the insoluble residue after pretreatment from 47% (untreated) to 67.79% (treated). The product of this treatment is characterised by having higher cellulose digestibility than untreated rice straw. It also has use as a carbohydrate source in ruminant feed since the in-vivo digestibility by the cow increased from 56.85 % to 76.54% (P < 0.001). The treated rice straw could also be used for commercial process such as the generation of Single Cell Protein. Growth of Sporotrichum pulverulentum on treated rice straw gave a protein product of 24.41 % as compared to 3.8% on untreated rice straw. 相似文献
96.
Active solar distillation system integrated with solar pond is the green energy system for desalination without negative environmental impact. This clean technology has potential to contribute a lot to water security, sustainable development, and world stability. In this article, results of the energy as well as exergy analysis performed on this novel system integrated with solar pond are presented. This theoretical analysis is carried out in the climatic conditions of New Delhi (India) during a typical summer day. The model and procedures can be helpful in the design, and performance investigation of the actual system anywhere in the world. The daily productivity, energy, and exergy efficiency of the passive solar still are found to be 5 L/m2, 38.63 %, and 2.71 %, respectively, corresponding to a sum total of 24.436 MJ/m2 day solar energy input in passive mode. With the integration of solar pond in the active solar still, the daily productivity, energy, and exergy efficiency rises to about 9.5 L/m2, 46 %, and 14.81 % respectively, for thermal energy input from 100 to 500 W/m2 during off-sunshine hours. The further improvement in the performance of the same system is observed if the thermal energy is supplied continuously (24 h) to the solar still in addition to incident solar radiation. The proposed system will meet the demand of freshwater in both rural and urban areas and help in reducing the load of CO2 emission on the environment, saving high grade energy consumed for desalination through conventional devices and technologies. 相似文献
97.
This work reports the surface functionalization of polymeric PLGA nanoparticles by non-covalent insertion of a homo-bifunctional chemical crosslinker, bis(sulfosuccinimidyl) suberate (BS3) for targeted cancer therapy. We dissolved BS3 in aqueous solution of PVA during formulation of nanoparticles by a modified solid/oil/water emulsion solvent evaporation method. The non-covalent insertion of BS3 was confirmed by Fourier transform infrared (FTIR) spectroscopy. Curcumin and annexin A2 were used as a model drug and a cell specific target, respectively. Nanoparticles were characterized for particle size, zeta potential and surface morphology. The qualitative assessment of antibody attachment was performed by transmission electron microscopy (TEM) as well as confocal microscopy. The optimized formulation showed antibody attachment of 86%. However, antibody attachment was abolished upon blocking the functional groups of BS3. The availability of functional antibodies was evaluated by the presence of a light chain fraction after gel electrophoresis. We further evaluated the in vitro release kinetics of curcumin from antibody coated and uncoated nanoparticles. The release of curcumin is enhanced upon antibody attachment and followed an anomalous release pattern. We also observed that the cellular uptake of nanoparticles was significantly higher in annexin A2 positive cells than in negative cells. Therefore, these results demonstrate the potential use of this method for functionalization as well as to deliver chemotherapeutic agents for treating cancer. 相似文献
98.
InSug O-Sullivan Ranjan Kc Gurjit Singh Vaskar Das Kaige Ma Xin Li Fackson Mwale Gina Votta-Velis Benjamin Bruce Arivarasu Natarajan Anbazhagan Andre J. van Wijnen Hee-Jeong Im 《International journal of molecular sciences》2022,23(20)
Tropomyosin receptor kinase A (TrkA/NTRK1) is a high-affinity receptor for nerve growth factor (NGF), a potent pain mediator. NGF/TrkA signaling elevates synovial sensory neuronal distributions in the joints and causes osteoarthritis (OA) pain. We investigated the mechanisms of pain transmission as to whether peripheral sensory neurons are linked to the cellular plasticity in the dorsal root ganglia (DRG) and are critical for OA hyperalgesia. Sensory neuron-specific deletion of TrkA was achieved by tamoxifen injection in 4-week-old TrkAfl/fl;NaV1.8CreERT2 (Ntrk1 fl/fl;Scn10aCreERT2) mice. OA was induced by partial medial meniscectomy (PMM) in 12-week-old mice, and OA-pain-related behavior was analyzed for 12 weeks followed by comprehensive histopathological examinations. OA-associated joint pain was markedly improved without cartilage protection in sensory-neuron-specific conditional TrkA knock-out (cKO) mice. Alleviated hyperalgesia was associated with suppression of the NGF/TrkA pathway and reduced angiogenesis in fibroblast-like synovial cells. Elevated pain transmitters in the DRG of OA-induced mice were significantly diminished in sensory-neuron-specific TrkA cKO and global TrkA cKO mice. Spinal glial activity and brain-derived neurotropic factor (BDNF) were significantly increased in OA-induced mice but were substantially eliminated by sensory-neuron-specific deletion. Our results suggest that augmentation of NGF/TrkA signaling in the joint synovium and the peripheral sensory neurons facilitate pro-nociception and centralized pain sensitization. 相似文献
99.
100.
Two commercial precipitation-hardening (PH) stainless steels were modified with 2.64 to 2.86 wt% Ti and 1.2 to 1.3 wt% B via rapid solidification technology (RST) and powder metallurgy (PM). The resulting alloys exhibited improved tensile and yield strengths over their commercial PH stainless steel counterparts at room and elevated temperatures. Ductility improvements at elevated temperatures were also observed. The improved mechanical properties were due to extremely fine microstructures stabilized by a fine dispersion of boride phases. 相似文献