A methodology for product mix planning in semiconductor foundrymanufacturing

Since a semiconductor foundry plant manufactures a wide range of memory and logic products using the make-to-order business model, the product mix is an important production decision. This paper first describes the characteristics of the product mix planning problem in foundry manufacturing that are attributable to the long flow time and queuing network behaviors. The issues of time bucket selection, mix optimization and bottleneck-based planning are next addressed. A decision software system based on integer linear programming techniques and a heuristic procedure has been implemented for mix planning. Data provided by a wafer plant has been used to study problems related to product mix planning. It was determined that the suitable time bucket of planning is either one week or one month and the lead-time offset factor should be included in the logic of workload calculation. This paper also presents various facets of product mix decisions and how they should be integrated with operations management     

Benzodithiophene Hole‐Transporting Materials for Efficient Tin‐Based Perovskite Solar Cells

Developing efficient interfacial hole transporting materials (HTMs) is crucial for achieving high‐performance Pb‐free Sn‐based halide perovskite solar cells (PSCs). Here, a new series of benzodithiophene (BDT)‐based organic small molecules containing tetra‐ and di‐triphenyl amine donors prepared via a straightforward and scalable synthetic route is reported. The thermal, optical, and electrochemical properties of two BDT‐based molecules are shown to be structurally and energetically suitable to serve as HTMs for Sn‐based PSCs. It is reported here that ethylenediammonium/formamidinium tin iodide solar cells using BDT‐based HTMs deliver a champion power conversion efficiency up to 7.59%, outperforming analogous reference solar cells using traditional and expensive HTMs. Thus, these BDT‐based molecules are promising candidates as HTMs for the fabrication of high‐performance Sn‐based PSCs.     

Room-Temperature Quantum Cascade Laser: ZnO/Zn1−x Mg x O Versus GaN/Al x Ga1−x N

A ZnO/Zn_1?x Mg _x O-based quantum cascade laser (QCL) is proposed as a candidate for generation of THz radiation at room temperature. The structural and material properties, field dependence of the THz lasing frequency, and generated power are reported for a resonant phonon ZnO/Zn_0.95Mg_0.05O QCL emitting at 5.27 THz. The theoretical results are compared with those from GaN/Al _x Ga_1?x N QCLs of similar geometry. Higher calculated optical output powers [ $ {P}_{\rm{ZnMgO}} $  = 2.89 mW (nonpolar) at 5.27 THz and 2.75 mW (polar) at 4.93 THz] are obtained with the ZnO/Zn_0.95Mg_0.05O structure as compared with GaN/Al_0.05Ga_0.95N QCLs [ $ {P}_{\rm{AlGaN}} $  = 2.37 mW (nonpolar) at 4.67 THz and 2.29 mW (polar) at 4.52 THz]. Furthermore, a higher wall-plug efficiency (WPE) is obtained for ZnO/ZnMgO QCLs [24.61% (nonpolar) and 23.12% (polar)] when compared with GaN/AlGaN structures [14.11% (nonpolar) and 13.87% (polar)]. These results show that ZnO/ZnMgO material is optimally suited for THz QCLs.     

Atomic‐Scale CoOx Species in Metal–Organic Frameworks for Oxygen Evolution Reaction

The activity of electrocatalysts strongly depends on the number of active sites, which can be increased by downsizing electrocatalysts. Single‐atom catalysts have attracted special attention due to atomic‐scale active sites. However, it is a huge challenge to obtain atomic‐scale CoO_x catalysts. The Co‐based metal–organic frameworks (MOFs) own atomically dispersed Co ions, which motivates to design a possible pathway to partially on‐site transform these Co ions to active atomic‐scale CoO_x species, while reserving the highly porous features of MOFs. In this work, for the first time, the targeted on‐site formation of atomic‐scale CoO_x species is realized in ZIF‐67 by O₂ plasma. The abundant pores in ZIF‐67 provide channels for O₂ plasma to activate the Co ions in MOFs to on‐site produce atomic‐scale CoO_x species, which act as the active sites to catalyze the oxygen evolution reaction with an even better activity than RuO₂.     

New CO2 laser lines in the 11-μm wavelength region:new hot bands

Nineteen new laser lines in the 11-μm wavelength region have been observed in CW oscillation from a CO₂ laser with a high-Q, high-resolution cavity at a higher than usual current density. The frequency of each line has been measured using heterodyne frequency measurement techniques. Analysis of the frequencies shows that 15 lines are rotation-vibration transitions of the 01¹2-[11¹1,03¹1]_I band (the first sequence hot band) of the CO₂ molecule and four lines belong to the rotation-vibration transitions of the 02²1-[12 ²0, 04²0]_I band of CO₂     

IMPACCT: Methodology and Tools for Power-Aware Embedded Systems

Power-aware systems are those that must exploit a widerange of power/performance trade-offs in order to adapt to the power availabilityand application requirements. They require the integration of many novel powermanagement techniques, ranging from voltage scaling to subsystem shutdown.However, those techniques do not always compose synergistically with eachother; in fact, they can combine subtractively and often yield counterintuitive,and sometimes incorrect, results in the context of a complete system. Thiscan become a serious problem as more of these power aware systems are beingdeployed in mission critical applications.To address the problem of technique integration for power-aware embedded systems, we propose a new design tool framework called IMPACCT and the associated design methodology. The system modeling methodology includes application model for capturing timing/powerconstraints and mode dependencies at the system level. The tool performs power-awarescheduling and mode selection to ensure that all timing/power constraintsare satisfied and that all overhead is taken into account. IMPACCT then synthesizesthe implementation targeting a symmetric multiprocessor platform. Experimentalresults show that the increased dynamic range of power/performance settingsenabled a Mars rover to achieve significant acceleration while using lessenergy. More importantly, our tool correctly combines the state-of-the-arttechniques at the system level, thereby saving even experienced designersfrom many pitfalls of system-level power management.     

Fabrication process simulation and reliability improvement of high-brightness LEDs

To enhance the light extraction efficiency and thermal performance of AlGaInP light-emitting diodes (LEDs), the wafer bonding technique which can replace the GaAs substrate with other high thermal conductivity substrates was applied. However, this technique may make the film crack during either the removal etching process of the GaAs substrate or the annealing process after the GaAs removal. Therefore, this crack problem is an important issue in the reliability/yield of high-brightness LEDs. In this research, a detailed finite element model of the high-brightness AlGaInP LED, which is replaced by the GaAs substrate with high thermal conductivity substrate through the Au–In metal bonding technique, was developed and fabricated. In addition, the mechanical behavior of wafer-level metal bonding was also simulated by finite element analysis (FEA) and validated by experimental measurements. Hence, the above validated simulation technique combined with process modeling is used to understand the stress variation of the multilayer structure of AlGaInP LED during the fabrication process and to find the principal cause of the film crack.     

Minimum-energy multicast in mobile ad hoc networks using network coding

The minimum energy required to transmit one bit of information through a network characterizes the most economical way to communicate in a network. In this paper, we show that, under a layered model of wireless networks, the minimum energy-per-bit for multicasting in a mobile ad hoc network can be found by a linear program; the minimum energy-per-bit can be attained by performing network coding. Compared with conventional routing solutions, network coding not only allows a potentially lower energy-per-bit to be achieved, but also enables the optimal solution to be found in polynomial time, in sharp contrast with the NP-hardness of constructing the minimum-energy multicast tree as the optimal routing solution. We further show that the minimum energy multicast formulation is equivalent to a cost minimization with linear edge-based pricing, where the edge prices are the energy-per-bits of the corresponding physical broadcast links. This paper also investigates minimum energy multicasting with routing. Due to the linearity of the pricing scheme, the minimum energy-per-bit for routing is achievable by using a single distribution tree. A characterization of the admissible rate region for routing with a single tree is presented. The minimum energy-per-bit for multicasting with routing is found by an integer linear program. We show that the relaxation of this integer linear program, studied earlier in the Steiner tree literature, can now be interpreted as the optimization for minimum energy multicasting with network coding. In short, this paper presents a unifying study of minimum energy multicasting with network coding and routing.     

Optimization of the host/vector system and culture conditions for production of penicillin acylase in Escherichia coli

Culture performance for the production of penicillin acylase (PAC) in a bioreactor was investigated using HB101 or ATCC11105 as the host and pCLL2902, pCLL3201 or pTrcKnPAC2902 as the expression plasmid. We observed that the production of PAC by HB101 harboring pCLL3201 was, similar to ATCC11105, induced by phenyl acetic acid (PAA) and catabolicaily repressed by glucose, whereas the production of PAC by HB101 harboring pCLL2902 did not require PAA for induction and was not repressed by glucose. PAC activity of HB101 harboring pCLL2902 was significantly higher than that of HB101 harboring pCLL3201. There was no significant effect of host or carbon source on the production of PAC using pCLL2902. The production of PAC by HB101 harboring pTrcKnPAC2902, in which the pac gene expression was controlled by the trc promoter system, was about the same as that by HB101 harboring pCLL2902, when the culture was appropriately induced with isopropyl beta-d-thiogalactopyranoside (IPTG). Therefore, the use of both pCLL2902 and pTrcKnPAC2902 could be expected to be feasible for industrial applications. However, optimization of IPTG induction for HB101 harboring pTrcKnPAC2902 might be required, since formation of inclusion bodies tends to limit the production of PAC in some cases.     

Dithering and its effects on sigma-delta and multistage sigma-delta modulation

The spectrum of the quantization error in a dithered sigma-delta modulator is derived under the constraint that the dithering signal does not cause overload. The results apply to DC, sinusoidal, and more general quasi-stationary signals. It is shown in the case of a simple sigma-delta modulation that no-overload dithering can smooth the error spectrum and can make the quantization error asymptotically uncorrelated with the input. It does not, however, make the quantization error white. In the case of multistage sigma-delta modulation with the appropriate dithering, the quantization error becomes white, even for a system with only two stages. The signal-to-quantization-noise ratio (SQNR) is derived for sigma-delta and multistage sigma-delta oversampled analog-to-digital conversion with additive dithering. Simulation results, are presented to support the theoretical analysis.<>