Alternative fatty food simulants for migration testing of polymeric food contact materials.

The amounts of substances migrating from plastics into foodstuffs with high fat contents are in most cases higher than in foodstuffs with water contents. This increase in migration commonly is due to the higher solubility of the migrating organic compounds in fat compared to water. The increase in migration is not necessarily due to an increase in the substance's diffusion coefficient due to interactions between the fat and the plastic as is often assumed. Ethanol is a good simulant for fatty foods because it has little interaction with many plastics, e.g. polyolefins, migrants are readily soluble in it, and because it is easy to work with analytically. The utilizable limits of ethanol and ethanol/water mixtures as food simulants are developed from the physical background of diffusion. The use of ethanol and ethanol/water mixtures is supported by published experimental migration results.     

IDENTIFICATION OF NITROGEN COMPOUNDS AND THEIR EVOLUTIONDURINGAGEING NABSENCE ANDPRESENCE OF ADDITIVES EFFICIENCYOFHYDROTREATMENT

As established by several previous works, nitrogen compounds play a prominent role in the evolution of middle distillates containing cracked components, particularly regarding sediment formation and color evolution.

In a first part, this paper describes and compares stability properties of fuel blends using both an accelerated ageing method at 120°C (248°F ) and long term storage methods at 43°C(110°F) -ASTM 0 4625 - and at ambient temperature. Effectiveness of stabilizing additives is also evaluated. In mixtures containing LCOs, insoluble products are formed progressively during ageings, more or less rapidly according to the chemical constitution of the mixtures.

Then, it reports the complete identification of nitrogen compounds using gas chromatography equipped with a selective nitrogen detector and mass spectrometry showing that in light cycle oils, alkyl indoles and carbazoles are the main families.

Evolution of these compounds was followed kinetically during ageings in absence and presence of additives and alkyl indoles appeared as the moat evolutionary.

It appeared that some additives avoided evolutions of alkyl indoles without preventing sediment formation and color evolution. Oxidation mechanism involving nitrogen compounds should not be the only one to explain the storage evolutions of middle distillates.

Hydrotreatment converts all the alkyl indoles of LCO and prevents coloration end deposits in the storage of the mixtures of steaight-run distillates and LCOs.     

DIFFUSION LAG TIME FOR MULTIPLE AND PERIODIC LAMINATES

The permeability and lag time for a heterogeneous diffusion system, in which the diffusivity and partition coefficient for the diffusant are dependent on position, are formulated in terms of a linear asymptotic analysis. A repeated integration of the diffusion equation is used to obtain the time dependence of the total solute release into the receiver, Q(t). The asymptotic form of Q(t) is linear in time. The slope, and intercept of this linear asymptote with the time axis, respectively, give formulas for the steady-state permeability and lag time. These formulas are then applied to diffusion systems of multiple laminates, consisting of a series of different homogeneous slabs. Thus, for the first time, a concise treatment of diffusion in multiple laminates is obtained. The formulas are also applied to periodic laminates, consisting of a series of identical slabs, but with position-dependent diffusivity and partition coefficient. We found that the lag time can be well approximated by (nh))²/(6D_eff), where n and h are, respectively, the number and thickness of individual lamella, and D_eff is an effective diffusivity, for which a relation in terms of the local property distributions is obtained. This approximation becomes more accurate with increasing number of lamellae. At n = 5, the relative error is already within 4%. Finally a procedure is discussed for readily obtaining the lag time for periodic structures consisting of a serial repetition of a multi-laminate.     

Measuring interdiffusion at an interface between two elastomers with tapping-mode and contact-resonance atomic force microscopy imaging

Despite the common use of tapping-mode atomic force microscopy to image composites or polymer blends, very few studies have focused on the measurement of the interdiffusion at an interface between two polymers in contact. In this study, we show how to assess the interphase between two polymers with two methods. First, stable and robust tapping conditions are established, and the problem of the phase contrast is discussed. Second, a contact-resonance method is presented: the tip in contact with the sample is electrostatically excited at its resonance frequency by a self-controlled oscillator. The gain and frequency images allow us to measure the interdiffusion width. Both methods (using high and weak mechanical solicitation) give the same assessment of the interdiffusion width. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Fast and accurate pricing of discretely monitored barrier options by numerical path integration

Barrier options are financial derivative contracts that are activated or deactivated according to the crossing of specified barriers by an underlying asset price. Exact models for pricing barrier options assume continuous monitoring of the underlying dynamics, usually a stock price. Barrier options in traded markets, however, nearly always assume less frequent observation, e.g. daily or weekly. These situations require approximate solutions to the pricing problem. We present a new approach to pricing such discretely monitored barrier options that may be applied in many realistic situations. In particular, we study daily monitored up-and-out call options of the European type with a single underlying stock. The approach is based on numerical approximation of the transition probability density associated with the stochastic differential equation describing the stock price dynamics, and provides accurate results in less than one second whenever a contract expires in a year or less. The flexibility of the method permits more complex underlying dynamics than the Black and Scholes paradigm, and its relative simplicity renders it quite easy to implement.     

Space-charge-limited currents for organic solar cells optimisation

Basic suppositions and microphysical origin of the occurrence of the space-charge-limited currents (SCLC) are presented in general and for the temperature-modulated space-charge-limited currents (TM-SCLC) in particular. The criteria are given for the spectroscopical method TM-SCLC to be used for localized electron states elucidation in organic semiconducting materials for organic solar cells optimization and modelling. The “visibility “of the localized states by SCLC method, i.e. the power of the SCLC method to distinguish the localized states, is tested by the modelling, varying the temperature, energy position of localized states and their concentration. Generally, it was determined that the SCLC measurements results are more reliable with the increased energy of the states, with their increased concentration and with decreased temperature. The correlation (or its absence) between the measured current and activation energy on applied voltage, expressed by the dependence of preexponential factor of conductivity on activation energy (Meyer–Neldel rule), gives the possibility to determine the energy range where the reconstruction of density of localized states function is reliable.     

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