Novel Al2O3‐C Refractories with Less Residual Carbon Due to Nanoscaled Additives for Continuous Steel Casting Applications

A new generation of thermal shock resistant Al₂O₃‐C refractories with approximately 30% less residual carbon and functionalized due to nanoscaled additives based on carbon nanotubes (CNTs) and alumina nanosheets (α‐Al₂O₃) were developed and investigated after coking at 1000 and 1400 °C. With the aid of electron backscatter diffraction analyses (EBSD) on fracture surfaces of the carbon bonded samples, Al₃CON was identified on the nanosheet shapes already at 1000 °C coking temperature. The Al₃CON new phase based on the reaction between alumina nanosheets and CNTs offers a chemical interconnecting phase for the carbon as well as for the oxide alumina filler. The new refractory composite structure presents excellent thermo‐mechanical properties in spite the lower carbon content. In addition, due to EDS and EBSD analyses amorphous whiskers and platelets within the system of Si? O were observed in samples coked at 1000 °C, that were transformed to crystalline β‐SiC‐whiskers in samples coked at 1400 °C.     

Development of [60] fullerene supported on silica catalysts for the photo-oxidation of alkenes

Simple or successive incipient wetness impregnation followed by heating at 180 °C is proved an efficient preparation method for dispersing effectively onto the silica surface various amounts of C₆₀ in the range 1–4% (w/w). BET, XRD, DRS, TGA, microelectrophoresis and photoluminescence have been used to characterize the photocatalysts prepared. A high dispersion was obtained for the quite stable supported C₆₀ phase, comprised mainly from relatively small or medium size C₆₀ clusters/aggregates. The photocatalytic activity was assessed in the singlet oxygen oxidation of alkenes by examining the photo-oxygenation of 2-methyl-2-heptene as a probe reaction. The catalytic tests were carried out at 0–5 °C in CH₃CN, under oxygen atmosphere and using a 300 W xenon lamp as the light source. The heterogeneous catalysts obtained were proved to be active in the photocatalytic oxidation of olefins via a ¹O₂ ene reaction. The catalysts exhibited significant conversion, turnover number and turnover frequency values, substantially higher than those achieved over the unsupported C₆₀. The conversion increases with the amount of the supported C₆₀ up to a value equal to 3% (w/w) and then it decreases whereas turnover number and turnover frequency decreases monotonically as the amount of the supported C₆₀ increases. The easy separation of these solid catalysts from the reaction mixture, the high activity and stability as well as the retained activity in subsequent catalytic cycles, make these supported catalysts suitable for a small-scale synthesis of fine chemicals.     

Decatungstate catalyst supported on silica and γ-alumina: Efficient photocatalytic oxidation of benzyl alcohols

Four supported catalysts with the same tungsten loading were prepared by depositing decatungstate species W₁₀O⁴⁻₃₂, through wet impregnation, on the surface of γ-alumina and silica at different pH values. The prepared samples were characterized using BET measurements as well as XRD, UV–vis DR, and XP spectroscopies. Higher dispersion of W(VI) oxo-species was obtained in the silica-supported catalysts compared with the corresponding alumina-supported ones. Within the same support, the dispersion was higher when the impregnation pH is lower than the point of zero charge (pzc) of the support. The decatungstate anions were present mainly on the silica surface without any modification, whereas these underwent a partial depolymerization on their deposition on the γ-alumina surface. The extent of depolymerization was less in the sample prepared at pH above pzc. These findings were explained in terms of the mode of deposition of the W(VI) species from the solution onto the support surface. The photocatalytic activity of the aforementioned catalysts, concerning the photooxidation of 1-phenylethanol, depends on the fraction of the W₁₀O⁴⁻₃₂ supported species rather than on the W(VI) dispersion. Thus, extremely high conversions have been obtained over the silica-based catalysts and also over the γ-alumina-based catalyst prepared at relatively high pH. These catalysts also are very effective in the photooxidation of a series of secondary and primary benzyl alcohols, in which benzyl ketones and benzoic acids were formed as the only or major products, respectively. The easy separation of the solid catalyst from the reaction mixture, the high activity, selectivity, and stability as well as the retained activity in subsequent catalytic cycles, make these supported catalysts suitable for a small-scale synthesis. Based on product analysis and kinetic data on the heterogeneous oxidation of benzyl alcohols, we suggest that a hydrogen abstraction transfer (HAT) mechanism predominates with respect to an electron transfer (ET) one in these reactions.     

Water supply management approaches using US on the island of Rhodes, Greece

Desalination powered by renewable energy sources (RES) is presented as an alternative option for the water supply augmentation in the semi-arid region of the island of Rhodes. The case study was chosen as the island relies mostly on the exploitation of groundwater resources and faces serious water shortage problems in an already stressed environment. Alternatives are discussed and compared in contrast to the construction of storage dams to meet urban water needs up to the year 2040. Results may indicate that through the use of financial incentives coupled with holistic water management approaches, desalination powered by RES could be an attractive and environmentally friendly option in an effort to solve problems related to water quantity and quality in semi-arid regions with adequate renewable energy potential.     

Providing and verifying advanced IP services in hierarchical DiffServ networks‐the case of GEANT

The differentiated services (DiffServ) framework is widely proposed as an efficient method for providing advanced IP services to large‐scale networks, with QoS requirements. However, the provisioning of such services in production networks has proved to be more difficult than initially expected, in defining, setting and verifying appropriate Service Level Agreements (SLAs). GEANT, the Gigabit core pan‐European research network, on a pilot basis introduced ‘Premium IP’ service, offering bounded delay and negligible packet loss to the European National Research & Education Networks (NRENs) that it interconnects. However, large scale provisioning of this new service requires the definition of efficient interaction procedures between administrative domains involved and methods for SLA monitoring. This paper focuses on these issues and presents the experience acquired from the early experiments in GEANT, as an example of hierarchical Gigabit multi‐domain environment, enabled with QoS provisioning to its constituent NRENs. This model scales more efficiently than the common peering Internet Service provider (ISP) commercial paradigm. Finally, we outline other options that promise QoS, such as Layer 2 VPNs in MPLS backbones, with non‐standard (yet) mechanisms. Copyright © 2004 John Wiley & Sons, Ltd.     

Using Information Retrieval techniques for supporting data mining

The classic two-stepped approach of the Apriori algorithm and its descendants, which consisted of finding all large itemsets and then using these itemsets to generate all association rules has worked well for certain categories of data. Nevertheless for many other data types this approach shows highly degraded performance and proves rather inefficient.

We argue that we need to search all the search space of candidate itemsets but rather let the database unveil its secrets as the customers use it. We propose a system that does not merely scan all possible combinations of the itemsets, but rather acts like a search engine specifically implemented for making recommendations to the customers using techniques borrowed from Information Retrieval.     

Simulation and modelling methods in aluminium rolling industry

Aluminium coil production plants can be described as multi-stage processes which are often characterised by complexity and are expected to manipulate huge amount of data. Effective scheduling is a key issue for these processes since it can improve throughput rates and machine utilisation. This paper studies the production line of companies which produce high-quality rolled aluminium lithographic strips. An efficient representation for such production processes is provided and subsequently used for an extensive analysis and performance evaluation through appropriate metrics. In particular, the work addresses the implementation of an overall model in a simulation environment, capable of integrating the various aspects of the specific production management processes. The model was successfully validated using actual production data, and it was found that it is suitable for the modelling, analysis and performance evaluation of the complex aluminium coils production process. With the aid of the model, various scenarios were investigated via extensive simulation runs, such as installing additional machine centres and reducing pre-set times the products spend in intermediate storage areas.     

A study of forward error correction for mobile multicast

3rd Generation Partnership Project (3GPP) has standardized the use of forward error correction (FEC) for the provision of reliable data transmission in the mobile multicast framework. This error control method inevitably adds a constant overhead in the transmitted data. However, it is so simple as to meet a prime objective for mobile multicast services; that is scalability to applications with thousands of receivers. In this paper, we present a study on the impact of application layer FEC on mobile multicast transmissions. We examine whether it is beneficial or not, how the optimal code dimension varies based on network conditions, which parameters affect the optimal code selection, and how this can be done. Additionally, we focus on one of the most critical aspects in mobile multicast transmission, which is power control. The evaluation is performed with the aid of a novel scheme that incorporates the properties of an evolved mobile network, as they are specified by the 3GPP. Copyright © 2010 John Wiley & Sons, Ltd.