Kinetic Study on Absorption of SO2 and NOX with Acidic NaClO2 Solutions Using the Spraying Column

The operating conditions of this study are close to the typical operating conditions of flue gas desulfurization system in coal-fired power plants. The aim of this study is to investigate the absorption kinetics of SO2 and NO from simulated flue gas into an aqueous solution of acidic sodium chlorite using a bench-scale spraying column. The range of absorption rates measured in this study is between 1.91×10?11 and 9.59×10?10?mol?s?1?cm?2. The range of rate constants measured in this study is between 1.32×107 and 1.21×108?(L?mol?1)1.9?s?1, and the average rate constant is 6.16×107?(L?mol?1)1.9?s?1. The activation energy and frequency factor are 129 Kcal/mol (53.97 KJ/mol) and 6.93×1016?[(L/mol)1.9/s], respectively.     

Work-hardening and recovery mechanisms in gamma-based titanium aluminides

The work-hardening mechanisms in two-phase γ-titanium aluminide alloys were characterized in terms of the glide obstacles determining the velocity and slip path of dislocations, utilizing transmission electron microscopy (TEM) observations and thermodynamic-glide parameters. There was clear evidence that short-range obstacles in the form of dislocation debris and dipoles were produced during plastic deformation at room temperature. These dislocation obstacles contributed significantly to work hardening. The observed strong strain hardening arose from long-range elastic dislocation interactions and the production of dipole and debris defects. The thermal stability of these deformation-induced defects was assessed by isothermal and isochronal annealing. The results indicated that the dipole and debris defects were relatively unstable upon annealing at moderately high temperatures, which led to significant recovery of work hardening. This article is based on a presentation made in the symposium entitled “Fundamentals of Structural Intermetallics,” presented at the 2002 TMS Annual Meeting, February 21–27, 2002, in Seattle, Washington, under the auspices of the ASM and TMS Joint Committee on Mechanical Behavior of Materials.     

Thermodynamic calculations for Nb-containing high-speed steels and white-cast-iron alloys

Thermodynamical equilibria have been calculated for a wide variety of high-speed steel compositions belonging to the multicomponent system Fe-C-W-Mo-V-Cr-Nb as well as for two series of white-cast-iron alloys containing niobium. Some temperature-concentration diagrams for both classes of alloys are presented and calculated quantities (melting and transformation temperatures, amounts and compositions of phases) are compared with experimental data. Good agreement between calculated and experimental information has been obtained, with the exception of the MC phase compositions and transformation temperatures for white-cast-iron alloys with high carbon and chromium contents. These differences can, however, be satisfactorily explained by plausible kinetic effects.     

Floating-patch MEMS antennas on HRS substrate for millimetre-wave applications

Novel floating-patch micro-electro-mechanical system (MEMS) antennas are proposed for millimetre-wave applications. The floating-patch MEMS antennas are fabricated on a high resistivity silicon (HRS) substrate using surface micromachining technology. Simulation and experimental results for reflection coefficients and radiation patterns are presented.     

Deposition and Properties of Superconducting MgB2 Thin Films

The recently discovered superconductor MgB₂ with T _c at 39 K has great potential in superconducting electronics. In this paper, we review the deposition techniques used for MgB₂ thin films in the light of a thermodynamic study of the Mg-B system with the calculation of phase diagrams (CALPHAD) modeling technique. This thermodynamic study identifies a growth window in the pressure–temperature phase diagram, in which the magnesium pressure is very high for likely in situ growth temperatures. A Hybrid Physical–Chemical Vapor Deposition (HPCVD) technique that successfully achieves such a high Mg pressure is shown to produce in situ epitaxial MgB₂ thin films with bulk superconducting properties.     

Interstate forensic psychology consultations: A call for reform and proposal of a model rule.

Forensic psychology has made important gains in professional recognition and stature in the courts, resulting in increasing demands for mobility of expertise. Current regulations regarding the interjurisdictional temporary forensic practice of psychology, however, are characterized by variability of regulations, ambiguity and inaccessibility, and continuing total barriers. A uniform, well-reasoned policy is needed. A conceptual basis for such a policy is provided by a discussion of licensing rationales and the application of these to forensic practice. Uniformity, public and professional protection, and practicability are identified as fundamental regulatory criteria. A Model Rule Regarding the Temporary Forensic Practice of Psychology is proposed for adoption by state licensing boards on a nationwide basis. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Effects of ternary additions on the thermoelastic martensitic transformation of NiAl

Nickel-rich β-NiAl alloys, which are potential materials for high-temperature shape-memory alloys, show a thermoelastic martensitic transformation, which produces their shape memory effect. However, the transformation to Ni₅Al₃ phase during heating of NiAl martensite can interrupt the reversible martensitic transformation; consequently, the shape memory effect in NiAl martensite might not appear after heating. The phase transformation process in binary Ni-(34 to 37)Al martensite was investigated by differential thermal analysis (DTA) method, and we found that the condition of reversible martensitic transformation was not the β → Ni₅Al₃ transformation, but rather the M → Ni₅Al₃ transformation occurring at 250 °C to 300 °C. Therefore, the transformation temperature of M → Ni₅Al₃ determined the highest operating temperature for the shape memory effect. For verifying the critical temperature, the phase transformation process was investigated for eight ternary Ni-33Al-X alloys (X=Cu, Co, Fe, Mn, Cr, Ti, Si, and Nb). Only Ti, Si, and Nb additions were found to be effective in dropping the M _s temperature, and they facilitated the shape memory effect in Ni-33Al-X alloys. In particular, the addition of Si and Nb raised the transformation temperature of M → Ni₅Al₃, a potentially beneficial effect for shape memory at higher temperatures. This article is based on a presentation made in the symposium entitled “Fundamentals of Structural Intermetallics,” presented at the 2002 TMS Annual Meeting, February 21–27, 2002, in Seattle, Washington, under the auspices of the ASM and TMS Joint Committee on Mechanical Behavior of Materials.     

Influence of Ni Interlayers on the Mechanical Properties of Ti6Al4V/(WC-Co) Friction Welds

Ni interlayers were introduced prior to dissimilar friction welding of Ti6Al4V base material to three cemented carbide substrates. The fracture strength of Ti6Al4V/(WC-6 wt% Co) welds were poor and were markedly improved when 20-µm thick Ni interlayers were introduced prior to dissimilar friction welding. These results were only produced when the (WC-6 wt% Co) cermet was electroplated prior to friction welding. When the Ti6Al4V alloy was electroplated prior to friction welding, fractured WC particles and cracking were observed in the (WC-Co) carbide substrate. The fracture strengths of Ti6Al4V/(WC-11 wt% Co) and Ti6Al4V/(WC-24 wt% Co) welds were not improved when 20-µm thick Ni interlayers were introduced prior to friction welding. During mechanical testing, the Ni layer retained at the dissimilar joint interface created a region of weakness.     

Experimental and analytical studies of innovative prestressed concrete box-girder bridges

This paper presents experimental and analytical results of four scaled prestressed concrete box-girder bridges with corrugated steel webs. The location of prestressing strands at both ends of the specimens and the thickness of end diaphragms are the two major parameters. Based on the experimental results of all four specimens, their seismic behavior is critically examined, including hysteretic loops, ductility factor, dissipated energy, and failure mode, etc. It was found that both the thickness of end diaphragms and the location of prestressing strands at both ends of the specimens are insignificant when the specimens failed at the mid-span due to concrete crushing, and the proposed analytical model can be used to predict the load-displacement relationship of such bridges.