Graft copolymerization of styrene onto casein initiated by potassium diperiodatonickelate (IV) in alkaline medium

A novel redox system, potassium diperiodatonickelate (Ni(IV))‐casein is used to initiate graft copolymerization of Styrene onto casein under different conditions in aqueous alkaline solution. Graft copolymers with both high grafting efficiency (>98%) and percentage of grafting(>300%) are obtained, which indicated that (Ni(IV))‐casein redox pair is an efficient initiator for this grafting. The effects of reaction parameters, such as monomer‐to‐casein weight ratio, initiator concentration, pH, time, and temperature, are investigated. A tentative initiation mechanism is proposed. The structures and properties of the graft copolymer are characterized by Fourier transform infrared Spectroscopy, X‐ray diffraction diagrams, and Scanning Electron Microscope. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 4247–4251, 2006     

Polypropylene/polyamide 6/polyethylene-octene elastomer blends. Part 3. Mechanisms of volume dilatation during plastic deformation under uniaxial tension

It has been shown in a previous paper in this series that important dilatation is produced by plastic deformation under tension of neat PP and PP/PA6/POE blends, for which the POE to PA6 concentration ratio equals 1/2. In this work, the detailed mechanisms of this volume change are investigated from electron micrographs (SEM and TEM) obtained in the deformed state. At low alloy content, it is thus observed that dilatation results from decohesion of the PA6 particles from the PP matrix. As the amount of PA6 and POE increases, voids are nucleated preferentially in the thicker POE interphase making a shell around the PA6 particles, and secondarily in isolated POE particles. Unexpectedly, it has been found that the overall volume dilatation decreases with total alloying content. This is interpreted by: (i) the increasing contribution of PA6 that intrinsically deforms with less cavitation than PP, (ii) the post-cavitation rubber-like stretching of POE particles and, (iii) the early formation of a percolating network of shear bands from the diffuse array of voids formed after the yield point. These mechanisms explain the gradual increase of the resistance to impact of the PP/PA6/POE as their alloying content is increased.     

VoIP技术及其安全性研究

本文首先介绍了VoIP技术的研究和发展方向,通过分析VoIP的核心协议——SIP协议的安全问题和研究现状,说明VoIP安全性能的研究内容和现实意义,最后给出了本研究的发展方向。     

Numerical simulation on the rheo-diecasting of the semi-solid A356 aluminum alloy

The effect of injection pressure, piston velocity, and the forming temperature of semisolid slurry on the filling behavior of the semi-solid A356 aluminum alloy was investigated by simulation methods. The simulation results show that these processing parameters have an important effect on the filling behavior of the semi-solid A356 aluminum alloy. The slurry flows steadily in the cavity when the injection pressure, the piston velocity, and the forming temperature are low, but it is prone to turbulent flow w...     

建筑外饰面材料太阳辐射反射性能测试方法分析

外饰面材料的太阳辐射吸收性能影响着建筑的能源消耗,为降低建筑的能耗,外饰面材料的选取要考虑其太阳辐射性能.试验检测是获得外饰面材料太阳辐射性能参数的一种直接有效的方法.已有的测试方法各有其优缺点,本文在分析常用的测试方法的基础上,提出一种简捷经济的测试方法,为外饰面材料的太阳辐射性能测试提供指导.     

国家职业危害实验基地规划研究

针对我国职业危害形势的严峻性及我国现阶段职业危害防治研发基地和支撑条件案件相对落后的实际,提出建设国家职业危害实验基地。通过国内外调研,根据初步规划研究将建立职业危害检测与鉴定、放射卫生防护检测与评价、生物监测、工业通风研究、减振防噪研究、人类工效学研究、劳动防护用品检测与研发等七个研究中心,组成职业危害检测与评价和职业卫生工程两个研究平台,为提高我国职业危害的防治水平打下基础。     

一种组态式产品设计方法

为了实现产品的快速定制和设计知识的重用,以进一步提高设计效率,促进产品配置的智能化,在模块化的基础上,文章提出了一种组态式的产品设计方法。对组件、组态概念进行了界定;对组件化方法、组态过程进行了阐述;并给出了组态系统的方程。最后,以某工装夹具的组件化和组态过程为例,详细说明了组态设计的基本原理和方法。     

Cavitation characteristics of pit structure in ultrasonic field

Bubble collecting, bubble holding and micro-bubble ejecting characteristics of pit structure and the influence of cavitation bubble on the development of erosion pit are investigated by means of high-speed photography experiments. Pits tend to collect and hold wandering cavitation bubbles. The air holding phenomenon of pits can be a destination of the incubation period in the process of cavitation erosion. The holding bubble tends to eject micro-bubbles from the top of holding cavitation bubble, making the pit a source of nuclei. With bubbles being held in pits, the diameters of pits increase rapidly. But in the given experiment condition, there is a specific stable value beyond which the diameter of pits will not increase. This characteristic will be helpful in understanding and predicting the cavitation erosion process. Supported by the National Basic Research Program of China (“973” Program) (Grant No. 2007CB714105) and the National Natural Science Foundation of China (Grant No. 50539060)     

环形橡胶径向刚度特性仿真分析

利用ANSYS软件建立了环形橡胶的有限元参数化模型,将对模型仿真所得结果与已有数据进行对比,验证了仿真模型的正确性,实现了环形橡胶径向刚度的快速计算.在此基础上,分析了内外圆柱面半径与轴向长度对环形橡胶简化径向刚度值的影响,研究了环形橡胶的径向刚度特性,确立了在环形橡胶实际设计中需要考虑的要点,为环形橡胶的设计提供了依据.