Despite the rapid developments are achieved for perovskite solar cells (PSCs), the existence of various defects in the devices still limits the further enhancement of the power conversion efficiency (PCE) and the long-term stability of devices. Herein, the efficient organic potassium salt (OPS) of para-halogenated phenyl trifluoroborates is presented as the precursor additives to improve the performance of PSCs. Studies have shown that the 4-chlorophenyltrifluoroborate potassium salt (4-ClPTFBK) exhibits the most effective interaction with the perovskite lattice. Strong coordination between BF3−/halogen in anion and uncoordinated Pb2+/halide vacancies, along with the hydrogen bond between F in BF3− and H in FA+ are observed. Thus, due to the synergistic contribution of the potassium and anionic groups, the high-quality perovskite film with large grain size and low defect density is achieved. As a result, the optimal devices show an enhanced efficiency of 24.50%, much higher than that of the control device (22.63%). Furthermore, the unencapsulated devices present remarkable thermal and long-term stability, maintaining 86% of the initial PCE after thermal test at 80 °C for 1000 h and 95% after storage in the air for 2460 h. 相似文献
International Journal of Computer Vision - Can our video understanding systems perceive objects when a heavy occlusion exists in a scene? To answer this question, we collect a large-scale dataset... 相似文献
Action recognition based on a human skeleton is an extremely challenging research problem. The temporal information contained in the human skeleton is more difficult to extract than the spatial information. Many researchers focus on graph convolution networks and apply them to action recognition. In this study, an action recognition method based on a two-stream network called RNXt-GCN is proposed on the basis of the Spatial-Temporal Graph Convolutional Network (ST-GCN). The human skeleton is converted first into a spatial-temporal graph and a SkeleMotion image which are input into ST-GCN and ResNeXt, respectively, for performing the spatial-temporal convolution. The convolved features are then fused. The proposed method models the temporal information in action from the amplitude and direction of the action and addresses the shortcomings of isolated temporal information in the ST-GCN. The experiments are comprehensively performed on the four datasets: 1) UTD-MHAD, 2) Northwestern-UCLA, 3) NTU RGB-D 60, and 4) NTU RGB-D 120. The proposed model shows very competitive results compared with other models in our experiments. On the experiments of NTU RGB?+?D 120 dataset, our proposed model outperforms those of the state-of-the-art two-stream models.
The formation mechanism of surface texture for feed-direction ultrasonic vibration?assisted milling (UVAM) was investigated in this study by establishing a kinematic model and a pressing model of UVAM. The kinematic model showed that the cutter tip, which was supposed to be totally sharp, produced closed scratches by crossed trajectories. The variation trends of the interval for closed textures were of sine function. A comparative experiment was carried out by UVAM and conventional milling. A dividing line close to the X coordinate divides the surface feature into two parts. The pressing model showed that the tool minor cutting edge left clear traces with certain width because of the tool minor cutting edge angle. Scratches by tool minor cutting edge were intermittent and regularly varied when feed-direction vibration was introduced. All the surface feature changes are in the radial direction and the trajectory intersections shall always be the scratch grooves or ridges. The ratio between ultrasonic vibration frequency and spindle speed, tool radius, and the located cutter rotation angle affected the changing rule of scratches by tool minor cutting edge. The analytical models and the experimental results proved to each other reasonable. 相似文献
Although the photoacoustic effect is almost universally generated by radiation whose intensity is varied in time either by amplitude modulation of a continuous optical source or through the use of pulsed irradiation, it is possible to produce sound by movement of a continuous source in space. Here, the characteristics of sound production by movement of a light source in one dimension are discussed by solution to the wave equation for pressure. Solutions to the wave equation for the velocity potential, from which the acoustic pressure can be determined, are found using the D’Alembert integral and by Fourier transformation of the wave equation. The characteristics of the waveform generated by a Gaussian heat source moving uniformly in space are found to depend on the initial conditions for movement of the source. 相似文献