Méthode d'Analyses Statistiques Informatisées des Microtoponymes Franc-Comtois

Sans résumé Fran?oise Greffier works especially on microtoponymy; she does research at MIS (Mathématique, Informatique, Statistique), Université de Besan?on. Thèse de 3ieme cycle, I.M.S.S. (Informatique et Mathématique appliquées aux sciences sociales), Université de Grenoble II, 1985, soutenue par Fran?oise Greffier.     

Effect of Chlorine Atmosphere on the Anatase-Rutile Transformation

The anatase-rutile phase transformation in Ar–Cl₂ atmosphere has been investigated by X-ray powder diffraction, thermogravimetry, and scanning electron microscopy. At 950°C the phase transformation in Ar–Cl₂ atmosphere is about 300 times faster than in air. The growth of crystals of rutile from the vapor phase has been observed. We also determined that anatase powders with adsorbed chlorine rapidly rapidly transformed to rutile and underwent a color change from white to gray when they were heated in Ar atmosphere.     

For cost-reducing technologies, knowing markets is to change them

Benefiting from an understanding of economic and political markets includes recognition that engineers themselves can change these environments. Understanding healthcare and other technology markets includes an understanding that the markets sometimes don't just exist-they are altered and sometimes created by the technology. A less expensive and more effective means to monitor a disease such as PKU enhances the likelihood that insurers will cover costs of such monitoring. Recognizing the complexity of economics and policy recognizes that understanding sometimes comes in a burst of insight but more usually, and surely, builds in steps. Since improvements in quality of life are inadequately captured by the market, will political "markets" develop subsidies or regulations to encourage technology?.     

Effect of leavening agents and sugars on the formation of hydroxymethylfurfural in cookies during baking

The effects of recipe compositions in terms of leavening agent (ammonium and sodium bicarbonates) and sugars (sucrose and glucose), and baking conditions (temperature and time) on HMF formation in cookies were studied. Five recipes were prepared by varying the types of leavening agent and sugar. The cookies were baked at different temperatures (180, 200, 210 and 220 °C) for different time (10, 15, 20 and 25 min) to monitor physical and chemical changes in cookie composition in terms of water activity, pH, surface browning, sugar decomposition, and hydroxymethylfurfural (HMF) formation. Decreasing moisture to a level under a water activity of 0.4 appeared as the critical point in baking where the rate of HMF formation drastically increased after this point. After this stage, sucrose decomposed very rapidly if ammonium bicarbonate was used as the leavening agent at temperatures greater than 200 °C. Replacing ammonium bicarbonate with sodium bicarbonate maintained pH of cookies ranging between 9.0 and 10.0 during baking, which limited the decomposition of sucrose.     

Combined effect of gamma-irradiation and conventional cooking onAeromonas hydrophila in meatball

Irradiation combined with a conventional cooking procedure was applied to meatball and the effects on bacterial load and inoculatedAeromonas hydrophila were determined. Meatball samples were irradiated by using a⁶⁰Co source at the dose levels of 0, 0.30,0.75,1.50,2.50 kGy and cold stored at 4±1°C for 7 days. Bacterial load and the count ofA. hydrophila decreased when the irradiation dose level increased. A minimum inhibition effect was found at the dose of 0.30 kGy. Irradiation in combination with a conventional cooking procedure was found to be more effective in reducingA. hydrophila and the bacterial load in meatball. This study indicated that a dose of 0.75 kGy was sufficient to destroy approximately 10⁴ cfu/g ofA. hydrophila in meatball.     

Knowledge processing in control systems

A real-time knowledge processing procedure is proposed for rule-based systems in general and control systems applications in particular. Distinguishing features of the procedure include a mechanism for rule base compression and an inference scheme based on matrix operators. The procedure is also amenable for schedulability analysis to provide response time warranty. An application concerning supervisory group control of elevators is also included to show the usefulness of the proposed procedure     

Drying nano particles solution on an oscillating tip at an air liquid interface: what we can learn, what we can do

Evaporation of fluid at micro and nanometer scale may be used to self-assemble nanometre-sized particles in suspension. Evaporating process can be used to gently control flow in micro and nanofluidics, thus providing a potential mean to design a fine pattern onto a surface or to functionalize a nanoprobe tip. In this paper, we present an original experimental approach to explore this open and rather virgin domain. We use an oscillating tip at an air liquid interface with a controlled dipping depth of the tip within the range of the micrometer. Also, very small dipping depths of a few ten nanometers were achieved with multi walls carbon nanotubes glued at the tip apex. The liquid is an aqueous solution of functionalized nanoparticles diluted in water. Evaporation of water is the driving force determining the arrangement of nanoparticles on the tip. The results show various nanoparticles deposition patterns, from which the deposits can be classified in two categories. The type of deposit is shown to be strongly dependent on whether or not the triple line is pinned and of the peptide coating of the gold nanoparticle. In order to assess the classification, companion dynamical studies of nanomeniscus and related dissipation processes involved with thinning effects are presented.     

Stress reduction during phase change in Ge<Subscript>2</Subscript>Sb<Subscript>2</Subscript>Te<Subscript>5</Subscript> by capping TiN film

It has been one of the most important issues to minimize the stress reduction during phase change in GST (Ge₂Sb₂Te₅) alloy for PRAM (Phase-change Random Access Memory) applications, because the alloy has been reported to face the significant stress during the phase change. We fabricated GST/oxide/substrate as a basic structure, and then added two more structures by capping an adhesion layer (Ti) or a barrier metal (TiN) on GST layer, respectively. We report that TiN-capped structure shows about 40% stress reduction during the phase change compared with that of the basic structure. The stress reduction is considered to be due to the intrinsic compressive stress in TiN film itself.     

Synthesis by the solution combustion process and magnetic properties of iron oxide (Fe<Subscript>3</Subscript>O<Subscript>4</Subscript> and α-Fe<Subscript>2</Subscript>O<Subscript>3</Subscript>) particles

This article describes the solution combustion synthesis technique as applicable to iron oxide powder production using urea as fuel and ferric nitrate as an oxidizer. It focuses on the thermodynamic modeling of the combustion reaction under different fuel-to-oxidant ratios. X-ray diffraction showed magnetite (Fe₃O₄) and hematite (α-Fe₂O₃) phase formations for the as-synthesized powders. The smallest crystallite size was obtained by stoichiometric chemical reaction. The magnetic properties of the samples are also carefully discussed as superparamagnetic behavior.     

Photoinduced birefringence in blends of a polyurethane bearing azobenzene moieties and a poly(amide–imide)

A polyurethane (MDI‐DR19Cl) bearing azobenzene moieties was prepared by condensation of 4,4′‐diphenylmethylenediisocyanate and an azobenzene compound, 2‐chloro‐4‐nitro‐4′‐[bis‐(2‐hydroxyethyl)]amine‐azobenzene (DR19Cl). Blends of MDI‐DR19Cl and a poly(amide‐imide) were prepared and characterized by UV‐visible and Fourier transform infrared spectroscopy and by DSC. The purpose of using the blends was to overcome the lack of stability of cast films of pure MDI‐DR19Cl, which tend to crack on storage under ambient conditions. This was successfully achieved and, depending on blend proportions, flexible self‐standing films could be prepared after thermal treatment. Optical storage experiments performed with the blends and pure MDI‐DR19Cl cast films showed a decrease in the remnant values of photoinduced birefringence in the blends (60 % for the blend with 5 wt% MDI‐DR19Cl) compared to pure MDI‐DR19Cl (75%), but, taking into account the low content of MDI‐DR19Cl used, the results obtained are probably sufficient to show the viability of these blends in optical storage applications. Copyright © 2006 Society of Chemical Industry