Novel electrolytes for solid oxide fuel cells with improved mechanical properties

The improvement of the mechanical properties of novel structured electrolytes with triangular cut off geometry in the active region is presented by filleting the tips of triangles. The effect of fillet radius on the bending strength of the yttria stabilized zirconia electrolyte was investigated with a commercial finite element code implementing the calculated Weibull stress through the experimental stress–strain curve determined via tensile tests. The model was verified with the experimental three point bending test results for the electrolyte with unfilleted triangular cut off patterns. Ten different fillet radii ranging from 0.05 mm to 0.5 mm were considered in the simulations. The fracture displacement was found to increase with increasing fillet radius as expected. Since the electrolyte with fillet radius of 0.5 mm was found to show the highest flexural strength, single cell based on this electrolyte was fabricated and the cell performance was measured. It was found that the strength of the novel electrolyte with partly reduced thickness can be increased by 26.2% with sacrificing only 10.2% decrease in the performance. Since the final cell still showed 22.2% higher peak performance than the standard electrolyte supported cell, 10.2% decrease in the cell performance compared to the cell having unfilleted triangular cut off patterns is acceptable.     

A new congestion control algorithm for improving the performance of a broadcast-based multiprocessor architecture

Congestion occurring in the input queues of broadcast-based multiprocessor architectures can severely limit their overall performance. The existing congestion control algorithms estimate congestion based on a node’s output channel parameters such as the number of free virtual channels or the number of packets waiting at the channel queue. In this paper, we have proposed a new congestion control algorithm to prevent congestion on broadcast-based multiprocessor architectures with multiple input queues. Our algorithm performs congestion control at the packet level and takes into account the next input queue number which will be accessed by the processor, which form the fundamental differences between our algorithm and the algorithms based on the idea of virtual channel congestion control. The performance of the algorithm is evaluated by OPNET Modeler with various synthetic traffic patterns on a 64-node Simultaneous Optical Multiprocessor Exchange Bus (SOME-Bus) architecture employing the message passing protocol. Performance measures such as average input waiting time, average network response time and average processor utilization have been collected before and after applying the algorithm. The results show that the proposed algorithm is able to decrease the average input waiting time by 13.99% to 20.39%, average network response time by 8.76% to 20.36% and increase average processor utilization by 1.92% to 6.63%. The performance of the algorithm is compared with that of the other congestion control algorithms and it is observed that our algorithm performs better under all traffic patterns. Also, theoretical analysis of the proposed method is carried out by using queuing networks.     

Bypass routing: An on-demand local recovery protocol for ad hoc networks

On-demand routing protocols for ad hoc networks reduce the cost of routing in high mobility environments. However, route discovery in on-demand routing is typically performed via network-wide flooding, which consumes a substantial amount of bandwidth. In this paper, we present bypass routing, a local recovery protocol that aims to reduce the frequency of route request floods triggered by broken routes. Specifically, when a broken link is detected, a node patches the affected route using local information, which is acquired on-demand, and thereby bypasses the broken link. We implemented SLR (Source Routing with Local Recovery) as a prototype of our approach. Simulation studies show that SLR achieves efficient and effective local recovery while maintaining acceptable overhead.     

The effect of 1.5 T and 3 T magnetic resonance imaging on microleakage of amalgam restorations

The aim of this article is to compare the effects of 1.5 T and 3 T MRI on microleakage of amalgam restorations. A total of 90 extracted molar teeth were used in this study. Amalgam was used to restore standard Class V preparations (5 × 3 × 2 mm). Following the restoration, the teeth were divided into three groups according to magnetic resonance imaging (MRI) protocol (Group I: Control, Group II: 1.5 T MRI, and Group III: 3 T MRI). A total of 6,000 thermal cycles at 5°C–55°C were applied on all samples. Microleakage values were measured in millimeters using the ImageJ program. Microleakage values were higher in the gingival region compared to the occlusal region in all groups and the differences were statistically significant (p < .05). Microleakage values were not statistically different among the groups in the occlusal region (p > .05), while there were statistically significant differences among the groups with respect to microleakage values in the gingival region (p < .01). The highest mean microleakage amount in the gingival region was measured in Group III (1.192 ± 0.941 mm). This was followed by Group II (0.519 ± 0.813 mm) and Group I (0.347 ± 0.726 mm), respectively. Within the limitations of this in vitro study, we observed that higher microleakage values in amalgam restored teeth in which were exposed to MRI procedure. We also found that the teeth exposed to the stronger magnetic field showed higher microleakage amount.     

Fatty acid-based polyurethane films for wound dressing applications

Fatty acid-based polyurethane films were prepared for use as potential wound dressing material. The polymerization reaction was carried out with or without catalyst. Polymer films were prepared by casting-evaporation technique with or without crosslink-catalyst. The film prepared from uncatalyzed reaction product with crosslink-catalyst gave slightly higher crosslink density. The mechanical tests showed that, the increase in the tensile strength and decrease in the elongation at break is due to the increase in the degree of crosslinking. All films were flexible, and resisted to acid solution. The films prepared without crosslink-catalyst were more hydrophilic, absorbed more water. The highest permeability values were generally obtained for the films prepared without crosslink catalyst. Both the direct contact method and the MMT test were applied for determination of cytotoxicity of polymer films and the polyurethane film prepared from uncatalyzed reaction product without crosslink-catalyst showed better biocompatibility property, closest to the commercial product, Opsite.     

Optimization of electro-blown polysulfone nanofiber mats for air filtration applications

Durable, robust, and hydrophobic air filtration media was produced via electro-blow spinning (EBS) technique using polysulfone (PSU) due to its superior properties. To our knowledge, this is the first optimization study of PSU nanofiber production via EBS technique for air filtration applications. Concentration, air pressure, and voltage were determined as independent variables for the optimization based on “smaller is the better” approach of Taguchi Design of Experiment. The optimized values which supplied the smallest average fiber diameter (AFD) possible were obtained as 13 wt% PSU, 3 bar, and 7.5 kV. The AFD of the sample obtained from the confirmation experiment was calculated as 105 ± 34 nm. Surface morphologies, porosity values, and wettability behaviors of the samples were investigated by using scanning electron microscopy, gravimetric method, and water contact angle measurements, respectively. PSU nanofiber mats exhibited superhydrophobic behavior (water contact angle values up to 159.8°) which is important for various separation processes. Samples prepared at different deposition times (15, 30, 45, and 60 min) were investigated in terms of particle capture efficiency and pressure drop. The 0.3 μm particle filtration efficiency was found to be 98.09% at an expense of 202 Pa pressure drop which would be suitable for various respiratory and HVAC filter applications.     

The effect of learning analytics-based interventions in mobile learning on students' academic achievements,self-regulated learning skills,and motivations

Universal Access in the Information Society - This study examines the effects of using learning analytics (LA) in a mobile-based learning setting on students' self-regulated learning (SRL)...